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91.
Marcos V. dos S. Rezende Paulo J.R. Montes Mário E.G. Valerio 《Journal of luminescence》2012,132(5):1106-1111
The luminescence properties of Ce3+ in BaAl2O4 are reported. The results of simultaneous measurements of XEOL and XAS in the X-ray energy range that includes the Ba LII,III-edges and Ce LIII edge are shown. The XEOL yield increases as the energy of the photons increases. The radioluminescence spectra, taken from 200 to 1100 nm, showed broad emission bands corresponding to 5d1→2F5/2, 2F7/2 transitions of Ce3+ when incorporated into two nonequivalent Ba sites. The lifetime of the light emission was also measured using the single bunch operation mode at the Brazilian National Synchrotron Laboratory (LNLS), and BaAl2O4:Ce3+ showed single exponential decay time component of about 44.3 ns. 相似文献
92.
The main results of the extreme value theory developed for the investigation of the observables of dynamical systems rely,
up to now, on the block maxima approach. In this framework, extremes are identified with the block maxima of the time series
of the chosen observable, in the limit of infinitely long blocks. It has been proved that, assuming suitable mixing conditions
for the underlying dynamical systems, the extremes of a specific class of observables are distributed according to the so
called Generalised Extreme Value (GEV) distribution. Direct calculations show that in the case of quasi-periodic dynamics
the block maxima are not distributed according to the GEV distribution. In this paper we show that considering the exceedances
over a given threshold instead of the block-maxima approach it is possible to obtain a Generalised Pareto Distribution also
for extremes computed in systems which do not satisfy mixing conditions. Requiring that the invariant measure locally scales
with a well defined exponent—the local dimension—, we show that the limiting distribution for the exceedances of the observables
previously studied with the block maxima approach is a Generalised Pareto distribution where the parameters depend only on
the local dimensions and the values of the threshold but not on the number of observations considered. We also provide connections
with the results obtained with the block maxima approach. In order to provide further support to our findings, we present
the results of numerical experiments carried out considering the well-known Chirikov standard map. 相似文献
93.
94.
Silvia Coniglio Sandro Colagioia Fabrizio D'Alessandro Valerio D'Elia Valerie Orlando 《Tetrahedron letters》2004,45(28):5375-5378
A new, simple and efficient procedure for the preparation of secondary amides through internal condensation of acylmethanesulfonamides ammonium salts is described. The selective acylation of mixed primary-secondary amines could be an attractive application of the new method. 相似文献
95.
Supported by Comité Conjunto Hispano-Norteamericano and by NSF Grant #8120790 相似文献
96.
3-Benzyl-3-hydroxy-2-phenylphthalimidine ( 1 ) and 3-anilino-3-benzyl-2-phenylphthalimidine ( 2 ), the unusual adduct, are obtained from the title compounds. 3-Alkoxy-3-benzyl-2-phenylphthalimidines 3 are synthesized. The behaviour of 1 , 3-benzylidene-2-phenylphthalimidines ( 4 and 5 ), 3-(α-bromobenzylidene)-2-phenylphthalimidines ( 6 and 7 ) with respect to bases and the preparation of the open tautomer 13 of 1 and its hydrochloride are described. A hypothetical mechanism about the formation of 1 and 2 is suggested. 相似文献
97.
Stefaan Cottenier Veerle Vanhoof Doru Torumba Valerio Bellini Mehmet Çakmak Michel Rots 《Hyperfine Interactions》2004,158(1-4):9-18
For some years already, ab initio calculations based on Density Functional Theory (DFT) belong to the toolbox of the field of hyperfine interaction studies.
In this paper, the standard ab initio approach is schematically sketched. New features, methods and possibilities that broke through during the past few years
are listed, and their relation to the standard approach is explained. All this is illustrated by some highlights of recent
ab initio work done by the Nuclear Condensed Matter Group at the K.U.Leuven. 相似文献
98.
Kree Cole-McLaughlin Herbert Edelsbrunner John Harer Vijay Natarajan Valerio Pascucci 《Discrete and Computational Geometry》2004,32(2):231-244
Given a Morse function f over a 2-manifold with or without boundary,
the Reeb graph is obtained by contracting the connected components
of the level sets to points.
We prove tight upper and lower bounds on the
number of loops in the Reeb graph
that depend on the genus, the number of boundary components,
and whether or not the 2-manifold is orientable.
We also give an algorithm that constructs the Reeb graph in time
O(n log n), where n is the number of edges in the
triangulation used to represent the 2-manifold and the Morse function. 相似文献
99.
Giuliana Biagi Irene Giorgi Oreste Livi Valerio Scartoni Silvia Velo Antonio Lucacchini Generoso Senatore Pier Luigi Barili 《Journal of heterocyclic chemistry》1995,32(1):169-176
Several new 1,2,3-triazolo[4,5-b][1,4]diazepines were prepared starting from 1-benzyl-1 and 1-phenethyl-4,5-diamino-1,2,3-triazole 2 (Scheme 1), by condensation reactions with β-diketones (Scheme 2), β-ketoesters (Scheme 3), and diethyl malonates (Scheme 4). In the first case we obtained compounds 3 and 4 with basic properties, while the ester function condensations gave cyclic amide derivatives 7, 8, 10, 12 and 13 with acid properties. Some N-methyl derivatives 11, 14 and 15 were obtained from the cyclic amide compounds. Most of compounds were tested for their ability to displace [3H]flunitrazepam from bovine brain membranes but no compound showed benzodiazepine receptor binding affinity. 相似文献
100.
Giuliana Biagi Irene Giorgi Oreste Livi Antonio Nardi Valerio Scartoni 《Journal of heterocyclic chemistry》2002,39(6):1293-1298
Four new triazolylbenzimidazolthione derivatives (2a‐d), analogous to triazolylbenzimidazolone derivatives previously tested as activators of the BKCa potassium channels, were prepared and assayed without success. Some derivatives of a new tricyclic nitrogen heterocycle, 1,2,3‐triazolo[1,5‐a][1,3,5]benzo‐triazepine, bearing a carboxamido group in the 3 position, other substituents in the 8 position and a carbonyl (5a‐d) or thione (6a‐c) or methylthio (7a‐c) function in the 5 position were synthesised. The nucleophilic displacement of the methylthio substituent with morpholine or cyclopentylamine provided the 5‐amino‐substituted tricyclic derivatives 8a‐d. Starting from the l‐(2‐nitrophenyl)‐4‐cyano‐5‐amino‐1,2,3‐triazole (9), the 3‐cyano‐triazolobenzotriazepin‐5‐one derivative 12 was also obtained. The majority of the new compounds were tested towards the BKCa potassium channels, the benzodiazepine and adenosine A1 and A2a receptors, but no remarkable activity was detected. 相似文献