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351.
Surface Modification and Characterization of Dichloromethane Plasma Treated Polypropylene Film 总被引:3,自引:0,他引:3
Surface of polypropylene (PP) film was modified in plasma of dichloromethane (CH2Cl2). The nature of surface modifications and formation of cross-linked layer due to plasma polymerization was studied by surface energy measurements and solubility test. Surface modification achieved by CH2Cl2 plasma was compared with the reported work on chloroform (CHCl3) and carbontetrachloride (CCl4) plasma modifications. Modified surface characterized by ATR-FTIR technique indicated formation of saturated and unsaturated cross-linked product. On the basis of relative intensity change of the specific bands, the site of attachment of chlorine on PP surface was investigated. Adhesive strength of modified film was measured by T-peel test method. Stability of modified surface was studied by measuring surface energy and peel strength after two months. 相似文献
352.
Upadhyay DM Rai AK Rai DK Singh AN Kumar A 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2007,66(4-5):909-918
The molecular geometry of L and D-forms of alanine and serine in gas phase have been studied by using ab-initio quantum chemical calculations at the restricted Hartree-Fock (RHF) level by employing 6-31G and 6-311++G** basis sets. Subsequently, for considering the electron correlations, Density functional Calculations at the Becke3LYP (B3LYP) and Moller-Plesset second order (MP2) level of calculations have been carried out with the same basis sets for these optimized geometries. Effect of solvation in water on the optimized geometries was studied using the polarized continuum model of the self-consistent reaction field (SCRF) theory. The dipole moment, energy, polarizabilities and vibrational frequencies have been calculated in all cases. Frequency analysis was carried out to ensure that optimized geometry corresponds to a total energy minimum. 相似文献
353.
Pranav Upadhyay G. Alex Balan Dr. Devesh Kumar Prof. Dr. Simonetta Fornarini Prof. Dr. Maria Elisa Crestoni Dr. Sam P. de Visser 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(51):18608-18619
Cytochrome P450 enzymes are heme‐containing mono‐oxygenases that mainly react through oxygen‐atom transfer. Specific features of substrate and oxidant that determine the reaction rate constant for oxygen atom transfer are still poorly understood and therefore, we did a systematic gas‐phase study on reactions by iron(IV)‐oxo porphyrin cation radical structures with arenes. We present herein the first results obtained by using Fourier transform‐ion cyclotron resonance mass spectrometry and provide rate constants and product distributions for the assayed reactions. Product distributions and kinetic isotope effect studies implicate a rate‐determining aromatic hydroxylation reaction that correlates with the ionization energy of the substrate and no evidence of aliphatic hydroxylation products is observed. To further understand the details of the reaction mechanism, a computational study on a model complex was performed. These studies confirm the experimental hypothesis of dominant aromatic over aliphatic hydroxylation and show that the lack of an axial ligand affects the aliphatic pathways. Moreover, a two‐parabola valence bond model is used to rationalize the rate constant and identify key properties of the oxidant and substrate that drive the reaction. In particular, the work shows that aromatic hydroxylation rates correlate with the ionization energy of the substrate as well as with the electron affinity of the oxidant. 相似文献
354.
Ajit Kumar Indra Sen Ram Sunil Kumar Jagjiwan Ram A. N. Upadhyay Kedar Singh 《Journal of Thermal Analysis and Calorimetry》2018,134(2):923-931
Glassy Se100?x(Ge2Sb2Te5)x (x?=?5, 10, 15 and 20) bulk alloys were prepared by melt-quenched technique and studied by using differential scanning calorimetry at different heating rates under non-isothermal condition. The detailed thermal analysis shows that the glass transition temperature (Tg) depends on heating rates and x content. In particular, it is found that the glass-forming ability, thermal stability (Tc???Tg) and crystallization activation energy (Ec) increase with increased x content in amorphous Se, whereas glass transition activation energy (Eg) and fragility index (F) decrease with increased x contents. Variation in these parameters can be explained on the basis of network-forming ability of Se and bonding arrangement among the constituent atoms of alloys. 相似文献