Novel trisubstituted pyrido[3,2-e][1,2,4]triazines have been found to possess similar biological activity to the corresponding pyridopyrazine fungicides against important phytopathogens such as Mycosphaerella graminicola (wheat leaf blotch), Magnaporthe grisea (rice blast), and Rhizoctonia solani (rice sheath blight). They have been prepared for the first time from a monocyclic triazine by Niementowski-type ring condensation. 相似文献
A new metal borophosphate PbII4{Co2[B(OH)2P2O8](PO4)2}Cl ( 1 ), containing both Pb2+ cations and Cl– anions, was hydrothermally synthesized and characterized by powder X‐ray diffraction, ICP, TG/DTA, and FTIR spectroscopic analyses. The crystal structure determination from single‐crystal X‐ray diffraction reveals that compound 1 crystallizes in the trigonal space group Rc (No. 167), a = 9.7513(7) Å, c = 91.060(13) Å, V = 7498.7(13) Å3 and Z = 18. Its structure features a new cobalt borophosphate layer {Co2[B(OH)2P2O8](PO4)2}7– built up from CoO5 square pyramids, [B(OH)2P2O8]5– borophosphate trimers and PO4 tetrahedra. Extra‐framework Pb2+ and Cl– ions are located at the vacancy of layers to achieve the charge neutrality of the framework. Magnetic measurements indicate that antiferromagnetic interactions exist between Co2+ ions with a negative Weiss constant of –20.3 K. 相似文献
Lattice reduction algorithms have numerous applications in number theory, algebra, as well as in cryptanalysis. The most famous algorithm for lattice reduction is the LLL algorithm. In polynomial time it computes a reduced basis with provable output quality. One early improvement of the LLL algorithm was LLL with deep insertions (DeepLLL). The output of this version of LLL has higher quality in practice but the running time seems to explode. Weaker variants of DeepLLL, where the insertions are restricted to blocks, behave nicely in practice concerning the running time. However no proof of polynomial running time is known. In this paper PotLLL, a new variant of DeepLLL with provably polynomial running time, is presented. We compare the practical behavior of the new algorithm to classical LLL, BKZ as well as blockwise variants of DeepLLL regarding both the output quality and running time. 相似文献
The coordination polymer complex tetracesium bis(5-nitroisophthalate) heptahydrate [Cs4(C8H3NO6)2 (H2O)7]n has been synthesized and characterized using single-crystal X-ray diffraction. Crystals are monoclinic, space group P21/c, with Z = 4 in a cell with dimensions a = 12.3213(3), b = 6.7557(2), c = 36.2020(9) ?, β = 90.548(2)o. The complex is based on a repeating unit comprising four independent and different Cs coordination centres, two 6-coordinate,
and two 8-coordinate [Cs–O, range 2.959(5)–3.386(5) ?], and seven water molecules, two of which are monodentate and the other
five bridging, while all other oxygen atoms in the structure, including those of the nitro groups form inter-Cs bridges. Extensive
water O–H···O hydrogen-bonding interactions give a three-dimensional framework. This structure represents the first of an
alkali metal compound of 5-nitroisophthalic acid that has been reported. 相似文献
We solve the asymptotic Plateau problem in every Gromov hyperbolic Hadamard manifold (X,g) with bounded geometry. That is, we prove existence of complete (possibly singular) k-dimensional area minimizing surfaces in X with prescribed boundary data at infinity, for a large class of admissible limit sets and for all . The result also holds with respect to any riemannian metric on X which is lipschitz equivalent to g.
Received: 23 January 2001 / Accepted: 25 October 2001 Published online: 28 February 2002 相似文献
Thiamine hydrochloride ( 1a ; 3-[(4-amino-2-methylpyrimidin-5-yl)methyl]-5-(2-hydroxyethyl)-4-methylthia-zolium chloride hydrochloride; vitamin B1) has been synthesized in excellent yield by condensation of 3-mercapto-4-oxopentyl acetate (5a) with 3, 4-dihydro-7-methylpyrimido[4, 5-d]pyrimidine (4) in formic acid. The two intermediates 5a and 4 are prepared from 3-chloro-4-oxopentyl acetate (3) and 4-amino-2-methyl-5-(aminomethyl)-pyrimidine (Grewe diamine; 2a ), respectively. 相似文献
A trace analytical method based on high performance liquid chromatography coupled to quadrupole time-of-flight high resolution mass spectrometry was developed for simultaneous determination of perfluoroalkyl phosphonates (PFPAs, carbon chain lengths C6,8,10), perfluoroalkyl carboxylates (PFCAs, C5-12), and perfluoroalkyl sulfonates (PFSAs, C4,6,8,10) in drinking water (tap water). Analytes were enriched on a mixed mode co-polymeric sorbent (C8+quaternary amine) using solid phase extraction. Chromatographic separation was achieved on a Zorbax Extend C18 reversed phase column using a mobile phase gradient consisting of water, methanol, and acetonitrile containing 2mM ammonium acetate and 5 mM 1-methyl piperidine. The mass spectrometer was operated in electrospray negative ion mode. Use of 1-methyl piperidine in the mobile phase resulted in a significant increase in instrument sensitivity for PFPAs through improved chromatographic resolution, background suppression, and increased ionization efficiency. Method detection limits for extraction of 500 mL tap water were in the ranges of 0.095-0.17 ng/L, 0.027-0.17 ng/L, and 0.014-0.052 ng/L for PFPAs, PFCAs, and PFSAs, respectively. Whole method recoveries at a spiking level of 0.5 ng/L to 500 mL HPLC grade water were 40-56%, 56-97%, and 55-77% for PFPAs, PFCAs, and PFSAs, respectively. A matrix effect (signal enhancement) was observed in the detection of PFPAs in tap water extracts, leading to calculated recoveries of 249-297% at a 0.5 ng/L spiking level. This effect resulted in an additional improvement of method sensitivity for PFPAs. To compensate for the matrix effect, PFPAs in tap water were quantified using matrix-matched and extracted calibration standards. The method was successfully applied to the analysis of drinking water collected from six European countries. PFPAs were not detected except for perfluorooctyl phosphonate (PFOPA) at close to the detection limit of 0.095 ng/L in two water samples from Amsterdam, the Netherlands. Highest levels were found for perfluorobutane sulfonate (PFBS, 18.8 ng/L) and perfluorooctanoate (PFOA, 8.6 ng/L) in samples from Amsterdam as well as for perfluorooctane sulfonate (PFOS, 8.8 ng/L) in tap water from Stockholm, Sweden. 相似文献
A more thorough understanding of the properties of bulk material structures in solid–liquid separation processes is essential to understand better and optimize industrially established processes, such as cake filtration, whose process outcome is mainly dependent on the properties of the bulk material structure. Here, changes of bulk properties like porosity and permeability can originate from local variations in particle size, especially for non-spherical particles. In this study, we mix self-similar fractions of crushed, irregularly shaped Al2O3 particles (20 to 90 µm and 55 to 300 µm) to bimodal distributions. These mixtures vary in volume fraction of fines (0, 20, 30, 40, 50, 60 and 100 vol.%). The self-similarity of both systems serves the improved parameter correlation in the case of multimodal distributed particle systems. We use nondestructive 3D X-ray microscopy to capture the filter cake microstructure directly after mechanical dewatering, whereby we give particular attention to packing structure and particle–particle relationships (porosity, coordination number, particle size and corresponding hydraulic isolated liquid areas). Our results reveal widely varying distributions of local porosity and particle contact points. An average coordination number (here 5.84 to 6.04) is no longer a sufficient measure to describe the significant bulk porosity variation (in our case, 40 and 49%). Therefore, the explanation of the correlation is provided on a discrete particle level. While individual particles?<?90 µm had only two or three contacts, others?>?100 µm took up to 25. Due to this higher local coordination number, the liquid load of corresponding particles (liquid volume/particle volume) after mechanical dewatering increases from 0.48 to 1.47.