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111.
Santiago A. Pighín Sergio A. Cannas 《Journal of magnetism and magnetic materials》2010,322(24):3889-3894
We present the complete zero temperature phase diagram of a model for ultrathin films with perpendicular anisotropy. The whole parameter space of relevant coupling constants is studied in first order anisotropy approximation. Because the ground state is known to be formed by perpendicular stripes separated by Bloch walls, a standard variational approach is used, complemented with specially designed Monte Carlo simulations. We can distinguish four regimes according to the different nature of striped domains: a high anisotropy Ising regime with sharp domain walls, a saturated stripe regime with thicker walls inside which an in-plane component of the magnetization develops, a narrow canted-like regime, characterized by a sinusoidal variation of both the in-plane and the out of plane magnetization components, which upon further decrease of the anisotropy leads to an in-plane ferromagnetic state via a spin reorientation transition (SRT). The nature of domains and walls are described in some detail together with the variation of domain width with anisotropy, for any value of exchange and dipolar interactions. Our results, although strictly valid at T=0, can be valuable for interpreting data on the evolution of domain width at finite temperature, a still largely open problem. 相似文献
112.
Daniele Fazzi Eleonora Valeria Canesi Chiara Bertarelli Chiara Castiglioni Fabrizia Negri Giuseppe Zerbi 《Journal of Raman spectroscopy : JRS》2010,41(4):406-413
A combined theoretical and experimental Raman study is presented on a diphenyl bithiophene molecule known as a good candidate for the development of organic nonvolatile memory devices. Spectroscopic markers suitable to distinguish the different stable conformers of the molecule have been predicted and detected. The combined analysis of theoretical and experimental Raman spectra recorded in solution indicates that at room temperature a dynamical equilibrium, characterized by interconversion between the two more stable conformers (namely trans and cis), takes place and that the more populated species is the cis form. Referring to the solid phase instead, Raman spectra of single‐crystal samples show the presence of the only trans conformer, as confirmed by X‐ray measurements. Finally, Raman spectra of thin films, as those used for the memory device, were collected; samples just deposited from solution and after few hours from the deposition were analyzed. Following the evolution of selective spectroscopic Raman markers, an isomerization process from the abundant cis (as‐deposited) to the totally trans (after few hours) conformer in the solid phase was detected. These results open the way to the identification of the molecular isomers present in the thin film of the memory cell and finally of the active molecular species involved in the switching mechanism of the operating device. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
113.
This paper discusses the computation of real \(\mathtt {Z}\)-eigenvalues and \(\mathtt {H}\)-eigenvalues of nonsymmetric tensors. A generic nonsymmetric tensor has finitely many Z-eigenvalues, while there may be infinitely many ones for special tensors. The number of \(\mathtt {H}\)-eigenvalues is finite for all tensors. We propose Lasserre type semidefinite relaxation methods for computing such eigenvalues. For every tensor that has finitely many real \(\mathtt {Z}\)-eigenvalues, we can compute all of them; each of them can be computed by solving a finite sequence of semidefinite relaxations. For every tensor, we can compute all its real \(\mathtt {H}\)-eigenvalues; each of them can be computed by solving a finite sequence of semidefinite relaxations. 相似文献
114.
Nuvoli Daniele Alzari Valeria Sanna Roberta Scognamillo Sergio Alongi Jenny Malucelli Giulio Mariani Alberto 《Journal of nanoparticle research》2013,15(3):1-8
In this paper, GaN nanoparticles were synthesized from the complex Ga(H2NCONH2)6Cl3 in the flow of NH3 at a mild temperature (350 °C). Further purification was performed by the ethanol-thermal method. The ethanol-thermal method also prompted the GaN nanoparticles to grow into an anisotropic morphology. XRD patterns reveal that GaN nanoparticles have crystallized in a hexagonal wurtzite structure. TEM observation shows that the average size of the as-prepared nanoparticles is about 5–10 nm. The photoluminescence spectrum exhibits a broad green emission band with a peak at 510 nm. It can be known from the first-principle theoretic simulation by the TDDFT method that this fluorescence emission band is attributed to the hydride defects of V N-H on the surface of GaN nanoparticles. 相似文献
115.
We consider the mass-critical focusing nonlinear Schrödinger equation in the presence of an external potential, when the nonlinearity is inhomogeneous. We show that if the inhomogeneous factor in front of the nonlinearity is sufficiently flat at a critical point, then there exists a solution which blows up in finite time with the maximal (unstable) rate at this point. In the case where the critical point is a maximum, this solution has minimal mass among the blow-up solutions. As a corollary, we also obtain unstable blow-up solutions of the mass-critical Schrödinger equation on some surfaces. The proof is based on properties of the linearized operator around the ground state, and on a full use of the invariances of the equation with an homogeneous nonlinearity and no potential, via time-dependent modulations. 相似文献
116.
In this work, we studied the influence of time reaction and initiator amount on N-(1-naphthyl)acrylamide (NAM) polymerization, in dioxane and DMF. The same was done with three copolymers with methyl methacrylate (MMA). We found that NAM could be incorporated in high proportions in the copolymer. We also found that, with the same reaction time, the amount of benzoyl peroxide (BPO) has little or no effect on the polymerization degree; however reaction rates and yields were affected in DMF. All homopolymers showed a low dispersion (?), even when they were polymerized in solution. All DPNAMs can be classified as monodisperse. 相似文献
117.
Valeria Kagramanova Jutta Kunz Claus Lämmerzahl 《General Relativity and Gravitation》2008,40(6):1249-1278
Orbits of test particles and light rays are an important tool to study the properties of space-time metrics. Here we systematically
study the properties of the gravitational field of a globally regular magnetic monopole in terms of the geodesics of test
particles and light. The gravitational field depends on two dimensionless parameters, defined as ratios of the characteristic
mass scales present. For critical values of these parameters the resulting metric coefficients develop a singular behavior,
which has profound influence on the properties of the resulting space-time and which is clearly reflected in the orbits of
the test particles and light rays. 相似文献
118.
Valentina Noemi Madia Daniela De Vita Davide Ialongo Valeria Tudino Alessandro De Leo Luigi Scipione Roberto Di Santo Roberta Costi Antonella Messore 《Molecules (Basel, Switzerland)》2021,26(15)
Growing attention to environmental protection leads food industries to adopt a model of “circular economy” applying safe and sustainable technologies to recover, recycle and valorize by-products. Therefore, by-products become raw material for other industries. Tomato processing industry produces significant amounts of by-products, consisting of skins and seeds. Tomato skin is very rich in lycopene, and from its seeds, high nutritional oil can be extracted. Alternative use of the two fractions not only could cut disposal costs but also allow one to extract bioactive compounds and an oil with a high nutritional value. This review focused on the recent advance in extraction of lycopene, whose beneficial effects on health are widely recognized. 相似文献
119.
Efficient sustainable V-catalyzed oxidative desulfurization of fuels assisted by ionic liquids 《燃料化学学报》2018,46(9):1121-1129
Fuel desulfurization is an appealing topic for the chemical industry since severe environmental regulations regarding SO2 emissions have been legislated in many countries. In order to reduce the amount of sulfur-containing compounds in fuels, responsible for high SOx emission levels, a green chemistry approach is compulsory. In this paper, vanadium salen and salophen complexes were used in the oxidation of a model aromatic sulfide, such as dibenzothiophene (DBT), in the presence of H2O2 as green oxidant. The oxidative process was successfully coupled with the extraction of the oxidized compounds by ionic liquids. The system resulted highly selective for sulfide oxidation, showing poor reactivity toward the oxidation of alkenes and allowing a significant reduction of S content in a model benzine. To note, the use of microwave in place of standard heating allowed to obtain 98% of DBT oxidation and almost complete sulfur extraction in the model fuel in 1000 s. For these reasons, this system was considered an easy, rapid and clean process to achieve fuel desulfurization. 相似文献
120.
We give necessary and sufficient conditions for the Kurzweil–Henstock integrability of functions given by , where xn belong to a Banach space and the sets (En)n are measurable and pairwise disjoint. Also weakly completely continuous operators between Banach spaces are characterized by means of scalarly Kurzweil–Henstock integrable functions. 相似文献