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Menon S Vaidya H Pillai S Vidya R Mitscher LA 《Combinatorial chemistry & high throughput screening》2003,6(5):471-480
A solution phase strategy for the multiple parallel synthesis of a demonstration library of indazoles is described by which regio-selectivity problems inherent to previous syntheses of this nucleus are largely overcome. Synthesis of selected components proceeded satisfactorily indicating that a fully realized library of indazole analogs could readily be produced using this methodology. Simple modifications of the basic nucleophilic aromatic substitution route unambiguously produce a range of N-1 substitutions (alkyl, aryl and aralkyl) in 50-75% yields. Next a range of substituents was introduced at the C-3 position in 50-80% yields by O-alkylation. Careful choice of reagents and reaction conditions were required to prevent by-product formation due to competing alkylation at N-2 (trace to 15% yields). When present, these contaminants were readily removed by chromofiltration. A third diversity site was sketched in at C-5 in 75-90% yield by reductive alkylation or acylation. Screening of some of the demonstration library members in vitro revealed highly active antioxidants suggesting that producing a full library would be worthwhile. 相似文献
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Nayan Patel Mehmet Krta Vaidya Sankaran Suresh Menon 《Proceedings of the Combustion Institute》2007,31(2):2327-2334
Large-eddy simulation (LES) of a liquid-fueled lean-direct injection (LDI) combustor is carried out by resolving the entire inlet flow path through the swirl vanes and the combustor. A localized dynamic subgrid closure is combined with a subgrid mixing and combustion model so that no adjustable parameters are required for both non-reacting and reacting LES. Time-averaged velocity predictions compare well with the measured data. The unsteady flow features that play a major role in spray dispersion, fuel–air mixing and flame stabilization are identified from the simulation data. It is shown that the vortex breakdown bubble (VBB) is smaller with more intense reverse flow when there is heat release. The swirling shear layer plays a major role in spray dispersion and the VBB provides an efficient flameholding mechanism to stabilize the flame. 相似文献
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A systematic study on the water-intake capacity of the microemulsion formed using a catanionic surfactant (synthesized by taking equimolar mixture of acid and amine) with varying hydrocarbon chain length of the acid has been carried out. A decrease in the water-intake capacity with increase in the chain length was observed. Shorter chain length of co-surfactant (1-butanol compared to 1-octanol) led to higher water-intake capacity of microemulsions which may also be attributed to the high hydrophilic-lipophilic balance (HLB) of 1-butanol. Three new microemulsions based on catanionic surfactants have been used to synthesize quantum dots of CdS. The size of CdS quantum dots decreased with increase in chain length of the acid component of the catanionic surfactant. 相似文献
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Vaidya T Manbeck GF Chen S Frontier AJ Eisenberg R 《Journal of the American Chemical Society》2011,133(10):3300-3303
In contrast to 2-substituted pyrrole enones, furyl and benzofuryl enones do not undergo the Nazarov electrocyclization. Instead, these furyl and benzofuryl enones exhibit unusual rearrangement sequences in the presence of catalytic amounts of [IrBr(CO)(DIM)((R)-(+)-BINAP)](SbF(6))(2) (1; DIM = diethylisopropylidene malonate) and AgSbF(6) (1:1). A 1,2-H shift followed by intramolecular Friedel-Crafts alkylation leads to synthetically valuable cyclohexanones with furanylic quaternary centers. The electrophilicity of 1 is essential for this rearrangement. 相似文献