Efficient, multiwatt, continuous-wave laser operation on the (4)F((3/2))-(4)I((9/2)) transitions of Nd:YVO(4) and Nd:YAG

We report multiwatt, diode-pumped cw operation on the (4)F(3/2)-(4)I(9/2) laser transition at 914.5 nm in Nd:YVO(4), for which an output power of 3.0 W and a slope of efficiency of 22.8% were achieved. For the corresponding laser transition of Nd:YAG at 946 nm an output power of 5.35 W and a slope efficiency of 40.2% were measured. By intracavity frequency doubling, an output power of 1.5 W at 473 nm was generated.     

Investigating the effect of nanolayered silicates on blend segmental dynamics and minor component relaxation behavior in poly(ethylene oxide)/poly(methyl methacrylate) miscible blends

Polymer–silicate nanocomposites based on poly (ethylene oxide), PEO, poly(methyl methacrylate), PMMA, and sodium montmorillonite clay were fabricated and characterized to investigate the effect of nanolayered silicates on segmental dynamics of PEO/PMMA blends. X‐ray results indicate the formation of an exfoliated morphology in the nanocomposites. At low silicate contents, an enhancement in segmental dynamics of blend nanocomposites and also PEO, minor component in blend, is observed at temperature region below blend glass transition. This result can be attributed to the improvement of the confinement effect of rigid PMMA matrix on the PEO chains by introducing a low amount of layered silicates. On the other hand, at high silicate contents, an enhancement in segmental dynamics of blend nanocomposites and PEO is observed at temperature region above blend glass transition. This behavior could be interpreted based on the reduction of monomeric friction between two polymer components, which can facilitate segmental motions of blend components in nanocomposite systems. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2011     

Kalender-Formeln

Ohne Zusammenfassung     

Ueber Nachweis und Bestimmung von Jod

Ohne Zusammenfassung     

Steviosid aus Süßkraut

The diterpene glycoside stevioside is the most abundant among a group of sweet steviol glycosides, present in sweetleaf (Stevia rebaudiana), which is naturally occurring in Paraguay. It has already been used by the Guarani Indians as a sweetener. Since 2011 such “steviosides” have an EU approval as sweeteners E 960. They taste ca. 250 times sweeter than sucrose. Meanwhile, they have got a significant recognition, not least due to their use in Coca Cola life®. We describe the isolation of stevioside and rebaudioside A from dried leaves of the sweetleaf plant. The complete set of spectra for stevioside is reported. Based on students' laboratory work this project is a follow up of the book “Classics in Spectroscopy” by S. Berger und D. Sicker (Wiley‐VCH 2009).     

Zur Bestimmung der Verwölbungen und Profilverformungen von elastischen Stäben mit beliebigen und dünnwandigen Querschnitten

Übersicht Eine bereits vorgestellte Theorie, die eine schrittweise Bestimmung der Verwölbungen und Profilverformungen von Stäben mit beliebiger Querschnittsform ermöglicht, wird zusammengefaßt und hinsichtlich des Problems gekoppelter Biegung und Torsion erweitert. Dabei wird auf einer allgemeinen Approximationsstufe die Lage des Schub und Drillruhepunkts für das zugehörige Verwölbungsproblem angegeben und die Einführung von Hilfskräften zur Erzeugung von Gleichgewichtszuständen für das zugehörige Profilverformungsproblem erörtert. Die Theorie wird anschließend auf Stäbe mit dünnwandigen Querschnitten spezialisiert, Beispiele aus der Ingenieurpraxis sollen die Anwendbarkeit des Verfahrens zeigen.

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On the determination of cross-sectional warpings and distortions of bars with arbitrary and thin-walled cross-sections

Summary An already presented theory which allows for a stepwise determination of cross-sectional warpings and distortions of bars with arbitrary cross-sections is summarized and extended with respect to the problem of coupled bending and torsion. On a general approximation level the locations of the shear centers due to bending and torsion are given for the corresponding warping problem and the introduction of auxiliary forces in order to get equilibrated states of stress is discussed for the corresponding distortional problem. The theory is then specialized to bars with thin-walled cross-sections. Examples from the engineering practice shall demonstrate the applicability of the method.

     

Coordination networks from Cu cations and tetrakis(methylthio)benzenedicarboxylic acid: tunable bonding patterns and selective sensing for NH(3) gas

This paper aims to illustrate the rich potential of the thioether-carboxyl combination in generating coordination networks with tunable and interesting structural features. By simply varying the ratio between Cu(NO(3))(2) and the bifunctional ligand tetrakis(methylthio)benzenedicarboxylic acid (TMBD) as the reactants, three coordination networks can be hydrothermally synthesized in substantial yields, which present a distinct evolution with regard to metal-ligand interactions. Specifically, Cu(TMBD)(0.5)(H(2)TMBD)(0.5)·H(2)TMBD (1) was obtained with a relatively small (1:1) Cu(NO(3))(2)/TMBD ratio, and crystallizes as an one-dimensional (1D) coordination assembly based on Cu(I)-thioether interactions, which is integrated by hydrogen-bonding to additional H(2)TMBD molecules to form a three-dimensional (3D) composite network with all the carboxylic acid and carboxylate groups remaining uncoordinated to the metal ions. A medium (1.25:1) Cu(NO(3))(2)/TMBD ratio leads to compound Cu(2)TMBD, in which Cu(I) ions simultaneously bond to the carboxylate and thioether groups, while an even higher (2.4:1) Cu(NO(3))(2)/TMBD ratio produced a mixed-cation compound Cu(II)(2)OHCu(I)(TMBD)(2)·2H(2)O (2), in which the carboxylic groups are bonded to (cupric) Cu(II) ions, and the thioether groups to Cu(I). Despite the lack of open channels in 2, crystallites of this compound exhibit a distinct and selective absorption of NH(3), with a concomitant color change from green to blue, indicating substantial network flexibility and dynamics with regards to gas transport.     

Binary nucleation rates for ethanol/water mixtures in supersonic Laval nozzles

Although the conditions corresponding to the onset of condensation of aqueous-alcohol mixtures have been measured in supersonic nozzles [B. E. Wyslouzil et al., J. Chem. Phys. 113, 7317 (2000)], the true nucleation rates have not. Here, we propose a new analytical method to estimate the temperature, the concentrations of condensable species in both the vapor and the liquid phases, and the amount of the condensate using only the measured static pressure profiles in the nozzle. We applied the method to ethanol/water (CH(3)CH(2)OH/D(2)O or CH(3)CH(2)OD/D(2)O) mixtures and confirmed that the aerosol volume fractions derived from pressure measurements and small angle neutron scattering measurements are in very good agreement when this method is used. Combining the results from the pressure measurements with the number densities of the condensed droplets, measured either by small angle neutron or small angle x-ray scattering, we determined the first quantitative ethanol/water binary nucleation rates in the supersonic nozzle at a temperature of 229±1?K.     

Very Low Energy Electrons Transform the Cyclobutane‐Pyrimidine Dimer into a Highly Reactive Intermediate

Electrons with virtually no kinetic energy (close to 0 eV) trigger the decomposition of cytotoxic cyclobutane‐pyrimidine dimer (CPD) into a surprisingly large variety of fragment ions plus their neutral counterparts. The response of CPD to low energy electrons is thus comparable to that of explosives like trinitrotoluene (TNT). The dominant unimolecular reaction is the splitting into two thymine like units, which can be considered as the essential molecular step in the photolyase of CPD. We find that CPD is significantly more sensitive towards low energy electrons than its thymine building blocks. It is proposed that electron attachment at very low energy proceeds via dipole bound states, supported by the large dipole moment of the molecule (6.2 D). These states act as effective doorways to dissociative electron attachment (DEA).