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271.
A combination of 1,3-dihalo-5,5-dimethylhydantoin (X = Br, Cl) and sodium nitrite in the presence of wet SiO2 was used as an effective nitrosating agent for the nitrosation of N,N-dialkyl amines to their corresponding nitroso derivatives under mild and heterogeneous conditions in good to excellent yields. 相似文献
272.
The paper discusses the applicability of quasi-crystalline approximation to describing the thermal motion of water molecules in their normal and supercooled states. The problem is subjected to the critical analysis of experimental data on incoherent scattering of slow neutrons based on theories developed by Singwi-Sjolander [1] and Oskotsky [2] modified to duly take into account the limited applicability range of diffusion approximation. The applicability conditions of quasi-crystalline approximation are shown to be consistently satisfied only when water is in supercooled state and within a narrow temperature range above the melting temperature. 相似文献
273.
The semiclassical theory of proximity effects predicts a gap E g~?D/L 2 in the excitation spectrum of a long diffusive superconductor/normal-metal/superconductor (SNS) junction. Mesoscopic fluctuations lead to anomalously localized states in the normal part of the junction.As a result, a nonzero, yet exponentially small, density of states (DOS) appears at energies below E g. In the framework of the supermatrix nonlinear σ model, these prelocalized states are due to the instanton configurations with broken supersymmetry. The exact result for the DOS near the semiclassical threshold is found, provided the dimensionless conductance of the normal part G N is large. The case of poorly transparent interfaces between the normal and superconductive regions is also considered. In this limit, the total number of subgap states may be large. 相似文献
274.
Pulse radiolysis with kinetic spectroscopic detection was applied to study the kinetics of the first steps of radiation induced polymerization of cyclohexyl acrylate and cyclohexyl methacrylate in cyclohexane solvent. The reactions were initiated by cyclohexyl radicals produced in the radiolysis of the solvent. The transient absorption spectra of the -carboxyalkyl type radicals produced in addition reaction show maxima around 300 nm. This shifts to longer wavelength with time after the pulse. This phenomenon was explained by the oligomerization reaction. From the kinetic curves average rate coefficients of termination for the oligomer radicals (2kt) were determined as a function of time elapsed after the electron pulse. The values obtained were compared with those calculated for other (acrylate and methacrylate type) monomers. 相似文献
275.
D. J. Plazek C. A. Bero S. Neumeister G. Floudas G. Fytas K. L. Ngai 《Colloid and polymer science》1994,272(11):1430-1438
By making creep and recoverable creep measurements of a nearly monodisperse low molecular weight poly(methyl phenyl siloxane) sample, we have found on decreasing temperature towardsT
g that there is continuously a change in the viscoelastic spectrum concomitant with a decrease of the steadystate recoverable compliance. This behavior is exactly the same as previously observed in low molecular weight poly(styrene), proving that this spectacular anomaly in the viscoelasticity of low molecular weight polymers is general and deserves an explanation. Photon correlation spectroscopic measurements performed on the same sample have extended the observation of the viscoelastic response to shorter times and the result corroborates the trend of variation established by the creep data.Dedicated to Prof.Dr. E. W. Fischer on his 65th Birthday. Prof.Dr. Fischer is known for his valuable contribution to fosterine, international collaboration of research in polymer science. This work is an example of his contribution because it would not be possible without him bringing us together. One of us (KLN) would like to take this opportunity to thank Prof. Dr. Fischer for his unwaiving support of the 1st (Crete) and the 2nd (Alicante) International Discussion Meeting on Relaxations in Complex Systems 相似文献
276.
An analysis is made of the conditions of formation and the stability region of static-soliton-type magnetic nonuniformities
in a (001)-crystal plate with combined anisotropy. It is shown that if demagnetizing fields in the plate are taken into account,
static solitons can localize at certain defects for appropriate parameters of the material. The soliton stability region was
found to be bounded by two extreme values of the material parameters, namely, those at which the soliton is unstable against
collapse and at which it expands. It was also found that the soliton stability region differs considerably from that predicted
theoretically in the model disregarding the finite size of the sample and the presence of defects.
Fiz. Tverd. Tela (St. Petersburg) 40, 1498–1502 (August 1998) 相似文献
277.
Experimental data on the effect of thallium and sodium impurities on the lattice heat conductivity of PbTe at room temperature
are reported. Because the lattice of lead chalcogenides is strongly polarized near charged impurities, the effect of impurities
on the lattice heat conductivity depends substantially on their charge state. This property of the material has been used
to determine the charge state of the thallium impurity in PbTe. The results obtained argue for a model of quasi-local thallium-impurity
states which assumes low electron-correlation energy at an impurity center.
Fiz. Tverd. Tela (St. Petersburg) 40, 1206–1208 (July 1998) 相似文献
278.
The lidar equation for the vibrational backscattering of neodymium laser radiation and its harmonics by hydrogen molecules
is solved numerically. Inclined paths in the atmosphere are investigated with the aim of selecting the transmitter wavelength
for detecting the lowest concentrations of hydrogen.
Zh. Tekh. Fiz. 68, 20–22 (January 1998) 相似文献
279.
280.
We use the eikonal approximation to develop a general formula for the cross sections of inelastic collisions of multicharged
fast ions (including relativistic ions) with atoms that is applicable within a broad range of collision energies, has the
standard nonrelativistic limit, and becomes, in the ultrarelativistic case, the well-known result that follows from the exact
solution of the Dirac equation. As an example we study the excitation and ionization of a hydrogenlike atom, the single and
double excitation and ionization of a heliumlike atom, and multiple (up to the eighth order) ionization of the neon atom and
(up to eighteenth order) ionization of the argon atom. We derive simple analytical expressions for the inelastic cross sections
and establish recurrence relations linking the cross sections of ionization of different orders. Finally, we compare our results
with the experimental data.
Zh. éksp. Teor. Fiz. 114, 1646–1660 (November 1998) 相似文献