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71.
This work presents spectroscopic studies and electrochemical characterization of Cu(II)—dicyandiamide (DCDA) complex formation. The range of conditions leading to the precipitation of the complex is significantly larger than that presented in the literature. In all cases the stoichiometry of the compound is: [Cu(DCDA)2(SO4)(H2O)5). The spectroscopic data suggest that DCDA is a monodentate ligand forming a bond with Cu2+ via the nitryl nitrogen. Electroreduction of this complex is a two-step process occurring through a Cu(I)—DCDA intermediate. 相似文献
72.
Urszula Kosikowska Monika Wujec Nazar Trotsko Wojciech Ponka Piotr Paneth Agata Paneth 《Molecules (Basel, Switzerland)》2021,26(1)
The development of drug-resistant bacteria is currently one of the major challenges in medicine. Therefore, the discovery of novel lead structures for the design of antibacterial drugs is urgently needed. In this structure–activity relationship study, a library of ortho-, meta-, and para-fluorobenzoylthiosemicarbazides, and their cyclic analogues with 1,2,4-triazole scaffold, was created and tested for antibacterial activity against Gram-positive bacteria strains. While all tested 1,2,4-triazoles were devoid of potent activity, the antibacterial response of the thiosemicarbazides was highly dependent on substitution pattern at the N4 aryl position. The optimum activity for these compounds was found for trifluoromethyl derivatives such as 15a, 15b, and 16b, which were active against both the reference strains panel, and pathogenic methicillin-sensitive and methicillin-resistant Staphylococcus aureus clinical isolates at minimal inhibitory concentrations (MICs) ranging from 7.82 to 31.25 μg/mL. Based on the binding affinities obtained from docking, the conclusion can be reached that fluorobenzoylthiosemicarbazides can be considered as potential allosteric d-alanyl-d-alanine ligase inhibitors. 相似文献
73.
Hoffmann M Plutecka A Rychlewska U Kucybala Z Paczkowski J Pyszka I 《The journal of physical chemistry. A》2005,109(20):4568-4574
New bis(imidazo)pyridine dye has been synthesized and tested as a potential photoinitaitor for free-radical polymerization induced with the visible emission of an argon ion laser. The X-ray analysis based on data collected at 170 and 130 K, as well as density functional theory (DFT) calculations, revealed the presence of two different forms of imidazopyridine rings within the same molecule. These two forms of the same moiety had not only different geometries but different electronic structures as well. One of the imidazopyridine rings was in the ionic form, while the other was in the meso-ionic form. DFT calculations provided an explanation for such an observed phenomena. The averaging of ionic and meso-ionic forms of imidazopyridine rings within the same molecule is hindered because of an attractive interaction between them. Analysis of electronic density revealed that, indeed, a new type of bonding is formed as the result of an overlap between pi aromatic and pi C=O molecular orbitals. This bonding, like the hydrogen bond, is primarily of electrostatic character, and its energy was estimated at 3.5 kcal/mol. 相似文献
74.
Cherng-Chyi Tzeng Urszula Rychlewska Derek J. Hodgson Raymond P. Panzica 《Journal of heterocyclic chemistry》1986,23(1):33-42
The first examples of the unknown pyrazino[2,3-e]-as-triazine ring system, that is, the 6,7-dihydroxy-5,6,7,8-tetrahydropyrazino[2,3-e]-as-triazines, have been prepared by ring closure of selected 5,6-diamino-as-triazines with 40% aqueous glyoxal. These 4-azapteridines experience a novel exchange process with alcohols at the C(7)-position. When dissolved in alcohol and stirred at room temperature, the 7-alkoxy, 6-hydroxy analogues are formed and isolated. In fact, during ring closure, if alcohols are used as the solvent, only the latter compounds are obtained. Initially, cyclization of the ortho-diamino-as-triazines with glyoxal proceeds in a stereoselective manner giving rise to both the cis and trans adducts. A single-crystal X-ray diffraction study has determined the predominant and most stable adduct to be the trans (R,R or S,S) isomer. Spectroscopy (nmr) has verified the intermediacy of the cis adduct, but because of the aforementioned exchange process only the trans isomer is isolated. The site of exchange on these σ-adducts has been rigorously established as C(7). A plausible reaction mechanism by which this exchange process occurs is presented. 相似文献
75.
Foldamer population of imide triads derived from (R,R)-1,2-diaminocyclohexane was studied with the use of 1H NMR and CD spectroscopy, as well as computational modeling. Two stable foldamers of C and S shape, having correspondingly M and P helicity, are found to differ very little in energy. However, their interaction with the solvent results in significant shift of the equilibrium. For the interaction with aromatic solvent molecules a sandwich-type donor-acceptor model, stabilizing the S foldamer, is proposed. The limitations of the NMR and CD methods for studying the foldamer equilibrium in solution are discussed, pointing to the inadequacy of static computational models of CD spectra, not including the effect of rotation of the imide chromophores in the dynamic model of real molecules. 相似文献
76.
Determination of thermodynamic properties of isotactic poly(1-butene) at infinite dilution using density and inverse gas chromatography 总被引:2,自引:0,他引:2
The partial molar volumes, V1(M), and the molar volume of isotactic crystalline low-molecular-weight poly(1-butene), iPBu-1, V1, have been calculated from the measured density of {iPBu-1 + solvent (n-hexane, n-heptane, n-nonane, n-decane, p-xylene, cyclohexane and chloroform)} systems. Some of the thermodynamic quantities were also obtained for the iPBu-1 with eight hydrocarbons (n-octane, n-decane, n-undecane, n-dodecane, n-tridecane, o-xylene, m-xylene, p-xylene) by the method of inverse gas chromatography at various temperatures. The weight fraction activity coefficients of the solvent at infinite dilution, omega2(infinity) and the Flory-Huggins thermodynamic interaction parameters, chi21(infinity), between polymer and solvents were determined. The partial molar free energy, deltaG2(infinity), the partial molar heat of mixing, deltaH2(infinity), at infinite dilution and the polymer solubility parameter, delta1, were calculated. Additionally, the (solid + liquid) binary mixtures equilibria, SLE, of iPBu-1 with three hydrocarbons (n-octane, n-decane and m-xylene) were studied by a dynamic method. By performing these experiments over a large concentration range, the T-x phase diagrams of the polymer-solvent systems were constructed. The excess Gibbs energy models were used to describe the nonideal behaviour of the liquid phase. The omega2(infinity) were determined from the solubility measurements and were predicted by using the UNIFAC FV model. 相似文献
77.
Gawroński J Brzostowska M Kwit M Plutecka A Rychlewska U 《The Journal of organic chemistry》2005,70(24):10147-10150
[reaction: see text] Rhombimines, chiral macrocyclic tetraimines, are preferentially formed because of the structural bias in the reaction of aromatic ether-linked dialdehydes with enantiomerically pure trans-1,2-diaminocyclohexane. 相似文献
78.
The liquid–liquid equilibrium (LLE), or solid–liquid equilibrium (SLE) of more than 20 binary systems containing 1-hexyloxymethyl-3-methyl-imidazolium bis(trifluoromethylsulfonyl)-imide [C6H13OCH2MIM][Tf2N] with alcohol (butan-1-ol, or hexan-1-ol, or octan-1-ol), water and ketone (3-pentanone, or cyclopentanone) and of 1-hexyloxymethyl-3-methyl-imidazolium tetrafluoroborate [C6H13OCH2MIM][BF4] with alcohol (methanol, or ethanol, or butan-1-ol, or hexan-1-ol, or octan-1-ol), water and ketone (3-pentanone, or cyclopentanone) have been measured. The solubility of dialkoxy-imidazolium salts: (1) 1,3-dihexyloxymethyl-imidazolium bis(trifluoromethylsulfonyl)-imide [(C6H13OCH2)2IM][Tf2N] in alcohol (butan-1-ol, or hexan-1-ol, or octan-1-ol, or decan-1-ol), in water and hydrocarbon (benzene, hexane and cyclohexane); (2) 1,3-dihexyloxymethyl-imidazolium tetrafluoroborate [(C6H13OCH2)2IM][BF4] in alcohol (hexan-1-ol, or octan-1-ol, or decan-1-ol) and water have been measured. Measurements were carried out by using a dynamic method from T = 275 K to the boiling point of the solvent. In this work a systematic study of the impact of different factors on the phase behaviour of hexyloxy-imidazolium-based ionic liquids with polar and nonpolar solvents has been presented. Most of the examined systems showed immiscibility in the liquid phase with an upper critical solution temperature (UCST), or complete solubility of the ionic liquid at room temperature in many solvents. An increase in the alkyl chain length of alcohol resulted in an increase in the UCST. The choice of anion was shown to have large impact on the solubility: by changing the anion [Tf2N]− to [BF4]−, the solubility dramatically decreased and the UCST increased. By contrast, increasing hydrogen bonding opportunities with the solvent by replacing a methyl group with the second alkoxy-group on the imidazolium ring results in an increase of the solubility. 相似文献
79.
Iwona Włoch Urszula Bednarz Dorota Bród Andrzej Włoch Małgorzata Wołowiec-Musiał 《Discrete Applied Mathematics》2013,161(16-17):2695-2701
In this paper, we define a new kind of Fibonacci numbers generalized in the distance sense. This generalization is related to distance Fibonacci numbers and distance Lucas numbers, introduced quite recently. We also study distinct properties of these numbers for negative integers. Their representations and interpretations in graphs are also studied. 相似文献
80.
Agnieszka Plutecka Urszula Rychlewska 《Acta Crystallographica. Section C, Structural Chemistry》2009,65(2):m75-m77
The three‐dimensional metal–organic framework poly[bis(dimethylammonium) [hexa‐μ2‐formato‐κ12O:O′‐aluminium(III)sodium(I)]], {(C6H8N)2[AlNa(HCOO)6]}n, was obtained serendipitously and has been characterized by X‐ray diffraction. The product has arisen as a result of a hydrolysis reaction of dimethylformamide (DMF) and contains dimethylammonium (DMA) cations included in structural voids formed by a three‐dimensional [AlNa(HCOO)6]− network. This study provides evidence that, in the presence of traces of aluminium, DMF stored in a glass bottle can be hydrolysed to formate and dimethylamine with simultaneous extraction of Na+ cations from the glass. It also demonstrates that care must be taken regarding the metal and water content when DMF is not freshly distilled, since the hydrolysis of amide can occur. 相似文献