全文获取类型
收费全文 | 233篇 |
免费 | 10篇 |
国内免费 | 1篇 |
专业分类
化学 | 142篇 |
力学 | 2篇 |
数学 | 10篇 |
物理学 | 90篇 |
出版年
2023年 | 7篇 |
2022年 | 19篇 |
2021年 | 17篇 |
2020年 | 6篇 |
2019年 | 9篇 |
2018年 | 12篇 |
2017年 | 7篇 |
2016年 | 10篇 |
2015年 | 5篇 |
2014年 | 7篇 |
2013年 | 13篇 |
2012年 | 7篇 |
2011年 | 13篇 |
2010年 | 11篇 |
2009年 | 7篇 |
2008年 | 10篇 |
2007年 | 7篇 |
2006年 | 8篇 |
2005年 | 6篇 |
2004年 | 9篇 |
2003年 | 16篇 |
2002年 | 4篇 |
2001年 | 9篇 |
2000年 | 6篇 |
1999年 | 3篇 |
1998年 | 2篇 |
1997年 | 1篇 |
1996年 | 3篇 |
1995年 | 2篇 |
1994年 | 1篇 |
1992年 | 3篇 |
1990年 | 1篇 |
1984年 | 1篇 |
1982年 | 1篇 |
1975年 | 1篇 |
排序方式: 共有244条查询结果,搜索用时 31 毫秒
111.
Hočevar Mateja Berginc Marko Topič Marko Krašovec Urša Opara 《Journal of Sol-Gel Science and Technology》2010,53(3):647-654
A titanium oxide layer used in a dye-sensitized solar cell (DSSC) has to meet two opponent properties to enable high conversion
efficiency: a large surface area (for high dye loading) and good connection between TiO2 grains (for efficient extraction of electrons toward the front contact). In order to meet a trade-off between these criteria
a preparation method for TiO2 paste formulation based on Pechini sol–gel method and commercial nanocrystalline TiO2 powder has been developed. A series of TiO2 pastes with different molar ratios between titanium isopropoxide, citric acid and ethylene glycol (1:X:4X) in the paste have been examined. The structure and morphology as well as cross-cut tests of deposited and sintered TiO2 layers have been analyzed. Results reveal that the paste with X = 8 exhibits the best properties, resulting in an overall conversion efficiency of DSSC under standard test conditions (100 mW/cm2, 25 °C, AM 1.5G) up to 6.6% for ionic liquid based electrolyte. 相似文献
112.
N. Mărginean S.M. Lenzi A. Gadea E. Farnea S.J. Freeman D.R. Napoli D. Bazzacco S. Beghini B.R. Behera P.G. Bizzeti A. Bizzeti-Sona D. Bucurescu R. Chapman L. Corradi A.N. Deacon G. de Angelis F. Della Vedova E. Fioretto M. Ionescu-Bujor A. Iordachescu Th. Kröll A. Latina X. Liang S. Lunardi G. Montagnoli R. Mărginean M. Nespolo G. Pollarolo C. Rusu F. Scarlassara J.F. Smith K. Spohr A.M. Stefanini S. Szilner M. Trotta C.A. Ur B.J. Varley W. Zhimin 《Physics letters. [Part B]》2006
113.
张玉虎 柳敏良G.deAngelis Zs.Podolyak 郭文涛 A.Gadea C.Ur N.Marginean C.Rusu R.Schwengner D.R.Napoli R.Menegazzo S.Lunardi D.Bazzacco T.Martinez M.Axiotis A.Gargano S.M.Lenzi F.Brandolini W.vonOertzen 《中国物理 C》2004,28(9):941-946
通过重离子融合蒸发反应^16O(^82Se 4n)^94Mo布局了^94Mo核的高自旋态.利用多探头探测器阵列GASP进行了在束γ测量,从而重新研究了^94Mo核的高自旋态能级结构.基于新发现的一些重要的连接跃迁,对^94Mo核的高自旋态能级纲图做了重要修改.将新的能级结构与壳模型计算进行了比较和讨论.结果表明要正确的描述^94Mo核的高自旋态(自旋值大于14)能级结构,应考虑价中子在d5/2,g7/2和h11/2轨道上的激发. 相似文献
114.
Magnetic resonance imaging (MRI) has become a prominent imaging technique in medicine. Gadoliniumbased contrast agents are extensively used to enhance the contrast between normal and diseased tissues through MRI scans. The article illustrates the paramount significance of such contrast agents in MRI applications. Clinically approved contrast agents as well as those in trial period are discussed. Important parameters, i.e. hydration number, rotational correlation time, and mean residence lifetime, influencing the relaxivity (sensitivity) of such agents are described in detail. Various approaches towards relaxivity enhancement are discussed with appropriate examples from the recent literature. A decrease in the Gdwater proton distance results in significant relaxivity enhancement. A comprehensive classification and explanation of Gd3+-based contrast agents are presented. Each class is explained with suitable examples. The stability of contrast agents is dependent on their chemical structure. Future contrast agents need to be tissue specific of high relaxivity, low toxicity, and lower administered dose for in vivo use. 相似文献
115.
Lidia Armelao Dr. Davide Barreca Dr. Gregorio Bottaro Dr. Alberto Gasparotto Dr. Chiara Maccato Dr. Eugenio Tondello Prof. Oleg I. Lebedev Dr. Stuart Turner Gustaaf Van Tendeloo Prof. Cinzia Sada Dr. Urška Lavrenčič Štangar Prof. 《Chemphyschem》2009,10(18):3249-3259
The present work is devoted to the preparation of Ag/TiO2 nanosystems by an original synthetic strategy, based on the radio‐frequency (RF) sputtering of silver particles on titania‐based xerogels prepared by the sol–gel (SG) route. This approach takes advantage of the synergy between the microporous xerogel structure and the infiltration power characterizing RF‐sputtering, whose combination enables the obtainment of a tailored dispersion of Ag‐containing particles into the titania matrix. In addition, the system′s chemico‐physical features can be tuned further through proper ex situ thermal treatments in air at 400 and 600 °C. The synthesized composites are extensively characterized by the joint use of complementary techniques, that is, X‐ray photoelectron and X‐ray excited Auger electron spectroscopies (XPS, XE‐AES), secondary ion mass spectrometry (SIMS), glancing incidence X‐ray diffraction (GIXRD), field emission scanning electron microscopy (FE–SEM), transmission electron microscopy (TEM), electron diffraction (ED), high‐angle annular dark field scanning TEM (HAADF–STEM), energy‐filtered TEM (EF–TEM) and optical absorption spectroscopy. Finally, the photocatalytic performances of selected samples in the decomposition of the azo‐dye Plasmocorinth B are preliminarily investigated. The obtained results highlight the possibility of tailoring the system characteristics over a broad range, directly influencing their eventual functional properties. 相似文献
116.
M. Žitnik M. Budnar K. Ravnikar M. Uršič N. Grlj M. Jakomin Z. Rupnik P. Pelicon 《Journal of Radioanalytical and Nuclear Chemistry》2008,275(1):17-28
In evaluation of the influence of environmental pollution on the ecosystem, data about the elemental concentrations of the
atmospheric aerosols, combined with information about particle size and meteorological data, are of significant importance.
They are also necessary prerequisites for source/receptor studies and long-range transport modeling. As such, these data are
irreplaceable for the estimation of potential elemental input from air to the sea, an understanding of which is one of the
tasks of the Mediterranean Pollution Programme (MED POL). Three sampling locations (Sečovlje, Koper, and Iskrba) in Slovenia
were chosen for the present study, two at the coast and the third one in a scarcely inhabited, almost unpolluted area, as
a reference point, and the element concentrations in the collected particulate matter (PM) were determined. From the Iskrba
data the wet scavenging coefficient of airborne sulphur due to precipitation was estimated as k = (1.0±0.3)·10−4s−1 (at 1.5 mm·h−1). 相似文献
117.
A. S. Gordetsov S. V. Zimina S. V. Saprykina L. B. Loginova A. V. Piskunov V. F. Ur’yash E. M. Moseeva 《Russian Journal of General Chemistry》2011,81(4):658-662
1,3,5-Tris[bis(η5-cyclopentadienyl)chlorovanadium]melamin is prepared in high yield by the reaction of N,N′-bis(trimethylsilyl)dicyandiamide with bis(η5-cyclopentadienylvanadium) dichloride in tetrahydrofuran. As side products, trimethylchlorosilane and cyclopentadiene formed.
Reaction of N,N′-bis(trimethylsilyl) dicyandiamide with benzoyl chloride results in the formation of tris(benzoyl)melamin. 相似文献
118.
Li‐Ning Wang Dong‐Xiao Guo Shu‐Qi Wang Chang‐Sheng Wu Mujeeb Ur Rehman Hong‐Xiang Lou 《Helvetica chimica acta》2011,94(6):1146-1152
Four new phenolic glycosides, named rebouosides A–D ( 1 – 4 , resp.), along with three known ones 2‐(3,4‐dihydroxyphenyl)ethyl 2‐O‐α‐L ‐rhamnopyranosyl‐β‐D ‐allopyranoside ( 5 ), 2‐(3,4‐dihydroxyphenyl)ethyl β‐D ‐allopyranoside ( 6 ), 2‐(3,4‐dihydroxyphenyl)ethyl β‐D ‐glucopyranoside ( 7 ), and a nucleoside, inosine ( 8 ), were isolated from Chinese liverwort Reboulia hemisphaerica. Their structures were elucidated by acidic hydrolysis and extensive spectroscopic methods, including 2D‐NMR techniques. 相似文献
119.
Rother W Dewald A Iwasaki H Lenzi SM Starosta K Bazin D Baugher T Brown BA Crawford HL Fransen C Gade A Ginter TN Glasmacher T Grinyer GF Hackstein M Ilie G Jolie J McDaniel S Miller D Petkov P Pissulla T Ratkiewicz A Ur CA Voss P Walsh KA Weisshaar D Zell KO 《Physical review letters》2011,106(2):022502
The transition rates for the 2(1)+ states in (62,64,66)Fe were studied using the recoil distance Doppler-shift technique applied to projectile Coulomb excitation reactions. The deduced E2 strengths illustrate the enhanced collectivity of the neutron-rich Fe isotopes up to N = 40. The results are interpreted using the generalized concept of valence proton symmetry which describes the evolution of nuclear structure around N = 40 as governed by the number of valence protons with respect to Z ≈ 30. The trend of collectivity suggested by the experimental data is described by state-of-the-art shell-model calculations with a new effective interaction developed for the fpgd valence space. 相似文献
120.
David T. D. Childs Richard A. Hogg Dmitry G. Revin Ihtseham Ur Rehman John W. Cockburn 《应用光谱学评论》2013,48(10):822-839
AbstractInterest in mid-infrared spectroscopy instrumentation beyond classical FTIR using a thermal light source has increased dramatically in recent years. Synchrotron, supercontinuum, and external-cavity quantum cascade laser light sources are emerging as viable alternatives to the traditional thermal black-body emitter (Globar), especially for remote interrogation of samples (“stand-off” detection) and for hyperspectral imaging at diffraction-limited spatial resolution (“microspectroscopy”). It is thus timely to rigorously consider the relative merits of these different light sources for such applications. We study the theoretical maximum achievable signal-to-noise ratio (SNR) of FTIR using synchrotron or supercontinuum light vs. that of a tunable quantum cascade laser, by reinterpreting an important result that is well known in near-infrared optical coherence tomography imaging. We rigorously show that mid-infrared spectra can be acquired up to 1000 times faster—using the same detected light intensity, the same detector noise level, and without loss of SNR—using the tunable quantum cascade laser as compared with the FTIR approach using synchrotron or supercontinuum light. We experimentally demonstrate the effect using a novel, rapidly tunable quantum cascade laser that acquires spectra at rates of up to 400 per second. We also estimate the maximum potential spectral acquisition rate of our prototype system to be 100,000 per second. 相似文献