Structural and compositional stability of Co oxide grown on (001) bct Co

Room temperature (RT) adsorption of oxygen on the (001) surface of metastable, cubic Co film epitaxially grown on a Fe substrate results in the formation of about 7 monolayers (ML) crystalline CoO film, in the typical rocksalt structure 45° rotated with respect to the square unit mesh of the underlying Co film. We investigated the stability of this oxide layer upon annealing in the RT–620 K temperature range, by means of primary-beam diffraction modulated electron emission (PDMEE), and X-ray photoelectron spectroscopy (XPS). For temperatures up to 570 K, film thickness and local order are preserved, in spite of an increasing number of Co and O atoms bonded in sites of reduced coordination. For larger temperatures, thickness also reduces, but the oxide film is still characterized by a high degree of CoO-like local order.     

Spectral broadening of continuous-wave monochromatic pump radiation caused by stimulated Brillouin scattering in optical fiber

We experimentally show that, when stimulated Brillouin scattering is generated in optical fiber by use of monochromatic cw pump radiation, the transmitted pump radiation exhibits spectral broadening that is much narrower than the classical homogeneous gain-narrowed Brillouin bandwidth. The bandwidth is practically independent of the pump strength, fiber characteristics, and the waveguide-induced inhomogeneously broadened bandwidth of the Stokes emission. We show that these properties arise from strong parametric coupling of the Stokes and pump signals in the pump-depletion region.     

On impulsive functional differential inclusions with Hille-Yosida operators in Banach spaces

We consider a semilinear functional differential inclusion with infinite delay and impulse characteristics in a Banach space assuming that its linear part is a non-densely defined Hille-Yosida operator. We assume that the multivalued nonlinearity of upper Carathèodory or almost lower semicontinuous type satisfies a regularity condition expressed in terms of the measures of noncompactness. We apply the theory of integrated semigroups and the theory of condensing multivalued maps to obtain local and global existence results. The application to an optimization problem for an impulsive feedback control system is given.     

Fast-switching effect using viscous chiral-nematic materials

We report on chiral-nematic mixtures containing viscous chiral dopants, composed of rigid rod-like chiral molecules, in order to solve the problem of backflow in the middle layers of the liquid crystal cells. During the study, the viscoelastic properties of the liquid crystal compositions have been optimised, as well as the helical twisting power of the chiral compounds, the anchoring energy and the pre-tilt angle of alignment materials, the ratio between the cell gap and the helical pitch (d/P₀). After optimisation, we prepared test cells with low operating voltage – from 1.5 till 5.0 V, fast response time (τ_on + τ_off) – less than 1 ms, wide operating temperature range from ?40°C till +100°C, and good thermal stability. It should be noted that the response time of the new electro-optical mode does not strongly depend on the cell gap, which is in contrast to other known operating modes. We have achieved rather linear than quadratic dependence of the response time when changing the thickness of the cell.     

Oxidation behaviour of nickel silicides investigated by AES and XPS

The oxygen interaction with Ni silicide surfaces in a wide range of composition, from NiSi₂ to Ni₃Si, has been investigated at room temperature by AES and XPS techniques. It has been found that the Si oxidation is enhanced over that of pure Si in all the Ni-Si compounds, and that the strongest oxidation occurs in Ni richer silicides. In general, oxygen bonds with Si leaving the metal unoxidized, but in Ni₃Si evidence for the occurrence of Ni oxidation has been found at high exposures.     

Guiding functions and periodic solutions for inclusions with causal multioperators

In the present paper, the method of guiding functions is applied to study the periodic problem for a differential inclusion with a causal multioperator. At first we consider the case when the multioperator is closed and convex-valued. Then the case of a non-convex-valued and lower semicontinuous right-hand part is considered. Thereafter, the theory is extended to the case of non-smooth guiding functions.     

A Lax type operator for quantum finite W-algebras

Selecta Mathematica - For a reductive Lie algebra $$mathfrak {g}$$ , its nilpotent element f and its faithful finite dimensional representation, we construct a Lax operator L(z) with coefficients...     

Phenomenological model of chain-branching premixed flames

In this work, we introduce a global kinetic model that includes fuel, oxygen, products and two radical species involved in the reversible chain-branching, chain-propagation and chain-termination reactions. The model naturally extends the Zeldovich–Liñán and Zeldovich–Barenblatt–Dold models and can be used to describe both premixed and diffusion flames. Here it is applied to the problem of the deflagration wave propagation in the hydrocarbon fuel/air mixture with arbitrary equivalence ratio under the simplifying thermal-diffusive approximation. The conservation equations are solved numerically in order to obtain the velocity and structure of the combustion wave. It is demonstrated that the peak values of the adiabatic flame temperature and deflagration velocity are shifted towards the rich mixture composition if the reverse reactions of product decomposition are taken into account. The dependence of the flame speed and temperature on parameters of the system is analysed. The prospects of further investigation are discussed.