全文获取类型
收费全文 | 533636篇 |
免费 | 3928篇 |
国内免费 | 1160篇 |
专业分类
化学 | 249245篇 |
晶体学 | 8124篇 |
力学 | 29976篇 |
综合类 | 14篇 |
数学 | 89538篇 |
物理学 | 161827篇 |
出版年
2021年 | 4101篇 |
2020年 | 4637篇 |
2019年 | 5507篇 |
2018年 | 17540篇 |
2017年 | 17582篇 |
2016年 | 16121篇 |
2015年 | 6004篇 |
2014年 | 9737篇 |
2013年 | 19780篇 |
2012年 | 18749篇 |
2011年 | 27958篇 |
2010年 | 19622篇 |
2009年 | 20172篇 |
2008年 | 23183篇 |
2007年 | 24906篇 |
2006年 | 15432篇 |
2005年 | 14568篇 |
2004年 | 14059篇 |
2003年 | 13609篇 |
2002年 | 12769篇 |
2001年 | 12987篇 |
2000年 | 10165篇 |
1999年 | 7587篇 |
1998年 | 6672篇 |
1997年 | 6491篇 |
1996年 | 6103篇 |
1995年 | 5485篇 |
1994年 | 5416篇 |
1993年 | 5308篇 |
1992年 | 5893篇 |
1991年 | 6146篇 |
1990年 | 6060篇 |
1989年 | 6067篇 |
1988年 | 5823篇 |
1987年 | 5891篇 |
1986年 | 5503篇 |
1985年 | 6650篇 |
1984年 | 6904篇 |
1983年 | 5672篇 |
1982年 | 5940篇 |
1981年 | 5693篇 |
1980年 | 5324篇 |
1979年 | 6095篇 |
1978年 | 6116篇 |
1977年 | 6344篇 |
1976年 | 6238篇 |
1975年 | 5738篇 |
1974年 | 5643篇 |
1973年 | 5708篇 |
1972年 | 4559篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
991.
Jonathan L. Sessler Patricia J. Melfi Anne E.V. Gorden Doris K. Ford C. Drew Tait 《Tetrahedron》2004,60(49):11089-11097
Hexaphyrin(1.0.1.0.0.0) (isoamethyrin) undergoes a significant color change in the presence of UO22+, PuO22+, and NpO22+. The complexation of the first of these dioxo actinide cations was studied in semi-quantitative fashion in 1:1 MeOH-CH2Cl2. Under these conditions, the detection limit for UO22+ was found to be ca. 5.8 ppm by naked eye monitoring and <28 ppb by UV-vis spectroscopy. Isoamethyrin does not undergo a color change in the presence of most transition metals or when exposed to Gd(III). Isoamethyrin thus constitutes an attractive alternative to 2,2′(1,8-dihydroxy-3,6-disulfonaphthylene-2,7-bisazo)-bisbenzenarsonic acid (AzIII) and 2-(5-bromo-2-pyridylazo)-5-(diethylamino)phenol (BrPADAP), systems currently used as actinide cation sensors. 相似文献
992.
Using radical chemistry novel highly condensed heterocycles have been synthesized. The mechanism for their formation is discussed. 相似文献
993.
994.
The interaction between multiple incompressible air jets has been studied numerically and experimentally. The numerical predictions have been first validated using experimental data for a single jet configuration. The spreading features of five unequal jets in the configuration of one larger central jet surrounded by four smaller equi‐distant jets, have been studied, for different lateral spacing ratios of 1.5, 2.0 and 2.5 and a central jet Reynolds number of 1.24×105 (corresponding to a Mach number of 0.16). Flow of five equal jets has also been simulated, for the sake of comparison. The jet interactions commence at an axial distance of about 3–4 diameters and complete by an axial distance of about 10 diameters for the lowest spacing ratio of 1.5. For larger spacing ratios, the length required for the start and completion of jet interaction increase. Peripheral jets bend more towards the central jet and merge at a smaller distance, when their sizes are smaller than that of the central jet. The entrainment ratio for multiple jets is higher than that for a single jet. Excellent agreement is observed between the experimental data and theoretical predictions for both mean flow field and turbulent quantities, at regions away from the jet inlet. The potential core length and initial jet development, however, are not predicted very accurately due to differences in the assumed and actual velocity profiles at the jet inlet. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
995.
K.B. Welter Q. Wu Y. You K. Abel D. McCreary S.M. Bajorek J.N. Reyes Jr 《International Journal of Multiphase Flow》2004,30(12):407-1484
This article describes a comprehensive literature review of liquid entrainment in horizontal pipes with vertical-up branches. Deficiencies in the available data and correlations were identified. The Air–water Test Loop for Advanced Thermal–hydraulic Studies (ATLATS) was constructed and entrainment onset and steady-state data were collected for a wide range of flow conditions. Using new insights gained from experimental testing, the authors developed a model for predicting the onset of entrainment and steady-state entrainment rate. Previously published correlations, along with the new model, are compared against all available data. The new model shows very good agreement with the onset data, but is not very good at predicting branch quality at high liquid flow rates. 相似文献
996.
A technique is described for the measurement of all components of mean velocity and Reynolds stresses, in a complex turbulent flow where achieving coincidence data acquisition is difficult. The method is based on data recorded using four orientations of the laser probe. It is shown that the measurement errors are not the same for all the components of the Reynolds tensor, but they are sufficiently small to give a good accuracy. An application to a turbomachinery flow is given to illustrate the method. 相似文献
997.
A novel super-hydrophobic stearic acid (STA) film with a water contact angle of 166o was prepared by chemical adsorption on aluminum wafer coated with polyethyleneimine (PEI) film. The micro-tribological behavior
of the super-hydrophobic STA monolayer was compared with that of the polished and PEI-coated Al surfaces. The effect of relative
humidity on the adhesion and friction was investigated as well. It was found that the STA monolayer showed decreased friction,
while the adhesive force was greatly decreased by increasing the surface roughness of the Al wafer to reduce the contact area
between the atomic force microscope (AFM) tip and the sample surface to be tested. Thus the friction and adhesion of the Al
wafer was effectively decreased by generating the STA monolayer, which indicated that it could be feasible and rational to
prepare a surface with good adhesion resistance and lubricity by properly controlling the surface morphology and the chemical
composition. Both the adhesion and friction decreased as the relative humidity was lowered from 65% to 10%, though the decrease
extent became insignificant for the STA monolayer.
The project supported by the National Natural Science Foundation of China (50375151, 50323007, 10225209) and the Chinese Academy
of Sciences (KJCX-SW-L2) 相似文献
998.
The flowfield over a blunt-nosed cylinder was examined experimentally at a low subsonic speed for Re=1.88×105 and angles of attack up to 40°. Velocity measurements were carried out (employing a seven-hole Pitot tube) as well as wall static pressure and wall shear-stress measurements. Surface flow visualization was applied using liquid crystals and a mixture of oil–TiO2. For all the examined cases no flow asymmetries were found. For high angles of attack (20° and above) a separation “bubble” appears at the leeside of the nose area (streamwise flow separation). The basic feature of the circumferential pressure distribution at the after body area for these angles of attack is a plateau close to the suction peak and a fast recovery next to it. One streamwise vortex on each side of the symmetry plane is formed as well as a separation bubble about 90° far from this plane, where the cross-flow primary separation line is located. Each cross-flow primary separation line starts at the leeside nose area and moves towards the windward side along the cylindrical after body. The space between the two primary separation lines close to the wall is characterized by high flow fluctuations on the leeside, compared to the low fluctuations of the windward side. 相似文献
999.
G. Giardina G. Fazio A. Lamberto A. I. Muminov A. K. Nasirov U. T. Yakhshiev R. Palamara R. Ruggeri 《Acta Physica Hungarica A》2004,19(1-2):101-108
We study the effect of the entrance channel and the shell structure of reacting massive nuclei on the fusion mechanism and the formation of evaporation residues of heavy and superheavy nuclei. In the framework of the combined dinuclear system concept and advanced statistical model, we analyze the reactions 32S+182W, 48Ti+166Er and 60Ni+154Sm leading to 214Th*, and the reactions 48Ca+248Cm and the 48Ca+249Cf leading to the 296116 and 297118 compound nuclei, respectively. 相似文献
1000.
We carried out detailed calculations for photorefractive wave-mixing switches based on one of three crystals with high electro-optic coefficients, namely, BaTiO3, Strontium Barium Niobate (SBN (0.75)), and Potasium Sodium Strontium Barium Niobate (KNSBN). A comparison of results for the three crystals shows that a 0_-cut BaTiO3 crystal is suitable for a longitudinal switch and requires a voltage of about 80 for a 2-mm-thick crystal to induce sufficient phase mismatch. The electrodes must be transparent for the incident and diffracted beams. A 45_-cut SBN (0.75) crystal, however, is suitable for a lateral switch and requires a voltage of about 150 for a 1-mm-wide crystal. The electrodes do not need to be transparent. 相似文献