Colloidal Hybrid Nanostructures: A New Type of Functional Materials

One key goal of nanocrystal research is the development of experimental methods to selectively control the composition and shape of nanocrystals over a wide range of material combinations. The ability to selectively arrange nanosized domains of metallic, semiconducting, and magnetic materials into a single hybrid nanoparticle offers an intriguing route to engineer nanomaterials with multiple functionalities or the enhanced properties of one domain. In this Review, we focus on recent strategies used to create semiconductor–metal hybrid nanoparticles, present the emergent properties of these multicomponent materials, and discuss their potential applicability in different technologies.     

Some characteristics of multibeam holography

Holograms recorded with a number of reference beams are sensitive to alignment when reconstructed. Interference effects due to misalignment are evaluated, and as a result optimal recording parameters can be suggested.     

An eigenvalue problem for the numerical range of a bounded linear operator

LetX be a complex Lebesgue space with a unique duality mapJ fromX toX ^*, the conjugate space ofX. LetA be a bounded linear operator onX. In this paper we obtain a non-linear eigenvalue problem for (A)=sup{Re: W(A} whereW(A)={J(x)A(x)) : x=1}, under the assumption that (A) and the convex hull ofW(A) for some linear operatorsA onl _p , 2<p<.     

Atomic multipoles and perpendicular electrostatic forces in diatomic and planar molecules

Current methods for assigning atomic multipoles focus on reproduction of the molecular electrostatic potential. Another aspect of electrostatic interaction, which is usually overlooked, is the forces that an external electric field exerts on the nuclei of a molecule. In a self-consistent theory, both the electrostatic potential and force should be accounted for. However, in general it is not easy to meet this requirement for the force. For planar molecules, though, a formal solution is available in terms of atomic multipoles that are extracted from the molecular multipolar tensors. These Force-Related (FR) atomic multipoles are discussed in detail for some typical diatomics and planar polyatomics, and are shown to provide a solid uniform framework for treating both aspects of the electrostatics. In contrast, the commonly used potential-derived charges (i.e., the atomic charges obtained by fitting the electrostatic potential) can yield large deviations with respect to electrostatic forces on the nuclei, even when the electrostatic potential is very well reproduced.     

Krein's strings,the symmetric moment problem,and extending a real positive definite function

The symmetric moment problem is to find a possibly unique, positive symmetric measure that will produce a given sequence of moments {M_n}. Let us assume that the (Hankel) condition for existence of a solution is satisfied, and let σ_n be the unique measure, supported on n points, whose first 2n moments agree with M₀,…,M_2n−1. It is known that σ_2n ⇒ σ₀ (weak convergence) and σ_2n+1 ⇒ σ_∞, where σ₀ and σ_∞ are solutions to the full moment problem. Moreover, σ₀ = σ_∞ if and only if the problem has a unique solution. In this paper we present an analogue of this theorem for Krein's problem of extending to ℝ a real, even positive definite function originally defined on [−T,T] where T < ∞. Our proof relies on the machinery of Krein's strings. As we show, these strings help explain the connection between the moment and the extension problems. © 1999 John Wiley & Sons, Inc.     

The realization graph of a degree sequence with majorization gap 1 is Hamiltonian

It is known that the degree sequences of threshold graphs are characterized by the property that they are not majorized strictly by any degree sequence. Consequently every degree sequence d can be transformed into a threshold sequence by repeated operations consisting of subtracting I from a degree and adding 1 to a larger or equal degree. The minimum number of these operations required to transform d into a threshold sequence is called the majorization gap of d. A realization of a degree sequence d of length n is a graph on the vertices 1, …, n, where the degree of vertex i is d_i. The realization graph %plane1D;4A2;(d) of a degree sequence d has as vertices the realizations of d, and two realizations are neighbors in %plane1D;4A2;(d) if one can be obtained from the other by deleting two existing edges [a, b], [c, d] and adding two new edges [a, d]; [b, c] for some distinct vertices a, b, c, d. It is known that %plane1D;4A2;(d) is connected. We show that if d has a majorization gap of 1, then %plane1D;4A2;(d) is Hamiltonian.     

Study of ion–solvent interactions and activation energy of LiBr in DMSO,H<Subscript>2</Subscript>O and DMSO–H<Subscript>2</Subscript>O mixtures at various temperatures

The Jones–Dole B coefficients of the electrolyte Lithium bromide (LiBr), reference salts tetra butyl ammonium tetra phenyl borate (BU₄NBPh₄), tetra butyl ammonium bromide (BU₄NBr), and potassium chloride (KCl) in dimethylsulfoxide (DMSO), water, and DMSO–water mixtures were obtained at different temperatures range from 25 to 45 °C For this, the relative viscosities were measured for Lithium bromide (LiBr) and reference salts in DMSO, water, and DMSO–water mixtures at above-mentioned temperatures. The B coefficients of these electrolytes were behaved as structure makers in DMSO, while in H₂O and DMSO–H₂O mixtures, the B-coefficient values were less positive showing the weak structure-making effect. Ionic viscosity B coefficients allow us to assess the behavior of ions in the solvent mixtures. In this study it was observed that all the values of ionic B coefficient of (Li⁺) were positive and small showing the weak structure-making effects. It was also observed that Br⁻ ions maintain negative B coefficient values in all DMSO–H₂O mixtures, except in 60% DMSO mole fraction. From this it can be concluded that Br⁻ ion behaved as a structure breaker in water and in all DMSO–H₂O mixtures except in 60% DMSO mole fraction mixtures. The low B _± values of alkali metal ions and Br⁻ ions in water are due to the breakdown of the tetrahedral structural of water and the formation of strongly structured solvated ion. It is also observed that the values of the energy of activation of the flow for LiBr are greater in DMSO–water mixtures and in pure water than in DMSO. This may be due the presence of a network of hydrogen bonds which cause the hindrance in the flow of the solution of LiBr in DMSO–water mixtures and in pure water than in DMSO.