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61.
G. Vasudevan P. AnbuSrinivasan G. Madhurambal S. C. Mojumdar 《Journal of Thermal Analysis and Calorimetry》2011,104(3):975-979
Potassium Hydrogen Phthalate also known as Potassium Acid phthalate (KAP) has 14 natural growth faces with dominating (010) face. As the (010) face is more suitable for any surface morphological studies, a number of crystal growth studies have been made on this material in recent years. Here this semi organic crystal was grown by Slow Evaporation Solution Growth Technique. The effect of ammonium sulphate as dopant on the characteristic properties of KAP crystal was studied by thermal and spectral analysis. 相似文献
62.
Lewis acid–mediated arylation of N-protected 2/3-bromomethylindoles with different types of arenes is reported. 相似文献
63.
Let G = GL
N
or SL
N
as reductive linear algebraic group over a field k of characteristic p > 0. We prove several results that were previously established only when N ⩽ 5 or p > 2
N
: Let G act rationally on a finitely generated commutative k-algebra A and let grA be the Grosshans graded ring. We show that the cohomology algebra H
*(G, grA) is finitely generated over k. If moreover A has a good filtration and M is a Noetherian A-module with compatible G action, then M has finite good filtration dimension and the H
i
(G, M) are Noetherian A
G
-modules. To obtain results in this generality, we employ functorial resolution of the ideal of the diagonal in a product
of Grassmannians. 相似文献
64.
Catalase from bovine liver was covalently immobilized on hydrophilic polyurethane composite (CoFoam). The activity of the
enzyme was assayed in the decomposition of H2O2 at pH 7.0 and 25°C. The effects of water-to-prepolymer ration the addition of a crosslinking agent, and the utilization of
a spacer on enzyme, activity were examined. The results of immobilization of the enzyme in a large-scale unit are reported.
The advantage of the CoFoam composite lies in the low drop in pressure in a packed-bed reactor at fairly large flow rates.
For example, at flow rates of 10–12 L/min, the drop in pressure is typically 3 kPa. Enzymes immobilized on CoFoam represent
a novel use as catalysts in packed-bed reactors owing to the low drop in pressure. 相似文献
65.
The melting of alkyl chains in the saturated fatty acid zinc soaps of different chain lengths, Zn(C(n)H(2n+1)COO)(2); n = 11, 13, 15, and 17, have been investigated by powder X-ray diffraction, differential scanning calorimetry, and vibrational spectroscopy. These compounds have a layer structure with the alkyl chains arranged as tilted bilayers and with all methylene chains adopting a planar, all-trans conformation at room temperature. The saturated fatty acid zinc soaps exhibit a single reversible melting transition with the associated enthalpy change varying linearly with alkyl chain length, but surprisingly, the melting temperature remaining constant. Melting is associated with changes in the conformation of the alkyl chains and in the nature of coordination of the fatty acid to zinc. By monitoring features in the infrared spectra that are characteristic of the global conformation of the alkyl chains, a quantitative relation between conformational disorder and melting is established. It is found that, irrespective of the alkyl chain length, melting occurs when 30% of the chains in the soap are disordered. These results highlight the universal nature of the melting of saturated fatty acid zinc soaps and provide a simple explanation for the observed phenomena. 相似文献
66.
A simple, precise and rapid reversed-phase HPLC method was developed for the simultaneous estimation of acetaminophen, ibuprofen and chlorzoxazone in formulations. The method was carried out on a Kromasil® C8 column using a mixture of 0.2% triethylamine:acetonitrile (adjusted to pH 3.2 using dilute orthophosphoric acid), and detection was carried out at 215 nm using ketoprofen as internal standard. All these drugs showed linearity in the range of 2–10 μg ml−1, and limits of quantification was found to be 10, 50 and 20 ng ml−1 for acetaminophen, ibuprofen and chlorzoxazone, respectively. 相似文献
67.
Guliants VV Bhandari R Swaminathan B Vasudevan VK Brongersma HH Knoester A Gaffney AM Han S 《The journal of physical chemistry. B》2005,109(50):24046-24055
The outermost surfaces and subsurface layers of the orthorhombic (M1) Mo-V-O catalysts promoted with Te, Nb, and Sb oxide species at submonolayer surface coverage were examined by low-energy ion scattering (LEIS). This study indicated that the Nb oxide species was preferentially located at the topmost surface, while the subsurface Te and Sb concentrations declined gradually into the bulk. Although the original Mo-V-O catalyst was essentially unselective in propane oxidation to acrylic acid, significant improvement in the selectivity to acrylic acid was observed when Te, Nb, and Sb oxides were present as the surface species at submonolayer coverage. These findings further suggested that the formation of the surface V-O-M bonds (M = Nb, Te, or Sb) was highly beneficial for both the activity and selectivity of the orthorhombic Mo-V-O catalysts in propane oxidation to acrylic acid. The highest selectivity was observed when both Nb and Te (or Sb) oxide species were present at the surface. The selectivity trends established for the surface-promoted Mo-V-O catalyst parallel those found previously for the corresponding bulk Mo-V-M-O catalysts. These results further indicated that the introduction of surface metal oxide species is a highly promising method to prepare well-defined model catalysts for studies of the structure-activity/selectivity relationships as well as optimize the catalytic performance of the bulk mixed Mo-V-M-O catalysts for selective (amm)oxidation of propane. 相似文献
68.
Palligarnai T. Vasudevan Luting Olivia Li 《Applied biochemistry and biotechnology》1996,60(3):203-215
Studies of the kinetic behavior of horseradish peroxidase (HRP) at pH 8 and at room temperature indicate that the reaction
of phenol with H2O2 catalyzed by HRP exhibits normal Michaelis-Menten saturation kinetics. An irreversible reaction mechanism for the steady-state
kinetics of HRP, which is consistent with the experimental data, is considered. The second-order rate constants for the reactions
of HRP with H2O2 and compound II with phenol are 4.14 × 105 M-1s-1 and 5.54 × 104M-1s-1, respectively. 相似文献
69.
MA Freitas SR Dillon RC Dougherty AG Marshall 《Rapid communications in mass spectrometry : RCM》1999,13(15):1622-1625
The self-chemical ionization of diethylzinc is examined by Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry and semiempirical molecular orbital calculations. Electron impact of diethylzinc neutral produces the radical cation, C(4)H(15)Zn(+) (m/z x 122), which reacts further with the neutral (C(2)H(5))(2)Zn to give the following product ions: Zn(+) (m/z x 64), C(2)H(5)Zn(+) (m/z x 93), C(4)H(9)Zn(+) (m/z x 121), C(4)H(11)Zn(2)(+) (m/z x 187), and C(6)H(15)Zn(2)(+) (m/z x 215). To determine the structure and pathways for production of these ions, monoisotopic (12)C(4)H(15)(64)Zn(+), (64)Zn(+) and (12)C(2)H(5)(64)Zn(+) were individually isolated and reacted with the neutral background. We also performed semiempirical molecular orbital calculations (ZINDO/1). The molecular orbital calculations and experimental data are consistent in predicting that the ethyl group on the diethylzinc cation carries the positive charge. Copyright 1999 John Wiley & Sons, Ltd. 相似文献
70.
T. S. Vivekanandam A. Gopalan T. Vasudevan S. Umapathy 《Journal of polymer science. Part A, Polymer chemistry》1998,36(15):2715-2719
Polymerization of acrylamide (M) in the presence of ultrasound and peroxomonosulfate (PMS) was carried out for the first time for various concentration ranges of monomer and initiator and various temperatures at a constant frequency of 1 Mhz. The rate of polymerization Rp was found to increase with increase in the concentration of monomer and initiator and found to depend on [M] and [PMS]1/2. The rate of disappearance of initiator (-d[PMS]/dt) was also followed simultaneously under the experimental conditions and found to increase linearly with increase in [PMS]. A probable reaction mechanism was proposed on the basis of the observed results, and the individual rate constant were evaluated. © 1998 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 36: 2715–2719, 1998 相似文献