Determination of the number of ψ' events at BES Ⅲ

The number of ψ' events accumulated by the BESⅢ experiment from March 3 through April 14, 2009, is determined by counting inclusive hadronic events. The result is 106.41×(1.00±0.81%)×106 . The error is systematic dominant; the statistical error is negligible.     

ηπ+ π- resonant structure around 1.8 GeV/c(2) and η(1405) in J/ψ → ωηπ+ π-

We present results of a study of the decay J/ψ → ωηπ+ π- using a sample of (225.2 ± 2.8) × 10(6) J/ψ events collected by the BESIII detector, and report the observation of a new process J/ψ → ωX(1870) with a statistical significance of 7.2σ, in which X(1870) decays to a(0)(±)(980)π±. Fitting to ηπ+ π- mass spectrum yields a mass M = 1877.3 ± 6.3(stat)(-7.4)(+3.4)(syst) MeV/c(2), a width Γ = 57 ± 12(stat)(-4)(+19)(syst) MeV/c(2), and a product branching fraction B(J/ψ → ωX) × B(X→a(0)(±)(980)π±) × B(a(0) (±)(980) → ηπ±) = [1.50 ± 0.26(stat)(-0.36)(+0.72) (syst)] × 10(-4). Signals for J/ψ → ωf(1)(1285) and J/ψ → ω η(1405) are also clearly observed and measured.     

N=2超对称量子力学的新实现和形状不变性

构造新的超荷和定义权重函数,并研究了N=2一维超对称量子力学.在新的实现中讨论了若干实例.     

Synthesis of Polycyclic Aromatic Hydrocarbons by Phenyl Addition–Dehydrocyclization: The Third Way

Polycyclic aromatic hydrocarbons (PAHs) represent the link between resonance‐stabilized free radicals and carbonaceous nanoparticles generated in incomplete combustion processes and in circumstellar envelopes of carbon rich asymptotic giant branch (AGB) stars. Although these PAHs resemble building blocks of complex carbonaceous nanostructures, their fundamental formation mechanisms have remained elusive. By exploring these reaction mechanisms of the phenyl radical with biphenyl/naphthalene theoretically and experimentally, we provide compelling evidence on a novel phenyl‐addition/dehydrocyclization (PAC) pathway leading to prototype PAHs: triphenylene and fluoranthene. PAC operates efficiently at high temperatures leading through rapid molecular mass growth processes to complex aromatic structures, which are difficult to synthesize by traditional pathways such as hydrogen‐abstraction/acetylene‐addition. The elucidation of the fundamental reactions leading to PAHs is necessary to facilitate an understanding of the origin and evolution of the molecular universe and of carbon in our galaxy.     

Reactivity of the Indenyl Radical (C9H7) with Acetylene (C2H2) and Vinylacetylene (C4H4)

The reactions of the indenyl radicals with acetylene (C₂H₂) and vinylacetylene (C₄H₄) is studied in a hot chemical reactor coupled to synchrotron based vacuum ultraviolet ionization mass spectrometry. These experimental results are combined with theory to reveal that the resonantly stabilized and thermodynamically most stable 1-indenyl radical (C₉H₇^.) is always formed in the pyrolysis of 1-, 2-, 6-, and 7-bromoindenes at 1500 K. The 1-indenyl radical reacts with acetylene yielding 1-ethynylindene plus atomic hydrogen, rather than adding a second acetylene molecule and leading to ring closure and formation of fluorene as observed in other reaction mechanisms such as the hydrogen abstraction acetylene addition or hydrogen abstraction vinylacetylene addition pathways. While this reaction mechanism is analogous to the bimolecular reaction between the phenyl radical (C₆H₅^.) and acetylene forming phenylacetylene (C₆H₅CCH), the 1-indenyl+acetylene→1-ethynylindene+hydrogen reaction is highly endoergic (114 kJ mol⁻¹) and slow, contrary to the exoergic (−38 kJ mol⁻¹) and faster phenyl+acetylene→phenylacetylene+hydrogen reaction. In a similar manner, no ring closure leading to fluorene formation was observed in the reaction of 1-indenyl radical with vinylacetylene. These experimental results are explained through rate constant calculations based on theoretically derived potential energy surfaces.     

C36X(X=O,NH,S)各种可能异构体的芳香性研究

采用拓扑共振能方法对富勒烯C36X(X=O,NH,S)开环结构中的所有可能的异构体及阳离子和阴离子芳香性进行了理论研究. 计算结果表明,C36X的芳香性高于C36. C36X的阳离子因其共振能为负值而具有反芳香性. 反之,C36X的阴离子因共振能为正值而具有芳香性和较高的稳定性. C36的D6h和D2d异构体中杂原子X插入在5-5键时得到的化合物最稳定. 从理论上预测了C36X的负离子能形成稳定的金属富勒烯. 对C36X的阳离子和阴离子的芳香性进行了解释.     

Measurement of psi2S radiative decays

Using 14 x 10(6) psi(2S) events accumulated at the BESII detector, we report first measurements of branching fractions or upper limits for psi(2S) decays into gammapp, gamma2(pi+pi-), gammaKS0K+pi-+c.c., gammaK+K-pi+pi-, gammaK*0K-pi++c.c., gammaK*0K*0, gammapi+pi-pp, gamma2(K+K-), gamma3(pi+pi-), and gamma2(pi+pi-)K+K- with the invariant mass of hadrons below 2.9 GeV/c2. We also report branching fractions of psi(2S) decays into 2(pi+pi-)pi0, omegapi+pi-, omegaf2(1270), b1+/-pi-/+, and pi02(pi+pi-)K+K-.     

Organic Light‐Emitting Diodes Using a Neutral π Radical as Emitter: The Emission from a Doublet

Triplet harvesting is a main challenge in organic light‐emitting devices (OLEDs), because the radiative decay of the triplet is spin‐forbidden. Here, we propose a new kind of OLED, in which an organic open‐shell molecule, (4‐N‐carbazolyl‐2,6‐dichlorophenyl)bis(2,4,6‐trichlorophenyl)methyl (TTM‐1Cz) radical, is used as an emitter, to circumvent the transition problem of triplet. For TTM‐1Cz, there is only one unpaired electron in the highest singly occupied molecular orbital (SOMO). When this electron is excited to the lowest singly unoccupied molecular orbital (SUMO), the SOMO is empty. Thus, transition back of the excited electron to the SOMO is totally spin‐allowed. Spectral analysis showed that electroluminescence of the OLED originated from the electron transition between SUMO and SOMO. The magneto‐electroluminescence measurements revealed that the spin configuration of the excited state of TTM‐1Cz is a doublet. Our results pave a new way to obtain 100 % internal quantum efficiency of OLEDs.     

Evolution of emission manners of organic light-emitting diodes: From emission of singlet exciton to emission of doublet exciton

The emission manners of organic light-emitting diodes(OLEDs) have experienced almost three-decade evolution.In this review,we briefly summarized the emission manners of OLEDs including:(ⅰ) emission from singlet exciton;(ⅱ) emission from triplet exciton;(ⅲ) emission from singlet exciton converted from triplet exciton.Then we introduced a new type of OLEDs with the emission from doublet exciton,wherein organic neutral radicals are used as emitters.Due to the spin-allowed transition of doublet excitons,using neutral radicals as emitters is believed to be a new way to break the 25%upper limit of internal quantum efficiency of OLEDs.The progress of emissive stable neutral radicals is also shortly reviewed.     

Observation of a near-threshold enhancement in the omega(phi) mass spectrum from the doubly OZI-suppressed decay J/psi-->gamma(omega)phi

An enhancement near threshold is observed in the omega(phi) invariant mass spectrum from the doubly Okubo-Zweig-Iizuka-suppressed decays of J/psi-->gamma(omega)phi, based on a sample of 5.8 x 10(7) J/psi events collected with the BESII detector. A partial wave analysis shows that this enhancement favors JP=0+, and its mass and width are M=1812(+19)(-26)(stat)+/-18(syst) MeV/c2 and Gamma=105+/-20(stat)+/-28(syst) MeV/c2. The product branching fraction is determined to be B(J/psi-->gammaX)B(X-->omega(phi))=[2.61+/-0.27(stat)+/-0.65(syst)]x10(-4).