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991.
S. F. Dubinin V. E. Arkhipov Yu. G. Chukalkin S. G. Teploukhov V. D. Parkhomenko Ya. M. Mukovskiĭ 《Physics of the Solid State》2007,49(2):308-314
The magnetic structure and transport properties of partially disordered crystals of two-dimensional manganites La2?2x Sr1+2x Mn2O7 (x = 0.3, 0.4) are studied over a wide range of temperatures. The crystals are transformed into an atomically disordered state under irradiation with fast neutrons at a dose of 2 × 1019 cm?2. The average concentration of substitutional defects in the crystal is ≈4%. It is found that substitutional defects are responsible for the transition of these manganites from the ferromagnetic metal state to the insulator state with a spin glass structure. The results obtained are discussed in terms of the ratio between the kinetic energy of charge carriers and the exchange energy of localized spins. 相似文献
992.
E. Rapis 《Technical Physics》2002,47(4):510-512
Pronounced changes in the physical phase and in the phase transition dynamics of proteins in drying blood plasma are observed. The morphologies (topologies) of these nonequilibrium films in donors and in patients with various types of metastatic carcinoma qualitatively differ by the process of protein film self-assembly and by symmetry type. New types of defects and solid crystals appear, liquid crystals persist for a long time, etc. The microscopic examination of the drying protein plasma topology can be used for diagnosing metastatic carcinoma. 相似文献
993.
994.
J. M. Criado L. A. Pérez-Maqueda M. J. Diánez P. E. Sánchez-Jiménez 《Journal of Thermal Analysis and Calorimetry》2007,87(1):297-300
The SCTA method implies to control the temperature in such a way that
the reaction rate changes with the time according to a function previously
defined by the user. Constant Rate Thermal Analysis (CRTA) is one of the most
commonly used SCTA methods and implies achieving a temperature profile at
which the reaction rate remains constant all over the process at a value previously
selected by the user. This method permits to minimize the influence of heat
and mass transfer phenomena on the forward reaction. The scope of this work
is to develop a universal CRTA temperature controller that could be adapted
to any thermoanalytical device. The thermoanalytical signal is programmed
to follow a preset linear trend by means of a conventional controller that
at the time controls a second conventional temperature programmer that forces
the temperature to change for achieving the trend programmed for the thermoanalytical
signal. Examples of the performance of this control system with a Thermobalance
and a Thermomechanical Analyser (TMA) are given. 相似文献
995.
A. V. Porfir’eva G. A. Evtyugin E. Yu. Podshivalina L. I. Anchikova G. K. Budnikov 《Journal of Analytical Chemistry》2007,62(12):1180-1186
A new technique is proposed for detecting interactions between DNA and DNA autoimmune antibodies using a potentiometric sensor based on a glassy-carbon electrode modified with polyaniline and native DNA from chicken erythrocytes. It is shown that the DNA-antibody interaction changes the rate of polyaniline doping in transferring the DNA sensor from an alkaline (pH 7.5) solution, which is optimum for the immunochemical reaction, to an acidic (pH 3.0) solution. The dynamics of the variation of the DNA sensor potential depends on the titer of antibodies and their origin. The dependence of the DNA sensor signal on the dilution of the blood sera from systemic lupus erythematosus and autoimmune thyroiditis patients shows that DNA antibodies can be diagnosed by the characteristic maximum in the dilution curve found in the range of serum dilutions from 1: 20 to 1: 50. 相似文献
996.
E. S. Voropai M. P. Samtsov K. N. Kaplevskii A. A. Maskevich V. I. Stepuro O. I. Povarova I. M. Kuznetsova K. K. Turoverov A. L. Fink V. N. Uverskii 《Journal of Applied Spectroscopy》2003,70(6):868-874
Comparative analysis of the absorption and fluorescence spectra and fluorescence excitation spectra of thioflavin T (ThT) in various solvents and in the composition of amyloid fibrils has shown that ThT, when excited in the region of the long-wavelength absorption band, fluoresces in the spectral region with a maximum at 478–484 nm. The appearance in aqueous and alcohol solutions of a fluorescence band with a maximum near 440 nm has been attributed to the presence in the composition of the ThT preparations of an impurity with an absorption band in the 340–350-nm range. The literature data showing that in glycerol ThT has a wide fluorescence spectrum with two maxima are due to the artifact connected with the use of a high concentration of the dye. It has been suggested that the cause of the low quantum yield of ThT aqueous and alcohol solutions is the breakage of the system of conjugated bonds due to the reorientation of the benzothiozole and benzaminic rings of ThT in the excited state with respect to one another. The main factor determining the high quantum yield of fluorescence of ThT incorporated in fibrils is the steric restriction of the rotation of the rings about one another under these conditions. The suggestions made have been verified by the quantum-chemical calculation of the ThT molecule geometry in the ground and excited states. 相似文献
997.
The density of the vibrational states of an SiO2 melt under various PT conditions, the distributions of the Si-O-Si and O-Si-O angles in it, and its IR absorption spectra have been calculated by molecular dynamics with the use of a pairwise additive Born-Mayer potential. A comparison with the experimental data reveals that the ionic approximation selected is capable of basically reproducing the structural and spectroscopic properties of the melt, but the distributions of the bond angles are considerably broader than the experimentally determined distributions, and the absorption band caused by the stretching vibrations is not displayed in the calculated spectrum. The disparities indicated are apparently due to the isotropic nature of the potential of the interparticle interactions.V. I. Vernadskii Institute of Geochemistry and Analytical Chemistry, Academy of Sciences of the USSR, Moscow. Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 27, No. 4, pp. 467–470, July–August, 1991. Original article submitted October 12, 1990. 相似文献
998.
999.
1000.
G. Bouwmans B. Ségard P. Glorieux P. A. Khandokhin N. D. Milovsky E. Yu. Shirokov 《Radiophysics and Quantum Electronics》2004,47(10-11):729-742
This paper is devoted to the polarization dynamics of a longitudinally monomode bipolarized Nd:YAG laser: the low-frequency polarization dynamics of a microchip laser is studied experimentally and theoretically. The intensities and the relaxation oscillation spectrum of orthogonally polarized modes versus the direction of pump polarization is observed. A phase-sensitive model of a longitudinally monomode bipolarized solid-state laser with linear polarized diode laser pump is developed to account for the experimental observations. 相似文献