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111.
A numerical analysis of convective drying of a 3D porous solid of brick material is carried out using the finite element method
and mass lumping technique. The energy equation and moisture transport equations for the porous solid are derived based on
continuum approach following Whitaker’s theory of drying. The governing equations are solved using the Galerkin’s weighted
residual method, which convert the governing equations into discretized form of matrix equations. The resulting capacitance
matrices are made diagonal matrices by following the classical row-sum mass lumping technique. Hence with the use of the Eulerian
time marching scheme, the final equations are reduced to simple algebraic equations, which can be solved directly without
using an equation solver. The proposed numerical scheme is initially validated with experimental results for 1D drying problem
and then tested by application to convective drying of 3D porous solid of brick material for four different aspect ratios
obtained by varying the cross section of the solid. The mass lumping technique could correctly predict the wet bulb temperature
of the solid under evaporative drying conditions. A parametric study carried out for three different values of convective
heat transfer coefficients, 15, 30 and 45 W/m2 K shows an increased drying rate with increase in area of cross section and convective heat transfer coefficient. The proposed
numerical scheme could correctly predict the drying behavior shown in the form of temperature and moisture evolutions. 相似文献
112.
Murugesan Rajadurai Ayyapparaj Muthuchamy A. Raja Annamalai Dinesh K. Agrawal Chun-Ping Jen 《Molecules (Basel, Switzerland)》2021,26(10)
The effect of molybdenum additions on the phases, microstructures, and mechanical properties of pre-alloyed Ti6Al4V was studied through the spark plasma sintering technique. Ti6Al4V-xMo (where x = 0, 2, 4, 6 wt.% of Mo) alloys were developed, and the sintered compacts were characterized in terms of their phase composition, microstructure, and mechanical properties. The results show that the equiaxed primary alpha and Widmänstatten (alpha + beta) microstructure in pre-alloyed Ti6Al4V is transformed into a duplex and globular model with the increasing content of Mo from 0 to 6%. The changing pattern of the microstructure of the sample strongly influences the properties of the material. The solid solution hardening element such as Mo enhances mechanical properties such as yield strength, ultimate tensile strength, ductility, and hardness compared with the pre-alloyed Ti6Al4V alloy. 相似文献
113.
Andra Swetha Balu Satheesh kumar Jeevanandam Jaison Muthalagu Murugesan Danquah Michael K. 《Cellulose (London, England)》2021,28(9):5895-5910
Cellulose - Elimination of disease-causing bacteria from cotton fabrics is critically important to control several bacteria-mediated infections in humans. Antibacterial nanoparticles, particularly... 相似文献
114.
A series of novel 2,6-diaryl-3-(arylthio)piperidin-4-ones have been synthesized by reaction of arylthioacetones, substituted aromatic aldehydes, and methylamine/ammonium acetate and their structures elucidated by (1)H, (13)C, and 2D NMR (H, H-COSY, C, H-COSY, HMBC, and NOESY) spectroscopy. The NMR data reveal that all these piperidones exist in chair conformation with the 2,6-diaryl groups equatorially oriented, while the arylthio group prefers to be in either an equatorial or axial orientation depending on whether the substituent in the 2,6-diaryl rings is present in 4- or 2-position, respectively. In the case of NH-2,6-diaryl-3-(arylthio)piperidin-4-ones with o-substituted 2,6-diaryl groups, the arylthio group prefers the axial orientation presumably in a bid to minimize the steric and/or electronic repulsion. The arylthiopiperidin-4-ones exhibit significant antibacterial activity against Staphylococcus aureus, Vibrio cholerae, Salmonella typhi, and Escherichia coli and antifungal activity against Candida albicans and Aspergillus niger. 相似文献
115.
Ali. E. I. Elkhalifah Saikat Maitra M. Azmi Bustam T. Murugesan 《Journal of Thermal Analysis and Calorimetry》2012,110(2):765-771
Different cationic forms of montmorillonite, mainly K-, Na-, Ca- and Mg-montmorillonites were intercalated in this study via ion exchange process with mono-, di-, and triethanolammonium cations. The developed samples were characterized by TG, XRD, and CHNS techniques. Thermogravimetric study of ammonium-montmorillonites shows three thermal transition steps, which are attributable to the volatilization of the physically adsorbed water and dehydration, followed by the decomposition of the intercalated ammonium cations and dehydroxylation of the structural water of the modified clay, respectively, while untreated and cationic forms of montmorillonite showed only two decomposition steps. The type of ammonium cation has affected both desorption temperature (Position) and the amount of the adsorbed water (intensity). XRD results show a stepwise change in the crystallographic spacings of montmorillonite with the molar mass of ammonium cation, reflecting a change in the structure of the clay. CHNS data confirm the intercalation of ammonium cations into the interlayer space of montmorillonite and corroborate the effect of the molar mass of ammonium cation on the amount adsorbed by the clay. 相似文献
116.
G. Vadivelan M. Saravanabhavan V. Murugesan G. Gohulvani B. Babu 《Molecular Crystals and Liquid Crystals》2017,652(1):242-254
A new charge transfer (CT) complex benzimidazolium-4-methylbenzenesulfonate formed between benzimidazole and 4-methylbenzenesulfonic acid has been studied spectrophotometrically in methanol at room temperature. The binding of the novel CT complex with calf thymus DNA has been investigated by adsorption spectrum, the establish the ability of the CT complex for its interaction with the chosen DNA. The elemental stiochiometry and the X-ray crystallographic structure of the complex were studied, showing the significance of sulfonate anion in holding stability. Powder XRD confirms the crystalline nature of the compound. NMR signals explicitly confirmed the molecular structure crystal. Antioxidant activity of the CT complex was found to be potent. TG-DTA studies also proves the stability of the synthesized complex. 相似文献
117.
Sellamuthu Kathiresan Raman Dhivya Murugesan Vigneshwar Marichamy Rajasekaran Jyothi Ranjani Jeyaprakash Rajendhran 《Journal of Coordination Chemistry》2016,69(2):238-252
A series of non-enolizable β-diketonate-based copper(II) complexes with LCuCl2 [L = Knoevenagel condensates of curcumin (Salcimine) and methylacetoacetate (SalMaA)-based Schiff bases] chromospheres as functional models of chemotherapy drug cisplatin were investigated for their covalent interaction with herring sperm DNA. The synthesis and structural characterization of 1a and 1b have been reported in our previous article. However, their DNA interactions and cytotoxicity properties were not studied. These analyses have been carried out mainly through electrochemical techniques supplemented with spectral, relative viscosity, gel electrophoresis techniques, and AGS cancer cells using MTT assay. The cytotoxic activities of the ligand, curcumin-based copper complex, and cisplatin were tested against the AGS cancer cell line under similar experimental conditions showing that the complex exhibited cancer cell inhibitory rate closer to cisplatin even at low concentration. This was also seen in the docking of the Cu-complex onto a rich guanine B-DNA decamer, where a Cu–N3(guanine) interaction instead of Pt-N7 as cisplatin is detected. The obtained results in this study prove that these complexes could be a promising substitute for cisplatin as a new family of non-platinum-based anticancer metallo-drugs after in vivo tests on animal models. 相似文献
118.
Thangamariyappan Shanmugaprabha Karuppaiah Selvakumar Murugesan Vairalakshmi Kasi Rajasekaran Ponnusamy Sami 《Transition Metal Chemistry》2017,42(1):95-103
Kinetics of the oxidation of thiourea (tu) by heteropoly-α2-17-tungsto-1-vanadodiphosphate anion, α2-[P2VVW17O62]7?, have been studied spectrophotometrically in aqueous acidic medium at 25 °C. At low pH (2.4–3.0), the neutral form of tu is the only reactive species. At higher pH (4.2–4.9), both neutral and deprotonated forms of tu participate in the reaction. The observed mixed-order kinetics suggest two parallel reactions: one in which the order in [tu] is unity, and a second in which it is two. In both cases, the order in [α2-[P2VVW17O62]7?] is unity. Based on the kinetic studies, a mechanism is proposed, in which a second-order proton-coupled electron transfer involving NH2CSNH2 and α2-[P2VVW17O62]7? proceeds through a sequential electron transfer, followed by proton transfer such that the reaction is an “activation-controlled” outer-sphere electron transfer process. By applying the Marcus equation, the self-exchange rate constants for the couples \({\text{NH}}_{2} {\text{CSNH}}_{2}^{ \cdot + }\)/NH2CSNH2 and α2-[P2VVW17O62]7?/α2-[P2VIVW17O62]8? were evaluated. 相似文献
119.
Yamasaki T Mito F Ito Y Pandian S Kinoshita Y Nakano K Murugesan R Sakai K Utsumi H Yamada K 《The Journal of organic chemistry》2011,76(2):435-440
We have synthesized several nitroxides with different substituents which vary the steric and electronic environment around the N-O moiety and have systematically investigated the role of substituents on the stability of the radicals. Our results demonstrated the reactivity toward ascorbate correlates with the redox potential of the derivatives. Furthermore, ab initio calculations also indicated a correlation between the reduction rate and the computed singly occupied molecular orbital-lowest unoccupied molecular orbital energy gap, but not with solvent accessible surface area of the N-O moiety, supporting the experimental results and suggesting that the electronic factors largely determine the radicals' stability. Hence, it is possible to perform virtual screening of nitroxides to optimize their stability, which can help to rationally design novel nitroxides for their potential use in vivo. 相似文献
120.
Takafumi Fukushima Mariappan Murugesan Ji-Cheol Bea Hiroyuki Hashimoto Hisashi Kino Tetsu Tanaka Mitsumasa Koyanagi 《Journal of polymer science. Part A, Polymer chemistry》2020,58(16):2248-2258
Thin-film polyimides were prepared by solvent-less vapor deposition polymerization (VDP) from pyromellitic dianhydride and 4,4′-oxydianiline at 200 °C for liner dielectric formation of vertical interconnects called through-silicon vias (TSVs) used in three-dimensionally stacked integrated circuit (3DICs). FTIR, synchrotron XPS, and TDS were employed for determining the imidization ratio, and in addition, the mechanical properties, coefficient of thermal expansion and Young's modulus, of the VDP polyimide were characterized on Si wafers. The VDP polyimide exhibited extremely high conformality, beyond 75%, toward high-aspect-ratio deep Si holes, compared with conventional SiO2 prepared by plasma-enhanced chemical vapor deposition. The adhesion between the VDP polyimide and Si wafer was enhanced by an Al-chelate promotor. Remarkably, the VDP polyimide TSV liner dielectrics showed much less thermomechanical stresses applied to the Si surrounding the TSVs than the plasma-chemical vapor deposition SiO2. The small keep-out zone is expected for scaling down highly reliable 3DICs for the upcoming real artificial intelligence society. 相似文献