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131.
The CIMPA Research School on Mathematical Models for Security Applications was dedicated to the memory of Emeritus Professor Mirka Miller, who suggested that it be held in Havana. Mirka Miller, member of the editorial board of Mathematics in Computer Science, devoted her research to Graph Theory and Data Security, fields where she made important and beautiful contributions. 相似文献
132.
Busini V Moiani D Moscatelli D Zamolo L Cavallotti C 《The journal of physical chemistry. B》2006,110(46):23564-23577
The influence of the spacer arm on the interaction between agarose and a supported ligand was investigated through molecular dynamics for a combination of several spacers. The spacers differ for degree of hydrophobicity, length, and chemical composition, which was varied through insertion of thio, ether, and CH(2) groups. Agarose was modeled through a modified Glycam force field, whose parameters were determined through ab initio calculations. The structural model of agarose used for the calculations was obtained through MD studies of the conformational evolution of several agarose single and double helixes. The simulations showed that a modification of the spacer properties could determine a change of the stable structure of the ligand with respect to the support. In particular, if the spacer is hydrophilic and rigid, the favored structure is with extended spacer and solvated ligand. Either increasing the spacer length, and thus its flexibility, or decreasing its solvation free energy, which corresponds to diminishing its affinity for water, rapidly leads to a conformational change in which the ligand adsorbs on agarose. Interestingly, we found that if the spacer is long and hydrophilic, a third metastable structure, in which the spacer is sandwiched between the ligand and agarose, is possible. Simulations of several ligands adsorbed on neighboring sites on agarose showed that if the support is not held fixed through restraints, the interaction force between vicinal ligands is sufficient to determine a major conformational change of the system. 相似文献
133.
Rumyana Djingova Veronika Mihaylova Valentina Lyubomirova Dimiter L. Tsalev 《应用光谱学评论》2013,48(5):384-424
Abstract: The study of the ionome (ionomics) is defined as quantitative and simultaneous measurement of the element composition of living organisms and changes in this composition in response to physiological stimuli, development stage, and genetic modifications (Salt et al., Ann. Rev. Plant Biol., Vol. 59, 2008). The necessity of understanding the regulation processes of elements in the organisms demands determination of many elements in the organism, tissue, and cell (Baxter, Plant Biol., Vol. 12, 2009). A prospect for ionomics is environmental pollution where great variety of conditions and pollutants exist resulting in concentration and interelemental changes in the plant ionome. The capabilities of and problems with several multielement analytical techniques, including instrumental neutron activation analysis (INAA), X-ray fluorescence, inductively coupled plasma–atomic emission spectrometry (ICP-AES), inductively coupled plasma–mass spectrometry (ICP-MS), and atomic absorption spectrometry (AAS), which are adequate and most promising in ionomic and environmental studies of plants, are reviewed. References are confined mainly to the last 10–15 years. Information about concentrations, roles, binding forms, and pollution sources of the elements and comparison between methods with respect to limits of detection, determined elements, interferences, and economic considerations are tabulated. Some combinations of instrumental techniques supplementing each other are highly valued, namely, ICP-MS and ICP-AES and INAA and AAS or ICP-AES. 相似文献
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Valentina Noemi Madia Daniela De Vita Davide Ialongo Valeria Tudino Alessandro De Leo Luigi Scipione Roberto Di Santo Roberta Costi Antonella Messore 《Molecules (Basel, Switzerland)》2021,26(15)
Growing attention to environmental protection leads food industries to adopt a model of “circular economy” applying safe and sustainable technologies to recover, recycle and valorize by-products. Therefore, by-products become raw material for other industries. Tomato processing industry produces significant amounts of by-products, consisting of skins and seeds. Tomato skin is very rich in lycopene, and from its seeds, high nutritional oil can be extracted. Alternative use of the two fractions not only could cut disposal costs but also allow one to extract bioactive compounds and an oil with a high nutritional value. This review focused on the recent advance in extraction of lycopene, whose beneficial effects on health are widely recognized. 相似文献
136.
Riccardo Adami Ugo Boscain Valentina Franceschi Dario Prandi 《Annales de l'Institut Henri Poincaré (C) Analyse Non Linéaire》2021,38(4):1095-1113
In this paper we show that, for a sub-Laplacian Δ on a 3-dimensional manifold M, no point interaction centered at a point exists. When M is complete w.r.t. the associated sub-Riemannian structure, this means that Δ acting on is essentially self-adjoint in . A particular example is the standard sub-Laplacian on the Heisenberg group. This is in stark contrast with what happens in a Riemannian manifold N, whose associated Laplace-Beltrami operator acting on is never essentially self-adjoint in , if . We then apply this result to the Schrödinger evolution of a thin molecule, i.e., with a vanishing moment of inertia, rotating around its center of mass. 相似文献
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Propylphosphonic anhydride (T3P®) was successfully applied to the synthesis of an isoindolinone library by the utilization of an Ugi four-center, three-component reaction (Ugi-4C-3CR). The use of T3P® significantly shortened the required reaction time and the corresponding products were obtained in good to high yields. Moreover, a side-reaction was observed when phenylethylamine derivatives and tryptamine were used as the amine component. The latter reaction was applied to the microwave-assisted, one-pot synthesis of the isoquinoline alkaloid (±)-nuevamine. Surprisingly, the traditional Ugi four-component reaction (Ugi-4CR) was unsuccessful in the presence of T3P®. In this case an α-amino amide was produced excluding the carboxylic acid from the multicomponent reaction. 相似文献