Synthesis and investigation of the mesomorphic properties of pyran derivatives

4-[(5,6-Dihydro-2H-pyran-4-yl)methoxy]benzylidene-4-alkoxyanilines, which have the properties of smectic liquid crystals, were synthesized. The effect of the pyran ring in the benzylidene component and the length of the aliphatic radical in the aniline component on the type and thermal stability of the meso phase was ascertained.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 327–328, March, 1992.     

Synthesis of 24-epiteasterone

Starting from ergosterol, the synthesis of the brassinosteroid 24-epiteasterone has been achieved by the use of a new scheme for introducing a 3-hydroxy-6-keto group as the result of the Birch reduction of the corresponding 5-hydroxy-⁷-3,6-dione.Institute of Bioorganic Chemistry, Belorussian Academy of Sciences, Minsk. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 224–227, March–April, 1992.     

Synthesis of 2-R-fluorantheno[2,3-d]- and 2-R-fluorantheno[3,2-d]oxazoles

2-R-Fluorantheno[2,3-d]- and 2-R-fluorantheno[3,2-d]oxazoles were synthesized, and their UV and IR spectra were studied. Ten new compounds are described.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 905–907, July, 1974.     

Calculation of exclusive processes with baryons

Using the nucleon andΔ ₃₃-resonance wave functions found out in previous papers [14, 15] we calculate the electromagnetic and weak nucleon formfactors, the transition formfactorγ \(\bar N\) Δ and the decay widths of charmonium levels³ S ₁,³ P ₂ and³ P ₁ into \(\bar N\) N and \(\bar \Delta \) Δ.     

Relativistic correction to the triton binding energy in the framework of relativistic Hamiltonian dynamics

The relativistic correction to the triton binding energy approximated to the order (v/c)² is calculated in the framework of relativistic Hamiltonian dynamics. We discuss the generator representation of the Poincaré group for three relativistic particles and its connection with the Feynman diagrams in the infinite-momentum frame (the light-front dynamics). The relativistic correction enhances the attraction in the three-nucleon system. The five-channel calculation with the Reid soft-core potential yeilds the result =–0.54 MeV, which is governed mainly by theD-wave contribution. TheS-wave contributions to are only –0.10 MeV.     

Laser-pulse fluctuations due to thermal self-action in a turbulent atmosphere

Conclusions Refractive-index fluctuations caused by heating alter the intensity and phase fluctuation spectra arising from the turbulence. The large-scale part of the spectra is weakened, whereas the small-scale part is strengthened, and the spatial-frequency range in which the fluctuations are attenuated becomes narrower as the beam energy increases. Correspondingly, the fluctuation structure functions alter. For values of the arguments in those functions less than the radius of the first Fresnel zone , the thermal nonlinearity causes increases in the structural functions D_, with the energy. For , the dependence of D_, on energy is nonmonotone, with the fluctuations at first weakened but then strengthened. The reduction in fluctuation variance and the improvement in coherence is less pronounced over long lines than on short ones. The range in which geometrical optics can be used to derive the fluctuations is independent of the nonlinearity and is defined by k₂z/2k /4. The trend to the diffraction asymptote becomes slower as the nonlinearity increases.Atmospheric Physics Institute, Academy of Sciences of the USSR. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 32, No. 9, pp. 1063–1071, September, 1989.     

On FMR modes in bubble domain lattices

Two solutions of the problem of non-uniform ferromagnetic resonance in a hexagonal bubble domain lattice are presented under the simplifying assumption of lattice period much smaller than the film thickness. Fine divisions of the lattice cell into supposedly uniform subdomains render sets of linear equations for the local amplitudes which are solved numerically. Analytical solution of the time-dependent magnetostatic (Walker-mode) problem is obtained by expansion in simple elliptic functions similar to that suggested by Sigal. The results support, respectively, the interpretation of FMR experiments derived by Klem and Kaczér from a crude (minimal) subdivision of the elementary cell, and the three-mode dipolar-field model recently proposed by the author on a largely intuitive basis.     

Killing vectors of vacuum space times and electromagnetic four potentials

A conjecture is formulated about the connection between isometries of vacuum space times and the existence of corresponding space times with electromagnetic fields for which the structure of electromagnetic four potentials is readily predicted. One example is presented showing how this conjecture works, three others are only commented.     

Textural analysis of extruded materials with rhombohedral structure

A textural analysis of extruded rods of material with tetradymite (Bi₂Te₃) structure is conducted by constructing the distribution of the pole density of the (0001) and (1120) planes. The distribution of the poles of the planes is represented by a solid of revolution, and the pole density, which is a function of the angle () of the deviation of the normals to h_i from the extrusion axis, is determined by the diffraction method of specimen inclination using the diffracted ray intensity. It proves possible to identify textural components, and to determine how many there are and the degree of perfection of this method. A technique is worked out for the quantitative estimate of the average values of the components of the conductivity tensor in the grains, and the contribution of the texture to the macroscopic properties of the material is analyzed. To investigate the thin layers (for example, the layerwise distribution of texture in rods of rectangular cross section) we used the method of inverse pole diagrams, where the probability of coincidence of the h_i plane with the working surface of the specimen is analyzed.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 12, pp. 33–39, December, 1989.