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21.
Pietro Baraldi Gian Carlo Franchini Andrea Marchetti Gavino Sanna Lorenzo Tassi Alessandro Ulrici Giulia Vaccari 《Journal of solution chemistry》2000,29(5):489-504
Thermodynamic interactions in the ethane-1,2-diol (1) + 1,2-dimethoxyethane(2) + water (3) ternary system have been investigated in terms of the excessmolar volume, derived from density measurements at 19 different temperaturesfrom –10;dg to 80;dgC. Fourteen three-component mixtures have been considered,covering the entire composition range. The excess molar volumes are discussedin terms of conformational changes induced in each component by the presenceof another one. The results obtained support the hypothesis of the absence of anythree-component complex adducts under all experimental conditions investigated. 相似文献
22.
Andrea Sanna 《Fresenius' Journal of Analytical Chemistry》1906,45(7):447-448
Ohne Zusammenfassung 相似文献
23.
E. Łodyga-Chruścińska S. Ołdziej D. Sanna G. Micera L. Chruściński K. Kaczmarek R.J. Nachman J. Zabrocki A. Sykuła 《Polyhedron》2009
Spectroscopic data, including electronic absorption, CD and EPR results, as well as theoretical calculations have shown that the insertion of 4-aminopyroglutamate, a novel cis-peptide bond mimic, in the insect kinin peptide leads to an effective ligand towards Cu(II) ions at basic pH ranges. The 4-aminopyroglutamate motif induces a specific peptide conformation which favors the formation of one or two five-membered chelating rings stabilizing a bent structure, with the coordination of 3N-type or 4N-type in the metallopeptide molecule involving in metal bonding C-terminal of modified peptide. It is worth noting that the copper(II) bonding does not undergo hydrolysis even at a very high pH range. 相似文献
24.
25.
Sanna Pääkkönen 《Tetrahedron letters》2010,51(51):6695-6699
We report an improved, gentle, cyclic microwave activation technique for the oxidation of secondary alcohols using nonhazardous hypobromous acid (BrOH) as the reagent in acidic water. Several aliphatic and aromatic secondary alcohols were successfully oxidized to the corresponding ketones using this technique in high yields and with only minor amounts of side products. 相似文献
26.
Elena Sanna Eduardo C. Escudero-Adán Antonio Bauzá Pablo Ballester Antonio Frontera Carmen Rotger Antonio Costa 《Chemical science》2015,6(10):5466-5472
A crystalline porous material showing one-dimensional (1-D) rectangular micropores (12 × 9 Å2) has been assembled from a semirigid macrocyclic tetraimine and EtOAc as the templating agent. The 1-D nature of the material is intrinsic to the conformationally rigid structure of a macrocyclic sub-unit bearing four cyclohexylidene residues. The multiple dispersive forces established among the aliphatic residues glutted the 1-D channels and provided thermal stability to the material at temperatures below 160 °C. Upon removal of the template, the structure of the empty solid exhibited permanent microporosity (S
BET = 342 m2 g–1). Being a true molecular sponge, the channel framework of this material allowed the inclusion of a variety of molecular sample guests without compromising its crystalline nature. Remarkably, this crystalline material enabled the structure determination by X-ray diffraction of the included molecules. Theoretical studies demonstrated the vital role played by the dispersive forces in the overall stabilization of the crystal packing. 相似文献
27.
Chong SL Nissilä T Ketola RA Koutaniemi S Derba-Maceluch M Mellerowicz EJ Tenkanen M Tuomainen P 《Analytical and bioanalytical chemistry》2011,401(9):2995-3009
The atmospheric pressure matrix-assisted laser desorption/ionization with ion trap mass spectrometry (AP-MALDI-ITMS) was investigated
for its ability to analyse plant-derived oligosaccharides. The AP-MALDI-ITMS was able to detect xylooligosaccharides (XOS)
with chain length of up to ten xylopyranosyl residues. Though the conventional MALDI–time-of-flight/mass spectrometry (TOF/MS)
showed better sensitivity at higher mass range (>m/z 2,000), the AP-MALDI-ITMS seems to be more suitable for detection of acetylated XOS, and the measurement also corresponded
better than the MALDI-TOF/MS analysis to the actual compositions of the pentose- and hexose-derived oligosaccharides in a
complex sample. The structures of two isomeric aldotetrauronic acids and a mixture of acidic XOS were elucidated by AP-MALDI-ITMS
using multi-stages mass fragmentation up to MS3. Thus, the AP-MALDI-ITMS demonstrated an advantage in determining both mass and structures of plant-derived oligosaccharides.
In addition, the method of combining the direct endo-1,4-β-d-xylanase hydrolysis of plant material, and then followed by AP-MALDI-ITMS detection, was shown to recognize the substitution
variations of glucuronoxylans in hardwood species and in Arabidopsis thaliana. To our knowledge, this is the first report to demonstrate the acetylation of glucuronoxylan in A. thaliana. The method, which requires only a small amount of plant material, such as 1 to 5 mg for the A. thaliana stem material, can be applied as a high throughput fingerprinting tool for the fast comparison of glucuronoxylan structures
among plant species or transformants that result from in vivo cell wall modification. 相似文献
28.
The problem of the optimal scheduling of periodic demands for a given facility or commodity is presented and some properties of an integer programming model are discussed. Algorithms (both of implicit enumeration type and heuristic) are also given. 相似文献
29.
Meso- ( 1a ) and racemic dimethyl α,α'-dibromo o-benzenediacetate ( 1b ) when condensed with hydrazine and methylhydrazine furnished respectively 1,3-dicarbomethoxyisoindole ( 5a ) and its N-methyl derivative ( 5b ). Reaction of phenylhydrazine with 1a led to the N-phenylisoindole ( 5c ) and to the N-anilino isoindoline ( 6 ) as the cis isomer; conversely, 1b was transformed into a mixture of the 2-phenyl-1,2,3,4-tetrahydrophthalazine ( 7 ), the trans isomer of ( 6 ), the N-anilinoisoindole ( 5d ) and dimethyl α-(N'-phenylhydrazino)-o-benzenediacetate ( 8 ). Compounds 1a and 1b were also condensed with acetylhydrazine to give a mixture of the N-acetylaminoisoindoline ( 12 ) and of the 2-acetyl-1,2,3,4-tetrahydrophthalazine ( 13 ). 相似文献
30.
For every and every integer N, let be the minimum of the distance of τ from the sums , where . We prove that , for all sufficiently large positive integers N (depending on C and τ), where C is any positive constant less than . 相似文献