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991.
S. V. Kharitonov 《Journal of Analytical Chemistry》2003,58(2):176-183
Main transport properties were studied for selective membranes with low dielectric constants based on liquid ion exchangers involving nitrogen-containing organic base cations. Permeabilities and ion flows through a membrane were calculated for major and interfering ions. Dependences of the transport properties of membranes on the concentrations of the ion exchanger and near-membrane solution and their potentiometric characteristics are presented. It was demonstrated that the transport properties of liquid membranes are determined by two main factors: the transfer of counterions through the phase boundary by the extraction–exchange mechanism and the leaching of the ion exchanger from the membrane. 相似文献
992.
V. V. Kuznetsov Yu. V. Ermolenko A. Ya. Zheltov K. A. Kornev S. V. Sheremet'ev 《Journal of Analytical Chemistry》2004,59(1):17-22
The coprecipitation of azo compounds based on 4-nitrophenyl- and 4-sulfophenyldiazonium naphthol sulfonates as their diphenylguanidinium ion-pair complexes with analogous compounds of naphthalene-2-sulfonic acid and 4-phenylsulfodiazonium is investigated. The optimization of the coprecipitation is considered based on the notions of the driving force of the cocrystallization of impurities. The optical characteristics of colored ion-pair complexes are measured. It is found that the water solubility is decreased most substantially for azosulfonates with hydrophobic nitro groups and with no more than two sulfo groups in different aromatic nuclei, which can lead to a decrease in the detection limit due to preconcentration by coprecipitation, which stimulates the thermodynamic flux of concentrate elution. Coprecipitation is combined with flow-injection analysis in the on-line mode, and new procedures are developed for determining naphthol sulfonates and related azo compounds with the detection limit equal to 0.003–0.006 mg/50 mL. 相似文献
993.
Nathan S. Feldman Paul McGuire 《Proceedings of the American Mathematical Society》2003,131(6):1793-1801
In this paper we show that the spectral picture of an irreducible subnormal operator may be arbitrarily prescribed subject only to certain natural necessary conditions. This completes work begun by the second author.
994.
A. V. Ershov 《Journal of Mathematical Sciences》2004,123(4):4198-4220
In this paper, we consider homotopic properties of bundles of algebras, matrix Grassmanians, and homotopy functors connected with bundles of algebras. 相似文献
995.
The transformation of a shear surface magnetoelastic wave by the motion of the 180° confining domain wall in a ferromagnet is considered. Changes in the wave spectrum due to the motion of the wall are correlated with the variations of the energies of the elastic and magnetic subsystems. The efficiency of surface wave transformation by the domain wall motion is estimated in terms of energy. The frequency dependences of the mean energy density of the wave are found. It is shown that the energy density grows with wall velocity. 相似文献
996.
Savos'kin M. V. Yaroshenko A. P. Shologon V. I. Galushko L. Ya. 《Russian Journal of Applied Chemistry》2003,76(7):1179-1181
Petroleum sorption on expanded graphite prepared from residual graphite hydrosulfate at 300-900°C was studied as influenced by pretreatment of the sorbent with water. 相似文献
997.
The appearance of a steady current in a helical quantum wire under circularly polarized light is predicted. The effect is associated with the appearance of a travelling electromagnetic wave in the coordinate system related to the wire, the wavelength being determined by the period of the helix. The gyrotropy of a medium consisting of parallel quantum wires is considered. 相似文献
998.
Kurenkov V. F. Zhelonkina T. A. Ryabysheva N. A. Lobanov F. I. 《Russian Journal of Applied Chemistry》2003,76(8):1310-1314
The influence of single- and double-charged cations on degradation of metal 2-acrylamido-2-methylpropanesulfonate-N-vinylpyrrolidine copolymers in aqueous solutions in the presence of potassium peroxodisulfate, K2S2O8, at 50 and 70°C was studied by viscosimetry. 相似文献
999.
The features of anthracite oxidation as influenced by temperature and time were determined. Physicochemical and sorption characteristics of the resulting cation exchanger were studied. 相似文献
1000.