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231.
Levoglucosenone reacts with α-aminoazoles to yield azolo[1,5-a]pyrimidine systems fused with a carbohydrate fragment. The reaction oocurs much more smoothly than in the case of other α,β-unsaturated
ketones. The reactions of levoglucosenone with β-dicarbonyl compounds (dimedone, barbituric acid) in the presence of a base
results in the pyran ring closure, which has never been observed earlier in reactions of β-dicarbonyl compounds with α,β-unsaturated
ketones under the conditions of basic catalysis. The structures of products were established by IR and NMR spectroscopy.
For Part 3, see Ref. 1.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 553–558, March, 1997. 相似文献
232.
S. A. Gurevich T. A. Zaraiskaya S. G. Konnikov V. M. Mikushkin S. Yu. Nikonov A. A. Sitnikova S. E. Sysoev V. V. Khorenko V. V. Shnitov Yu. S. Gordeev 《Physics of the Solid State》1997,39(10):1691-1695
The concentration and chemical state of copper in the subsurface region of Cu/SiO2 composite films obtained by simultaneous magnetron sputtering from two sources (Cu and SiO2) are determined by x-ray photoelectron spectroscopy (XPS). It is established that copper in the as-grown film is primarily in the form of unoxidized atoms dispersed in a SiO2 matrix. Annealing of the film results in practically no oxidation, but about 70% of the copper atoms condense into metallic clusters with sizes below 10 Å in the subsurface region and about 50 Å in the bulk of the film. The changes in the binding energy of core electrons, and especially in the energies of Auger electrons, are so large in this situation that photoelectron and Auger spectroscopy are efficient methods for monitoring the chemical state of this composite material. 相似文献
233.
Ya. V. Fattakhov M. F. Galyautdinov T. N. L’vova I. B. Khaibullin 《Technical Physics》1997,42(12):1457-1459
The first results regarding the formation of a two-dimensional periodic structure of local melting regions on a silicon surface
upon pulsed light irradiation are presented. The conditions are established, and the mechanism of the formation of such structures
is discussed.
Zh. Tekh. Fiz. 67, 97–99 (December 1997) 相似文献
234.
F. A. van Goor S. V. Mitko V. N. Ochkin W. J. Witteman 《Journal of Russian Laser Research》1997,18(2):107-120
Experimental and theoretical results are presented on an XeF(C?A) blue-green laser driven by 5-kJ energy. The laser was pumped by a ferrite-induced discharge of 90 cm in length. The output energy of 0.22 J was obtained with a plane-parallel resonator. A program to simulate laser operation has been developed. Numerical results for a wide range of conditions are compared with experiments performed by us and by other authors. It is found that intracavity refractive losses limit laser operation for XeF pressures above 3 torr. The laser efficiency strongly depends on the discharge-to-cavity length ratio. Possible ways to increase the laser power and efficiency are discussed. 相似文献
235.
The temporal evolution of a long-pulse high-density electron beam in a high-power traveling-wave tube with a periodic magnetic
focusing system is investigated. The relation between the variation of the characteristics of the electron beam and ionization
of the residual gas and particles desorbed from the electrode surfaces is shown. A strong influence of the formation of the
collector plasma and the flux of ions from its surface on the beam dynamics is revealed. The effect of microwave fields in
the transport channel on the characteristics of the beam during its evolution is studied.
Zh. Tekh. Fiz. 67, 54–58 (December 1997) 相似文献
236.
V. A. Krakovskii 《Russian Physics Journal》1997,40(1):6-12
The problem of exciting bulk elastic waves at the surface of a piezoelectric with symmetries 422,622 has been solved by a
successive approximation method. In the approximation of a fixed electric field, created at the surface of the piezoelectric
crystal by a two-electrode transducer, the distributions are found for the shear wave stress and the energy flux density in
the far zone. The equivalent circuit parameters for a two-electrode radiator are determined taking account of the dynamic
piezoelectric correction obtained in the second approximation. The equivalent circuit parameters and the transducer loss are
treated for TeO2 crystals. A realistic possibility of using surface transducers in the development of acousto-optic modulators in the s.h.f.
region is shown.
Tomsk State Academy of Control Systems and Radio Electronics. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika,
No. 1, pp. 8–15, January, 1997. 相似文献
237.
238.
V. V. Ilyasov 《Russian Physics Journal》1997,40(6):574-578
An analysis is made of the thermodynamic stability of the dislocation structure in polycrystalline samples of Fe-C, deformed
under conditions of high rates and hydrostatic pressures, based on experimental and theoretical data concerning the internal
energy and on diffractometer measurements of the broadening of x-ray lines. The method of deformation calorimetry was used
to determine the internal energy in a wide range of deformations. A theoretical model is proposed for estimating the change
in internal energy in deformed alloys. An investigation is made of the dependence of the interdislocation interaction parameter
on the deformation rate for different stressed state-schemes and large plastic deformations. It is shown that the relative
quantity δU/A is correlated in a wide range of deformations with the relative root-mean-square distortions of the crystal lattice of the
deformed solid solution. The mechanisms for the accumulation of energy in deformed solid solutions having a body-centered
cubic lattice are considered.
Don State Technical University. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 6, pp. 77–83. 相似文献
239.
It is shown that equations describing the dynamics of Darwinian systems (DS) far from the bifurcation points may be expressed
in Hamiltonian form. The cases of DS with constant organization and DS with a constant flux through the system are considered.
The configurational part of phase space is formed by variables containing information on the structure of the system. Momentum
variables may be regarded as specific rates of multiplication. The evolution of DS with constant organization in this phase
space is expressed as uniform rectilinear motion. In the case of DS with a constant flux, the motion occurs in some effective
constant and uniform field. The meaning of the elements of the Hamiltonian structure is described in terms of theoretical
biology.
Tomsk State University. Scientific-Research Institute of Biological Systems, Tomsk State University. Translated from Izvestiya
Vysshikh Uchebnykh Zavedenii, Fizika, No. 7, pp. 23–28, July, 1997. 相似文献
240.