Hydrolysis of dimethyl 1-acetoxy-2,2,2-trichloroethyl phosphonate

Conclusions The hydrolysis of chloroacetophos in water includes the parallel cleavage of acetic acid, hydrochloric acid and methanol. The ratio of the products, formed in the parallel steps, was determined, and we also determined the total rate constant for the hydrolysis of chloroacetophos.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2336–2338, October, 1971.     

Thermal oxidative degradation of a composition based on a polyester resin and tetramethylammonium chloride

Thermal oxidative degradation of a composition based on a polyester resin modified with rosin and tetramethylammonium chloride and its use as a flux for low-temperature solder pastes were studied.     

Co-Pt bimetallic catalysts for the selective oxidation of carbon monoxide in hydrogen-containing mixtures

The performance of a Co-Pt powder and of Co-Pt catalysts supported on γ-Al₂O₃ and on the graphite-like carbon material Sibunit in selective CO oxidation in hydrogen-containing mixtures is considered. Fine particles of metal-metal solid solutions and intermetallides were obtained by the decomposition of a Co- and Pt-containing double complex salt in a hydrogen atmosphere at ～400°C. As compared to their Pt and Co monometallic counterparts, the bimetallic catalysts are more active and allow the CO concentration in hydrogen-containing mixtures to be reduced from 1 to 10^?3 vol %. This effect is likely due to the formation of bimetallic particles of a Co-Pt solid solution on the support surface.     

Reaction of 3,4-diaminofurazan with β-keto esters

The reaction of some linear and cyclic -keto esters with 3,4-diaminofurazan was investigated. Products of condensation at the keto group and the corresponding furazanodiazepinones were isolated and characterized. The structures of the compounds obtained are discussed.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1196–1199, September, 1978.     

Crystal and molecular structures of 2,10-diacetoxy-13-thiabicyclo[7.3.1]-cis-tridec-5-ene and 2,9-dichloro-13-thiabicyclo[8.2.1]-cis-tridec-5-ene sulfoxide

The crystal and molecular structures of 2,10-diacetoxy-13-thiabicyclo[7.3.1]-cis-tridec-5-ene and 2,9-dichloro-13-thiablcyclo[8.2.1]-cis-tridec-5-ene sulfoxide were established. The conformations of the molecules are such that the unshared pairs of electrons of the sulfur atoms are directed to the carboncarbon double bonds of their molecules. It was observed that there are stereochemical conditions for transannular transformations under the influence of polarized molecules and cations.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1628–1632, December, 1977.