Polymerization of butadiene on nanoparticles’ surfaces and formation of metal/polymer nanocomposites

In this paper, we demonstrate that laser vaporization of metals in the presence of a small concentration of butadiene vapor leads to the polymerization of butadiene and incorporation of the metal nanoparticles within the polymer matrix. The metal nanocomposites are characterized by electron microscopy, X-ray diffraction and EDX. The results from high pressure mass spectrometry indicate that multiple additions of butadiene molecules on the metal cations Fe⁺, Ni⁺ and Pt⁺, generated by laser vaporization, take place at room temperature thus providing an efficient means of initiating further polymerization reactions. The Pt⁺ reactions show extensive fragmentations and elimination steps generating hydrocarbon ions. The laser vaporization/polymerization method provides the ability to encapsulate several different metals or metal oxides which undoubtedly will play a significant role in tuning the various properties of the polymer composites.     

Estimate for the Gradient of the Solution to the Neumann Problem for (p,q)-Nonlinear Equations

We consider the Neumann boundary value problem for the class of (p,q)-nonlinear elliptic equations. The numbers p and q, 2 ⩽ p < q, characterize the power growth with respect to the gradient of eigenvalues of the leading matrix of the equation. An a priori estimate for the maximum of the modulus of the gradient of the solution is obtained in a neighborhood of the boundary of the domain for some interval of p and q. Bibliography: 5 titles. __________ Translated from Problemy Matematicheskogo Analiza, No. 31, 2005, pp. 47–57.     

Bases on multipunctured Riemann surfaces and interacting strings amplitudes

The Krichever-Novikov bases are studied on Riemann surfaces with more-than-two punctures. The bases are presented and the completness theorem is proven for the case of integer (up to a common constant) momenta. Then the interacting strings are considered, the amplitudes and partition functions are obtained, comparable with that of path-integral approach. For the amplitudes the simple geometric implication is proposed.     

Cyclotron resonance for electrons over helium in a resonator

The cyclotron resonance (CR) problem for electrons over a helium film occupying the lower part of a resonator is solved. This problem is shown to represent an example of the well-known problem on the behavior of a system of coupled oscillators. For such oscillators, the coupling constant is determined as a function of the problem parameters with its minimal value in zero magnetic field and its maximal value at resonance conditions, when the cyclotron frequency coincides with one of the resonator modes. The details of the CR absorption of microwave energy by the coupled system formed by 2D electrons and a resonator are calculated. The results are discussed in application to the known CR experiments with electrons over helium.     

Absorption and emission dynamics in concentrated optical ensembles under laser excitation

A new theoretical model describing the emission and absorption dynamics in an ensemble of molecules under intense coherent pulsed pumping is developed on the basis of the concepts of cooperative light-induced luminescence (CLIL). The CLIL development is described within the framework of formalism of the system density matrix in the space of photon wave functions. It is shown that the fast growth of CLIL relates to the development of coherent states of the quantum field in the area of efficient cooperative interactions of molecules (coherence volume). A system of equations for the calculation of CLIL energy, population of excited states, and optical absorption of the system in dependence on the laser pump energy density is solved. The theoretical results obtained are in good agreement with the experimental data.     

Reaction of 2-formyl-1,3-cyclohexanediones with cyanoacetamide

Chemistry of Heterocyclic Compounds -