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941.
E. S. Voropai M. P. Samtsov K. N. Kaplevskii A. A. Maskevich V. I. Stepuro O. I. Povarova I. M. Kuznetsova K. K. Turoverov A. L. Fink V. N. Uverskii 《Journal of Applied Spectroscopy》2003,70(6):868-874
Comparative analysis of the absorption and fluorescence spectra and fluorescence excitation spectra of thioflavin T (ThT) in various solvents and in the composition of amyloid fibrils has shown that ThT, when excited in the region of the long-wavelength absorption band, fluoresces in the spectral region with a maximum at 478–484 nm. The appearance in aqueous and alcohol solutions of a fluorescence band with a maximum near 440 nm has been attributed to the presence in the composition of the ThT preparations of an impurity with an absorption band in the 340–350-nm range. The literature data showing that in glycerol ThT has a wide fluorescence spectrum with two maxima are due to the artifact connected with the use of a high concentration of the dye. It has been suggested that the cause of the low quantum yield of ThT aqueous and alcohol solutions is the breakage of the system of conjugated bonds due to the reorientation of the benzothiozole and benzaminic rings of ThT in the excited state with respect to one another. The main factor determining the high quantum yield of fluorescence of ThT incorporated in fibrils is the steric restriction of the rotation of the rings about one another under these conditions. The suggestions made have been verified by the quantum-chemical calculation of the ThT molecule geometry in the ground and excited states. 相似文献
942.
We investigate a multicomponent anisotropic liquid system. The first spatial moment of the direct correlation function is taken into account to obtain asymptotic expressions for the pairwise correlation functions. In this approximation, we obtain the pairwise correlation functions that describe the system behavior not only in the critical-state neighborhood but also in the noncritical domain. We show that the critical parameters for the anisotropic system differ from those for the isotropic system. 相似文献
943.
Properties of the idempotently convex hull of a two-point set in a free semimodule over the idempotent semiring R max min and in a free semimodule over a linearly ordered idempotent semifield are studied. Construction algorithms for this hull are proposed. 相似文献
944.
945.
946.
D. V. Treschev 《Proceedings of the Steklov Institute of Mathematics》2007,259(1):196-235
We propose a method for constructing noncommutative analogs of objects from classical calculus, differential geometry, topology,
dynamical systems, etc. The standard (commutative) objects can be obtained from noncommutative ones by natural projections
(a set of canonical homomorphisms). The approach is ideologically close to the noncommutative geometry of A. Connes but differs
from it in technical details. 相似文献
947.
Madhu V. Nayakkankuppam 《Mathematical Programming》2007,109(2-3):477-504
We describe an approach to the parallel and distributed solution of large-scale, block structured semidefinite programs using
the spectral bundle method. Various elements of this approach (such as data distribution, an implicitly restarted Lanczos
method tailored to handle block diagonal structure, a mixed polyhedral-semidefinite subdifferential model, and other aspects
related to parallelism) are combined in an implementation called LAMBDA, which delivers faster solution times than previously
possible, and acceptable parallel scalability on sufficiently large problems.
This work was supported in part by NSF grants DMS-0215373 and DMS-0238008. 相似文献
948.
V. I. Maslov 《Russian Physics Journal》2007,50(5):425-428
An abrupt rise of the field electron emission (FEE) current from a high-temperature superconductor (HTSC) being in the normal
state has been detected. The current amplification with a factor reaching ∼106 occurs as an HTSC emitter is heated in the temperature range 110–170 K. The features of the temperature dependence of FEE
are discussed. Measured parameters of the effect observed are presented. Possible mechanisms of the process under consideration
are discussed.
__________
Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 5, pp. 13–16, May, 2007. 相似文献
949.
M.C. Ubaldi V. Stasi U. Colombo D. Piccinin M. Martinelli 《Photonics and Nanostructures》2007,5(2-3):145-148
Roughness reduction of a submicron waveguide profile in chemically amplified negative resist is here performed by proper selection of an alkali-based developer, taking into account that its smaller molecules lead to smoother resist surface by altering the developing mechanism of aggregate extraction performed with standard quaternary ammonium hydroxide. Roughness is then analyzed by means of classical Atomic Force Microscope inspection; furthermore, a non-invasive line edge roughness analysis approach based on top-down scanning electron microscope acquisition gives comparable results, in terms of standard deviation and molecular aggregate periodicity. 相似文献
950.
G. Bouwmans B. Ségard P. Glorieux P. A. Khandokhin N. D. Milovsky E. Yu. Shirokov 《Radiophysics and Quantum Electronics》2004,47(10-11):729-742
This paper is devoted to the polarization dynamics of a longitudinally monomode bipolarized Nd:YAG laser: the low-frequency polarization dynamics of a microchip laser is studied experimentally and theoretically. The intensities and the relaxation oscillation spectrum of orthogonally polarized modes versus the direction of pump polarization is observed. A phase-sensitive model of a longitudinally monomode bipolarized solid-state laser with linear polarized diode laser pump is developed to account for the experimental observations. 相似文献