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41.
In this paper we present some new and pertinent connections between the Strong Optimization and the Approximate Pareto type
Efficiency, in particular, with the usual Vector Optimization, at first in the Ordered Vector Spaces by the natural Convex
Cones and, afterwards, in the Ordered Hausdorff Locally Convex Spaces. The main result is obtained considering the notion
of full nuclear cone. Our results, is related to an appropriate scalarization method
Mathematics Subject Classification (2000). 90C29 相似文献
42.
This paper reports the mass spectrum of vinyltrimethylsilane over the range of electron-impact energy of 9 to 70 eV as determined with a quadrupole mass spectrometer. Less extensive data obtained with magnetic spectrometers are included for comparison as well as the spectrum of vinyl-tri(methyl-d3)silane. Plots of ion intensity as a function of electron energy, nominal appearance potentials and metastable ion transitions are given. The primary ionization results in an electron deficiency on the silicon atom, followed by loss of either ·CH3, C2H4 or ·C2H3 to give fragments of mass 85, 73 or 72, respectively. The primary fragment of mass 85 loses C2H2 to give the mass 59 ion. The primary fragment of mass 73 loses successively C2H4 and H2 to give first the mass 45 ion and then the mass 43 ion. At 15 eV, the relative intensities of the ions are 85 > 72 > 100 > 59 > 73. At 70 eV, the relative intensities are 59 > 85 > 43 > 45 > 73 > 72 > 100. 相似文献
43.
Nicolae Leopold Simona CîntÎ‐Pînzaru Lszl Szab Daniela Ilean Vasile Chi Onuc Cozar Wolfgang Kiefer 《Journal of Raman spectroscopy : JRS》2010,41(3):248-255
Conjugate acid–base forms of the drug metoclopramide were investigated by Raman spectroscopy in aqueous solutions and by surface‐enhanced Raman scattering (SERS), when the molecules were adsorbed on colloidal silver surfaces. Raman spectra were recorded at pH values below 8, metoclopramide being poorly water soluble at higher pH values. The SERS spectra of metoclopramide were recorded in the 3–11 pH range, even in spite of its low solubility at basic pH values. The Raman and SERS spectra were assigned by means of density functional theory (DFT) calculations. By monitoring several SERS marker bands, the protonated, neutral or the coexistence of both molecular species adsorbed on the colloidal silver particles could be evidenced. The adsorbate orientation was deduced to be perpendicular to the metal surface for the protonated molecular species and tilted for the neutral metoclopramide molecular species. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
44.
Vasile Mioc Daniel Paşca Cristina Stoica 《Nonlinear Analysis: Real World Applications》2010,11(2):920-931
The motion of a material point of unit mass in a field determined by a generalized Hénon–Heiles potential , with standard Cartesian coordinates and , is addressed for two limit situations: collision and escape. Using McGehee-type transformations, the corresponding collision and infinity boundary manifolds pasted on the phase space are determined. These are fictitious manifolds, but, due to the continuity with respect to initial data, their flow determines the near by orbit behaviour.The dynamics on the collision and infinity manifolds is fully described. The topology of the flow on the collision manifold is independent of the parameters. In the full phase space, while spiraling collision orbits are present, most of the orbits avoid collision. The topology of the flow on the infinity manifold changes as the ratio between and varies. More precisely, there are two symmetric pitchfork bifurcations along the line , due to the reshaping of the potential along the bifurcation line. Besides rectilinear and spiraling orbits, the near-escape dynamics includes oscillatory orbits, for which angular momentum alternates sign. 相似文献
45.
Manuela Iftime Carmen Racles Vasile Cozan Maria Bruma Alexander L'Vovich Rusanov 《Journal of Macromolecular Science: Physics》2013,52(8):1668-1680
Three poly(arylene ether sulfone)s (two polymers and one copolymer) containing diphenylfluorene, phenolphthalein and 2,4-bis[(4-chlorophenyl)sulfonyl]-1-(phenyltio) benzene)] units were synthesized by the classical Williamson polyetherification reaction. The association phenomenon in N,N-dimethylformamide (DMF) was investigated by different methods: gel permeation chromatography (GPC), viscosity, atomic force microscopy (AFM), fluorescence spectroscopy and dynamic light scattering (DLS). Both AFM and DLS measurements evidenced the formation of aggregates with spherical or ellipsoidal shape at a concentration around 0.05 wt.%. This behavior could be explained by dipole-dipole interactions between macromolecular chains, probably with the participation of solvent molecules, and by H-bonds involving hydroxyl end groups. 相似文献
46.
Danting Yang Nicoleta E. Mircescu Haibo Zhou Nicolae Leopold Vasile Chi Mircea Oltean Yibin Ying Christoph Haisch 《Journal of Raman spectroscopy : JRS》2013,44(11):1491-1496
Ethyl carbamate (EC), a potentially toxic compound, is found in alcoholic beverages and fermented foodstuff. A combined experimental and theoretical study of Raman on EC is reported in this work for the first time. The Raman bands observed for EC in solid phase are characteristic for the carbonyl group, C―C, C―H and N―H stretching and deformation vibrations. These spectral features coupled with a pKa study allowed establishing the neutral species of EC present in the aqueous solutions experimentally tested at different concentrations. In addition, by performing a density functional theory study in the gas phase, the calculated geometry, the harmonic vibrational modes, and the Raman scattering activities of EC were found to be in good agreement with our experimental data and helped establish the surface‐enhanced Raman scattering (SERS) behavior and EC adsorption geometry on the silver surfaces. The Raman peak at 1006 cm−1, assigned to the υs(CC) + ω(CH) modes, the strongest and best reproducible peak in the SERS spectra, was used for a quantitative evaluation of EC. The limit of detection, which corresponds to a signal‐to‐noise ratio equal to 3, was found to be 2 × 10−7 M (17.8 µg l−1). SERS spectra obtained by using hydroxylamine hydrochloride‐reduced silver nanoparticles provide a fast and reproducible qualitative and quantitative determination of EC in aqueous solution. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
47.
Abstract The problem of the mean square exponential stability for a class of discrete-time linear stochastic systems subject to independent random perturbations and Markovian switching is investigated. The case of the linear systems whose coefficients depend both to present state and the previous state of the Markov chain is considered. Three different definitions of the concept of exponential stability in mean square are introduced and it is shown that they are not always equivalent. One definition of the concept of mean square exponential stability is done in terms of the exponential stability of the evolution defined by a sequence of linear positive operators on an ordered Hilbert space. The other two definitions are given in terms of different types of exponential behavior of the trajectories of the considered system. In our approach the Markov chain is not prefixed. The only available information about the Markov chain is the sequence of probability transition matrices and the set of its states. In this way one obtains that if the system is affected by Markovian jumping the property of exponential stability is independent of the initial distribution of the Markov chain. The definition expressed in terms of exponential stability of the evolution generated by a sequence of linear positive operators, allows us to characterize the mean square exponential stability based on the existence of some quadratic Lyapunov functions. The results developed in this article may be used to derive some procedures for designing stabilizing controllers for the considered class of discrete-time linear stochastic systems in the presence of a delay in the transmission of the data. 相似文献
48.
We propose a bivariate non-homogeneous birth and death process as a model for predator–prey interactions. Its expectation is periodic, as it is a solution to the classical Lotka–Volterra system. Moreover, the mean age at extinction, as defined in Kendall (1948), is infinite. 相似文献
49.
Varga Zsolt Wallenius Maria Nicholl Adrian Mayer Klaus Balan Ionel Benea Vasile 《Journal of Radioanalytical and Nuclear Chemistry》2019,322(3):1585-1591
JRC-Karlsruhe obtained a swipe sample from a highly enriched uranium seizure, which had taken place in 2011. Due to the very low amount of uranium (nanograms) a new method needed to be developed to determine the U production date (age). The particles on the swipe were collected on a pyrolytic graphite planchet using a vacuum impactor and they were subsequently leached with ccHNO3. The “bulk” U isotopic composition (235U: 72.51?±?0.03 wt%) and the production date (December 1992?±?1 year) determined by MC-ICP-MS indicated that the material showed similarity with two other HEU cases seized earlier in Europe.
相似文献50.
We present a model of gauge theory based on the symmetry group G×SU(2) where G is the gravitational gauge group and SU(2) is the internal group of symmetry. We employ the spacetime of four-dimensional Minkowski, endowed with spherical coordinates, and describe the gauge fields by gauge potentials. The corresponding strength field tensors are calculated and the field equations are written. A solution of these equations is obtained for the case that the gauge potentials have a particular form potentials induces a metric of Schwarzschild type on with spherical symmetry. The solution for the gravitational the gravitational gauge group space. 相似文献