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991.
N. Moslemzadeh G. Beamson P. Tsakiropoulos J.F. Watts S.R. Haines P. Weightman 《Journal of Electron Spectroscopy and Related Phenomena》2006
High-energy X-ray photoelectron spectroscopy (XPS) is of particular importance for minimizing the effects of surface contamination by increasing photoelectron escape depths. In this study high-resolution high-energy Cu Kα1 and soft Al Kα1 XPS and Auger electron spectroscopy were used to compare the electronic structure of Ti in TiO2 powder and Ti metal. The Ti 1s in TiO2 XPS line is narrower and more symmetric than in Ti metal. A comparison of the relative intensities of the L23M23M45 and L23M23M23 Auger transitions in Ti metal and TiO2 is consistent with the expected transfer of Ti 3d electrons away from the Ti site in the oxide. The satellites accompanying the Ti 1s XPS line excited by Cu Kα1 X-rays occur at the same energies as the satellites accompanying the Ti 2s and 2p XPS lines excited by Al Kα1 X-rays indicating that they do not depend on the core-level, the experimental resolution or inelastic scattering processes. 相似文献
992.
A nonclassical problem is considered for the transport equation with coefficients depending on the energy of radiation. The task is to find the discontinuity surfaces for the coefficients of the equation from measurements of the radiation flux leaving the medium. For this tomography problem, an optimization problem is stated and numerically analyzed. The latter consists in determining the radiation energy that ensures the best reconstruction of the unknown medium. A simplified optimization problem is solved analytically. 相似文献
993.
Mössbauer investigations about iron atom redistribution in oxide films of zirconium alloys subjected to corrosion at 500°C in pure oxygen and water pair have been analysed. The alloys were also subjected to autoclave conditions at a pressure of 10.0 MPa and autoclave conditions at 350°C and at a pressure of 16.8 MPa, using distilled water and water with additives of lithium and fluorine. It is shown that, depending on the corrosion environment, various compounds of iron, such as α-Fe2O3, Fe3O4, and FeO, as solid solutions of iron in ZrO2 are formed in oxide films. 相似文献
994.
The mass spectrum ofcb meson is investigated with an effective quark-antiquark potential of the form -αc/r +Ar
νwith ν varying from 0.5 to 2.0. TheS andP-wave masses, pseudoscalar decay constant, weak decay partial widths in spectator model and the lifetime ofB
cmeson are computed. The properties calculated here are found to be in good agreement with other theoretical and experimental
values at potential index,ν = 1 相似文献
995.
The conversion of methanol into light olefins has been studied using the silver salt of dodecatungstosilicic acid supported on serosil. Special attention has been paid to the process of the acid sites formation during the initial reaction period and to the role of hydrogen. The significantly higher activity and stability of the supported silver salt compared with the supported free heteropoly acid is explained by a controlled formation process of acidic sites and their additional generation from hydrogen on the metallic silver surface. 相似文献
996.
The dependencies of the effective Hall properties on a scale, obtained by means of an iterative averaging method, manifest their fractal character. The influence of an intensity of the Hall effect on the fractal character of the Hall properties was considered. Scale ranges and dimensional characteristics of the effective Hall properties behavior were calculated and discussed. 相似文献
997.
N C Proudlove S Black A Fletcher 《The Journal of the Operational Research Society》2007,58(2):145-158
This paper considers efforts to improve in-patient flows, a particularly urgent issue in the National Health Service (NHS). The context is described and related to reasons why OR has been making relatively little contribution. The paper argues that large complex models may often be unnecessary and even get in the way of providing clear insight and guidance for problem owners. The importance of understanding the generic working of systems to lead to improvement, and the limitations of simply describing them, is stressed. It is demonstrated that some very simple models can be of significant practical value in understanding and managing complex systems, changing mindsets and driving collection and use of operationally valuable data. Recommendations for more effective engagement with the NHS are offered. 相似文献
998.
K. K. Kadyrzhanov S. Khazhekber S. N. Lukashenko V. P. Solodukhin I. V. Kazachevskiy V. L. Poznyak B. B. Knyazev Ch. Rofer 《Czechoslovak Journal of Physics》2003,53(1):A39-A44
Data on the spatial distribution of radionuclides (241Am, 239Pu, 137Cs and 152Eu) formed during nuclear explosions of different types near P2 SNTS test site are presented. Radionuclide contamination induced by the explosions varies in the concentrations of individual radionuclides, their proportions and species. Examination of the variations is a crucial task to plan remediation activities as well as those aimed at decrease of radiation risk for population and prevention of repeated contamination. Concentrations of 241Am and 239+240Pu that are the most toxic radionuclides in the area lie in hundred thousands of Bqkg?1. The most contaminated areas are classified by the radionuclide concentration, ratio and form present in soil. 相似文献
999.
B. Aneva 《The European Physical Journal C - Particles and Fields》2003,31(3):403-414
Deformed squeezed states are introduced as the q-analogues of the conventional undeformed harmonic oscillator algebra squeezed states. It is shown that the boundary vectors in the matrix-product states approach to multiparticle diffusion processes are deformed coherent or squeezed states of a deformed harmonic oscillator algebra. A deformed squeezed and coherent-states solution to the n-species stochastic diffusion boundary problem is proposed and studied.Received: 31 January 2003, Published online: 10 October 2003 相似文献
1000.
We present a full treatment of the microcanonical ensemble of the ideal hadron-resonance gas starting from a quantum-mechanical formulation which is appropriate for the statistical model of hadronization. By using a suitable transition operator for hadronization we are able to recover the results of the statistical theory, particularly the expressions of the rates of different channels. Explicit formulae are obtained for the phase space volume or density of states of the ideal relativistic gas in quantum statistics as a cluster decomposition, generalizing previous ones in the literature. The problem of the computation of averages in the hadron gas microcanonical ensemble and the comparison with canonical ones will be the main subject of a forthcoming second paper.Received: 8 July 2003, Revised: 17 October 2003, Published online: 5 May 2004 相似文献