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81.
Hydrogels of N‐vinylimidazole (VI) and sodium styrenesulfonate (SSS) were synthesized in aqueous solution by radical crosslinking copolymerization with N,N′‐methylene‐bis(acrylamide) as crosslinker. Swelling in several saline solutions was measured for hydrogel samples synthesized with different comonomer concentrations (CT = 10, 25, or 40%) and with SSS mole fractions covering a broad range (fSSS = 0–0.7), while the crosslinker ratio was 2 wt % in all cases. The degree of swelling in aqueous solution with a specific ionic strength (μ), plotted versus the SSS composition of the feed, shows a minimum for any set of samples synthesized with a fixed CT. The dependence of swelling on μ shows both polyelectrolyte (fSSS beyond the minimum) and antipolyelectrolyte behaviors (in the low fSSS limit). It was found that the nonGaussian factor of the crosslinking density and the polymer‐solvent interaction parameter increase with fSSS for any CT. Moreover, in the low fSSS limit, the osmotic swelling pressure is governed not only by the ionic contribution, but also by the polymer‐solvent mixing and, the concentration of mobile counterions inside the gel is not proportional to the net fixed charge but to the addition of cationic and anionic side groups, what discards the formation of ionic pairs. The antipolyelectrolyte effect is interpreted as due to the increasing protonation of VI as μ goes up. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1683–1693, 2007 相似文献
82.
E. Sh. Finkel'shtein N. V. Ushakov N. A. Pritula E. A. Andreev N. A. Platé 《Russian Chemical Bulletin》1992,41(1):185-187
The thermally initiated and platinum-catalyzed polymerization of 1-silacyclobutanes with substitutents containing a trimethylsilyl group was carried out. Soluble, high-molecular-weight, heterochain siltrimethylene polymers were obtained, containing trimethylsilyl groups removed from the main chain by various bridges.A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 117912 Moscow. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 1, pp. 223–225, January, 1992. 相似文献
83.
A. Mahoui J. Lapasset D. G. Sannikov J. Moret P. Saint Grégoire 《Zeitschrift für Physik B Condensed Matter》1995,99(4):543-549
The crystal structure [(C2H5)4N]2CuCl4 has been determined by X-ray diffraction at 243K. The room temperature phase (phase I) belongs to the space group P42/nm [1] whereas the low temperature phase (phase II) is orthorhombic and belongs to the space group Pnna. The phase transition at Tc=258K is of improper ferroelastic type and it is associated with the ordering of the CuCl4 2? and a partial ordering of the [(C2H5)4N]+ ions which are disordered in the high temperature tetragonal phase. At lower temperature, there occurs another instability which could correspond to a complete ordering in the crystal. 相似文献
84.
Details are given of a new method allowing an exact calculation of the spontaneous magnetization in the corner as well as along the edge at an arbitrary distance of the corner for a rectangular planar Ising ferromagnet. 相似文献
85.
F. Grisch P. Bouchardy M. Péalat B. Chanetz T. Pot M. C. Coët 《Applied physics. B, Lasers and optics》1993,56(1):14-20
Rotational temperature and nitrogen number density are measured in the shock wave/boundary layer interaction region in the vicinity of a two-dimensional compression corner disposed in a low pressure, 55 K, Mach 10 hypersonic air flow. Spatially-resolved data are recorded using a nonlinear optical technique named dual-line coherent anti-Stokes Raman scattering (DLCARS). Averaged temperature and density profiles are compared with those predicted by a Navier-Stokes solver. Good agreement is found. 相似文献
86.
G. Principi A. Maddalena Ajay Gupta R. Dal Maschio S. Diré 《Hyperfine Interactions》1992,69(1-4):619-622
Conversion electron Mössbauer spectroscopy (CEMS) has been used to study tin oxide films prepared by sol-gel dipping and sputtering. The spectra of films prepared by sol-gel route result close to that of crystalline SnO2 after heat treatment at a temperature as low as 150°C. The Mössbauer parameters of as sputter deposited films indicate that the structure of the deposited stannic oxide has an amorphous character more pronounced for thinner samples. The structure becomes predominantly that of crystalline SnO2 by heating at 550°C for 30 min provided the film thickness is higher than 10 nm. 相似文献
87.
Summary. This paper introduces and analyzes the convergence properties of a method that computes an approximation to the invariant
subspace associated with a group of eigenvalues of a large not necessarily diagonalizable matrix. The method belongs to the
family of projection type methods. At each step, it refines the approximate invariant subspace using a linearized Riccati's
equation which turns out to be the block analogue of the correction used in the Jacobi-Davidson method. The analysis conducted
in this paper shows that the method converges at a rate quasi-quadratic provided that the approximate invariant subspace is
close to the exact one. The implementation of the method based on multigrid techniques is also discussed and numerical experiments
are reported.
Received June 15, 2000 / Revised version received January 22, 2001 / Published online October 17, 2001 相似文献
88.
89.
Marcel Erné 《Order》1991,8(2):159-173
We introduce a special type of order-preserving maps between quasiordered sets, the so-called cut-stable maps. These form the largest morphism class such that the corresponding category of quasiordered sets contains the category of complete lattices and complete homomorphisms as a full reflective subcategory, the reflector being given by the Dedekind-MacNeille completion (alias normal completion or completion by cuts). Suitable restriction of the object class leads to the category of separated quasiordered sets and its full reflective subcategory of completely distributive lattices. Similar reflections are obtained for continuous lattices, algebraic lattices, etc. 相似文献
90.
We prove global existence of solutions to the continuous nonhomogeneous Smoluchowski equation for coagulation rates satisfying a more general structure condition than the Galkin–Tupchiev monotony hypothesis considered in (Ph. Laurençot, S. Mischler, Arch. Rational Mech. Anal. 162 (1) (2002) 45–99). The Smoluchowski coagulation rate fulfils this condition as well as some rates which vanish on the diagonal. Under the condition of positivity of the coagulation rate outside of the diagonal we prove that solutions tend to 0 in the large time asymptotic. These results depend on a new estimate from below for the dissipation rate of the Lp-norm, p>1. To cite this article: S. Mischler, M. Rodriguez Ricard, C. R. Acad. Sci. Paris, Ser. I 336 (2003). 相似文献