全文获取类型
收费全文 | 890篇 |
免费 | 30篇 |
专业分类
化学 | 795篇 |
晶体学 | 2篇 |
力学 | 16篇 |
数学 | 22篇 |
物理学 | 85篇 |
出版年
2022年 | 8篇 |
2021年 | 12篇 |
2020年 | 35篇 |
2019年 | 20篇 |
2018年 | 5篇 |
2017年 | 9篇 |
2016年 | 24篇 |
2015年 | 20篇 |
2014年 | 21篇 |
2013年 | 35篇 |
2012年 | 48篇 |
2011年 | 55篇 |
2010年 | 37篇 |
2009年 | 22篇 |
2008年 | 66篇 |
2007年 | 57篇 |
2006年 | 53篇 |
2005年 | 48篇 |
2004年 | 42篇 |
2003年 | 23篇 |
2002年 | 24篇 |
2001年 | 14篇 |
2000年 | 24篇 |
1999年 | 14篇 |
1998年 | 11篇 |
1997年 | 6篇 |
1996年 | 15篇 |
1995年 | 9篇 |
1994年 | 12篇 |
1993年 | 16篇 |
1992年 | 10篇 |
1991年 | 6篇 |
1990年 | 13篇 |
1989年 | 11篇 |
1988年 | 8篇 |
1987年 | 7篇 |
1986年 | 7篇 |
1985年 | 6篇 |
1984年 | 4篇 |
1983年 | 5篇 |
1982年 | 4篇 |
1981年 | 4篇 |
1979年 | 6篇 |
1978年 | 3篇 |
1976年 | 3篇 |
1973年 | 8篇 |
1972年 | 3篇 |
1967年 | 3篇 |
1942年 | 2篇 |
1866年 | 7篇 |
排序方式: 共有920条查询结果,搜索用时 0 毫秒
91.
92.
Birkel CS Kieslich G Bessas D Claudio T Branscheid R Kolb U Panthöfer M Hermann RP Tremel W 《Inorganic chemistry》2011,50(22):11807-11812
Understanding how solids form is a challenging task, and few strategies allow for elucidation of reaction pathways that are useful for designing the synthesis of solids. Here, we report a powerful solution-mediated approach for formation of nanocrystals of the thermoelectrically promising FeSb(2) that uses activated metal nanoparticles as precursors. The small particle size of the reactants ensures minimum diffusion paths, low activation barriers, and low reaction temperatures, thereby eliminating solid-solid diffusion as the rate-limiting step in conventional bulk-scale solid-state synthesis. A time- and temperature-dependent study of formation of nanoparticular FeSb(2) by X-ray powder diffraction and iron-57 M?ssbauer spectroscopy showed the incipient formation of the binary phase in the temperature range of 200-250 °C. 相似文献
93.
Andreas Hilgeroth Günter Hempel Ute Baumeister Detlef Reichert 《Solid state nuclear magnetic resonance》1999,13(4):4125-243
13C CPMAS NMR spectroscopy has been applied to monitor the solid-state reaction of two different photodimerizing 4-phenyl-1,4-dihydropyridines yielding a cage dimer in one case and an anti-dimer in the other case. The spectra of the reacting monomers exhibit a magnetical inequivalence of chemically equivalent CO and C2/4 carbon atoms caused by a rotation of the pseudoaxially oriented 4-phenyl substituent out off the plane through N1, C3, C8 which could be determined by X-ray crystal structure analyses of the centrosymmetrically arranged monomers. The 13C CPMAS NMR monitoring of the cage dimer formation proves that the reaction takes place in two steps via a syn-dimer for which a non-symmetrical structure was derived from the spectrum. The non-symmetrical structure was confirmed by X-ray crystal structure analysis of one structurally related derivative. A centrosymmetric structure for both the finally formed cage dimer and the anti-dimer of the other monitored photoreaction was proved by their spectra with one set of signals for each half of the dimers, respectively. Thus, conformational properties of the molecules as well as the symmetry of the products can be directly derived from the 13C CPMAS NMR spectra. 相似文献
94.
An isotope dilution technique using enriched stable isotopes is applied to determine the interchangeable heavy-metal fraction
in soils. Metals in two soil samples are extracted at constant pH, with water, NH4NO3, and EDTA. A spike of enriched stable isotopes is added to the suspension of sample and eluant at the beginning of the extraction.
The heavy-metal fraction which exchanges with the added spike during the extraction is called the interchangeable fraction.
The extractable heavy-metal fractions are obtained from the heavy-metal concentrations in the eluates. Isotope ratios and
concentrations are determined by HR-ICP-MS. The isotope dilution technique described enables both the extractable and the
interchangeable heavy-metal fractions to be determined in the same experiment. The combination of both results gives additional
information on elemental availability under different conditions that cannot be obtained by analyzing the extractable heavy-metal
fractions alone. It is demonstrated that in some cases different eluants just shift the distribution of the interchangeable
fraction of an element between the solid and liquid phases (e.g., Pb and Cd in a topsoil sample) while the amount of the interchangeable
fraction itself remains constant. For other elements, as Ni, Zn, and Cr, the use of different eluants (different pH, complexing
agents) sometimes enlarges the interchangeable fraction.
Received: 8 December 1998 / Revised: 30 June 1999 / Accepted: 2 July 1999 相似文献
95.
96.
Ingo Brasack Horst Böttcher Ute Hempel 《Journal of Sol-Gel Science and Technology》2000,19(1-3):479-482
Biocomposite layers of silica and various bone-relevant proteins such as collagen, gelatine and commercial collagen hydrolysate can be obtained from coatings of silica sols mixed with proteins in water/dioxane. Investigations into the mechanical and cell proliferation properties for different sol parameters (pH, solvent), type and concentration of proteins, annealing and crosslinking of the biocomposite layers revealed that such coatings are highly biocompatible with excellent mechanical properties. 相似文献
97.
A system of independent electrons interacting with an arbitrary number of fixed point scatterers on the surface of an infinitely long cylinder is considered. It is shown that (at zero temperature) the equilibrium Byers-Yang Hall current takes the same value as for free electrons if the Fermi energy lies in an energy gap. 相似文献
98.
99.
100.