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381.
Samya S. Alenezi Naif D. Alenezi Godwin U. Ebiloma Manal J. Natto Marzuq A. Ungogo John O. Igoli Valerie A. Ferro Alexander I. Gray James Fearnley Harry P. de Koning David G. Watson 《Molecules (Basel, Switzerland)》2022,27(5)
Profiling a propolis sample from Papua New Guinea (PNG) using high-resolution mass spectrometry indicated that it contained several triterpenoids. Further fractionation by column chromatography and medium-pressure liquid chromatography (MPLC) followed by nuclear magnetic resonance spectroscopy (NMR) identified 12 triterpenoids. Five of these were obtained pure and the others as mixtures of two or three compounds. The compounds identified were: mangiferonic acid, ambonic acid, isomangiferolic acid, ambolic acid, 27-hydroxyisomangiferolic acid, cycloartenol, cycloeucalenol, 24-methylenecycloartenol, 20-hydroxybetulin, betulin, betulinic acid and madecassic acid. The fractions from the propolis and the purified compounds were tested in vitro against Crithidia fasciculata, Trypanosoma congolense, drug-resistant Trypanosoma congolense, Trypanosoma b. brucei and multidrug-resistant Trypanosoma b. brucei (B48). They were also assayed for their toxicity against U947 cells. The compounds and fractions displayed moderate to high activity against parasitic protozoa but only low cytotoxicity against the mammalian cells. The most active isolated compound, 20-hydroxybetulin, was found to be trypanostatic when different concentrations were tested against T. b. brucei growth. 相似文献
382.
383.
Sebastien Gibanel Valerie Heroguez Yves Gnanou Esteban Aramendia Alexander Bucsi Jacqueline Forcada 《先进技术聚合物》2001,12(8):494-499
Monodispersed polymer colloids with aldehyde and acetal functionalities, introduced by the macromonomer technique, were synthesized by a two‐step emulsion polymerization process. The latex samples so formed were chosen as the polymeric support to carry out covalent coupling with the antibody IgG anti‐C reactive protein, to test the utility of the latex–protein complexes formed in immunoassays. More than the 45% of the initially linked protein was covalently coupled in the acetal latex samples. Copyright © 2001 John Wiley & Sons, Ltd. 相似文献
384.
Stochastic epidemics and rumours on finite random networks 总被引:3,自引:0,他引:3
In this paper, we investigate the stochastic spread of epidemics and rumours on networks. We focus on the general stochastic (SIR) epidemic model and a recently proposed rumour model on networks in Nekovee et al. (2007) [3], and on networks with different random structures, taking into account the structure of the underlying network at the level of the degree–degree correlation function. Using embedded Markov chain techniques and ignoring density correlations between neighbouring nodes, we derive a set of equations for the final size of the epidemic/rumour on a homogeneous network that can be solved numerically, and compare the resulting distribution with the solution of the corresponding mean-field deterministic model. The final size distribution is found to switch from unimodal to bimodal form (indicating the possibility of substantial spread of the epidemic/rumour) at a threshold value that is higher than that for the deterministic model. However, the difference between the two thresholds decreases with the network size, n, following a n−1/3 behaviour. We then compare results (obtained by Monte Carlo simulation) for the full stochastic model on a homogeneous network, including density correlations at neighbouring nodes, with those for the approximating stochastic model and show that the latter reproduces the exact simulation results with great accuracy. Finally, further Monte Carlo simulations of the full stochastic model are used to explore the effects on the final size distribution of network size and structure (using homogeneous networks, simple random graphs and the Barabasi–Albert scale-free networks). 相似文献
385.
Laura A. Rusch‐Salazar Valerie V. Sheares 《Journal of polymer science. Part A, Polymer chemistry》2003,41(14):2277-2287
A new series of high‐performance poly(arylene phosphine oxide) (PAPO) materials were synthesized postpolymerization from fluorinated poly(arylene phosphine oxide) (f‐PAPO). The new materials had increased solubility and film‐forming ability over the parent f‐PAPO. With the careful choice of the nucleophile, the thermal stability was also increased. The parent polymer f‐PAPO was synthesized via Ni(0) coupling from aromatic chloride and mesylate monomers. Both monomers were polymerized successfully to create polymers with intrinsic viscosities of 0.235 and 0.123 dL/g, respectively. The higher molecular weight f‐PAPO gave a glass transition of 320 °C and a char yield of 54% at 650 °C in air. The substitution of f‐PAPO via nucleophilic aromatic substitution produced PAPO thermoplastics with significant changes in the properties. The largest increase in the thermal stability relative to f‐PAPO was from 563 to 600 °C 10% weight‐loss values in nitrogen after the displacement of fluoride by 4‐aminophenol, which yielded poly[4‐(4‐aminopheonxyphenyl)bis(4′‐phenyl)phosphine oxide]. Additionally, the char yield increased from 54 to 71% in air at 650 °C. The solubility of the parent polymer was improved after substitution with 3‐tert‐butylphenol, n‐nonylamine, and poly(ethylene glycol)monomethyl ether. All of these became soluble in chloroform, N,N‐dimethylacetamide, and dimethyl sulfoxide. Copolymers were synthesized with 2,5‐dichloro‐4′‐fluorobenzophenone to improve the solubility of f‐PAPO without the loss of thermal stability. These copolymers also underwent nucleophilic aromatic substitution to create an epoxy cure agent that was used with the DEN 431 resin. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 2277–2287, 2003 相似文献
386.
Summary In a recent paper, [4], Csordas and Varga have unified and extended earlier theorems, of Varga in [10] and Wonicki in [11], on the comparison of the asymptotic rates of convergence of two iteration matrices induced by two regular splittings. The main purpose of this note is to show a connection between the Csordas-Varga paper and a paper by Beauwens, [1], in which a comparison theorem is developed for the asymptotic rate of convergence of two nonnegative iteration matrices induced by two splittings which are not necessarily regular. Monotonic norms already used in [1] play an important role in our work here.Research supported in part by NSF grant number DMS-8400879 相似文献
387.
J. P. Guenier P. Simon J. Delcourt M. F. Didierjean C. Lefevre J. Muller 《Chromatographia》1984,18(3):137-144
Summary After a brief review of several methods described in the literature this paper discusses air-sampling on 2,4-dinitrophenylhydrazine-coated silica gel and identification requirements for aldehydes and ketones most commonly found in industrial pollution.Quantitative analysis of formaldehyde and acetaldehyde either by GC or by HPLC techniques is established using a dynamic system producing test atmospheres and compared with the usual colorimetric determinations. 相似文献
388.
James Hunt Selby A. R. Knox Valerie Oliphant 《Journal of organometallic chemistry》1974,80(3):C50-C52
Trithiocarbonate complexes are formed when metal carbonyl anions are treated consecutively with carbon disulphide and a neutralising agent such as methyl iodide or Re(CO)5 Br. 相似文献
389.
Deanne L. Snavely Valerie A. Walters Steven D. Colson Kenneth B. Wiberg 《Chemical physics letters》1984,103(5):423-429
The 700 and 3050 cm?1 region of benzene seeded in argon is studied using Fourier-transform infrared absorption spectroscopy. Analysis of the sequence band structure in the 700 cm?1 region gave new anharmonic constants and values of Trot (79 ± 15 K) and Tvib (/2~160 K) which indicate a disequilibrium between the rotational and vibrational degrees of freedom. A band contour analysis of the 3050 cm?1 Fermi triad is used to obtain new values of the Coriolis coupling constants and band origins. 相似文献
390.
A versatile method for tuning the chemistry and size of nanoscopic features by living free radical polymerization 总被引:2,自引:0,他引:2
von Werne TA Germack DS Hagberg EC Sheares VV Hawker CJ Carter KR 《Journal of the American Chemical Society》2003,125(13):3831-3838
A novel approach is presented for manipulating the size and chemistry of nanoscopic features using a combination of contact molding and living free radical polymerization. In this approach a highly cross-linked photopolymer, based on a methacrylate/acrylate mixture, was patterned into submicrometer-sized features on a silicon wafer using a contact-molding technique. A critical component of the monomer mixture was the incorporation of an initiator containing monomer into the network structure, which provides sites for functional group amplification. Features ranging in size from 5 microm to <60 nm were accurately replicated by this process and living free radical polymerizations, both atom transfer radical and nitroxide-mediated polymerization (NMP), could be conducted from these initiating sites to yield polymer brushes which represent a grafted layer of linear chains attached to the original network polymer. Grafts consisting of polystyrene, poly(methyl methacrylate), and poly(2-hydroxyethyl)methacrylate were grown with controlled thicknesses ranging from 10 to 143 nm and graft molecular weights of between 18 000 to 290 000 amu. As a result of this secondary graft process, feature sizes could be tuned from the original 100 nm down to 20 nm, and the surface chemistry varied from hydrophilic to hydrophobic starting from the same initial master pattern. The thin films and patterned features were characterized by contact angle, ellipsometry, optical, and atomic force microscopies. 相似文献