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11.
Determination of abamectin in citrus fruits by liquid chromatography-electrospray ionization mass spectrometry 总被引:4,自引:0,他引:4
Liquid chromatography coupled to electrospray mass spectrometry (LC-ES-MS) with positive ion detection was used to determine abamectin in oranges. MS conditions were optimized to achieve maximum sensitivity. The main ion for abamectin was [M+Na]+ at a fragmentor voltage of 180 V. Abundant structural information can be obtained at different fragmentor voltages. The detection limit for the standard solution was 12 pg injected, and good linearity and reproducibility were observed. Abamectin residues were extracted using matrix solid-phase dispersion. Orange samples were homogenized with C18 bonded silica placed onto a glass column and eluted with dichloromethane. Recoveries of the abamectin from oranges fortified with approximately 0.01-10 mg/kg ranged from 94 to 99% with an overall average recovery of 96%. The quantification limit is 0.0025 mg/kg, which means detection limit for this analyte could be set at a few hundred picograms per gram of fruit. The presence in the electrosprayed solution of numerous citrus constituents did not interfere significantly with the ionization process of abamectin. The assay procedure provides a simple, rapid, and sensitive method for monitoring residues in oranges. The method was applied to field treatment orange samples. 相似文献
12.
P. Paasche C. Angelescu S. Ananthamurthy D. Biswas T. Valenzuela G. Werth 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2003,22(2):183-188
We have measured the storage instabilities of electrons in a Penning trap at low magnetic fields. These measurements are carried
out as a function of the trapping voltage, for different magnetic fields. It is seen that these instabilities occur at the
same positions when the trapping voltage is expressed as a percentage of the maximum voltage, given by the stability limit.
The characteristic frequencies at which these instabilities occur, obey a relation that is given by n
zω
z + n
+ω
+ + n
-ω
- = 0, where ω
z, ω
+ and ω
- are the axial, perturbed cyclotron and the magnetron frequencies of the trapped electrons respectively, and the n's are integers. The reason for these instabilities are attributed to higher order static perturbations in the trapping potential.
Received 5 August 2002 / Received in final form 14 October 2002 Published online 17 December 2002
RID="a"
ID="a"Present address: Dept. of Physics, Rampurhat College, Rampurhat, Birbhum, West Bengal, India.
RID="b"
ID="b"e-mail: werth@mail.uni-mainz.de 相似文献
13.
We report on marked memory effects in the vortex system of twinned YBa2Cu3O7 single crystals observed in ac susceptibility measurements. We show that the vortex system can be trapped in different metastable states with variable degree of order arising in response to different system histories. The pressure exerted by the oscillating ac field assists the vortex system in ordering, locally reducing the critical current density in the penetrated outer zone of the sample. The robustness of the ordered and disordered states together with the spatial profile of the critical current density lead to the observed memory effects. 相似文献
14.
Lesley A. Chesson Luciano O. Valenzuela Gabriel J. Bowen Thure E. Cerling James R. Ehleringer 《Rapid communications in mass spectrometry : RCM》2011,25(24):3713-3722
Published datasets of proteinaceous animal tissues suggest that co‐variation between amino acid hydrogen (δ2H) and oxygen (δ18O) isotope ratios is a common feature in systems where isotopic variation is driven by geographic or temporal variation in the δ2H and δ18O values of environmental water. This has led to the development of models relating tissue δ2H and δ18O values to those of water, with potential application in a number of fields. However, the strength and ubiquity of the influence of environmental water on protein isotope ratios across taxonomic groups, and thus the relevance of predictive models, is an open question. Here we report strong co‐variation of δ2H and δ18O values across a suite of terrestrial and aquatic animal meats purchased in American food markets, including beef, poultry (chicken and turkey), chicken eggs, pork, lamb, freshwater fish, and marine fish. Significant isotope co‐variation was not found for small collections of marine bivalves and crustaceans. These results imply that isotopic signals from environmental water were propagated similarly through most of the diverse natural and human‐managed foodwebs represented by our samples. Freshwater fish had the largest variation in δ2H and δ18O values, with ranges of 121 ‰ and 19.2 ‰, respectively, reflecting the large isotopic variation in environmental freshwaters. In contrast marine animals had the smallest variation for both δ2H (7 ‰ range, crustaceans) and δ18O (3.0 ‰ range, bivalves) values. Known‐origin beef samples demonstrated direct relationships between the variance of environmental water isotope ratios and that of collected meats. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
15.
The protected ceramide: N‐((2S,3S,4R)‐3,4‐bis(benzyloxy)‐1‐hydroxyoctadecan‐2‐yl)tetracosanamide, was attempted to introduce a triflate as a leaving group followed by a nucleophilic substitution with azido group in one‐pot manner. Unexpectedly, the oxazole ring formed via a thermodynamically favored intramolecular cyclization was opened to generate the original ceramide by triflic acid. In addition, the residual acid promoted a formylation of the primary hydroxy group in DMF. 相似文献
16.
Christine L. Valenzuela 《Journal of Heuristics》2001,7(1):5-21
The genetic algorithm (GA) described in this paper breeds permutations of transmitters for minimum span frequency assignment. The approach hybridizes a GA with a greedy algorithm, and employs a technique called Generalized Saturation Degree to seed the initial population. Several permutation operators from the GA literature are compared, and results indicate that position based operators are more appropriate for this kind of problem than are order based operators. My offspring versus mid-parent correlation studies on crossovers show Pearson's correlation coefficient to be a reliable predictor of performance in most cases. Results presented herein represent improvements over previously published results. 相似文献
17.
R. Valenzuela G. Alvarez H. Montiel M.P. Gutirrez M.E. Mata-Zamora F. Barrn A.Y. Snchez I. Betancourt R. Zamorano 《Journal of magnetism and magnetic materials》2008,320(14):1961-1965
A low-field non-resonant microwave absorption has recently been observed in a variety of magnetically ordered materials at low DC fields (−1000 Oe HDC+1000 Oe), which is known as low-field microwave absorption (LFA). It has been shown that LFA is essentially similar to giant magnetoimpedance (GMI), and clearly different from ferromagnetic resonance (FMR). LFA strongly depends on the anisotropy field of the sample. In contrast with FMR (which can be described as the homogeneous precession of spins in the saturated state), LFA can be thought as a spin rotation process occurring during the magnetic saturation. In this work, we present a detailed study of the basic features of LFA in several types of materials: ferrites and amorphous microwires and ribbons; in particular the effects sample shape, temperature up to the Curie transition, the influence of easy axis and the effects of annealings. These examples show that once LFA is fully understood, it can become a powerful characterization tool. 相似文献
18.
19.
20.
The unpinning or propagation field, hp, where domain walls are unpinned and start their displacement under the AC magnetic field of as-cast amorphous wires of nominal composition (Co94Fe6)72.5B15Si12.5, was determined for each torsion angle between –90° (counterclockwise) and +150° (clockwise) at a constant frequency of 1 kHz. A plot of hp as a function of torsion angle showed a sharp minimum at a torsion angle of +120. The results are interpreted in terms of the counterbalance effect of the torsion against the intrinsic helical anisotropy induced during the wire fabrication. 相似文献