全文获取类型
收费全文 | 663篇 |
免费 | 22篇 |
国内免费 | 3篇 |
专业分类
化学 | 533篇 |
晶体学 | 2篇 |
力学 | 3篇 |
数学 | 63篇 |
物理学 | 87篇 |
出版年
2023年 | 4篇 |
2022年 | 11篇 |
2021年 | 7篇 |
2020年 | 12篇 |
2019年 | 8篇 |
2018年 | 9篇 |
2017年 | 7篇 |
2016年 | 15篇 |
2015年 | 8篇 |
2014年 | 20篇 |
2013年 | 25篇 |
2012年 | 36篇 |
2011年 | 45篇 |
2010年 | 30篇 |
2009年 | 24篇 |
2008年 | 43篇 |
2007年 | 40篇 |
2006年 | 44篇 |
2005年 | 33篇 |
2004年 | 26篇 |
2003年 | 28篇 |
2002年 | 28篇 |
2001年 | 13篇 |
2000年 | 15篇 |
1999年 | 11篇 |
1998年 | 12篇 |
1997年 | 10篇 |
1996年 | 14篇 |
1995年 | 9篇 |
1994年 | 5篇 |
1993年 | 4篇 |
1992年 | 7篇 |
1991年 | 4篇 |
1990年 | 4篇 |
1989年 | 4篇 |
1988年 | 6篇 |
1987年 | 11篇 |
1986年 | 10篇 |
1985年 | 7篇 |
1984年 | 6篇 |
1983年 | 7篇 |
1982年 | 2篇 |
1981年 | 9篇 |
1980年 | 3篇 |
1978年 | 2篇 |
1977年 | 3篇 |
1975年 | 2篇 |
1974年 | 1篇 |
1972年 | 1篇 |
1963年 | 1篇 |
排序方式: 共有688条查询结果,搜索用时 31 毫秒
121.
Helge Hannebauer Thorsten Dullweber Ulrike Baumann Tom Falcon Rolf Brendel 《固体物理学:研究快报》2014,8(8):675-679
We evaluate industrial‐type PERC solar cells applying a 5 busbar front grid and fineline‐printed Ag fingers. We obtain finger widths down to 46 µm when using a stencil with 40 µm opening for the finger print, whereas the busbar is printed in a separate printing step with a different Ag paste (dual print). This compares to finger widths of 62 µm to 66 µm when applying print‐on‐print. The 5 busbar front grid with the best dual print process reduces the shadowing loss of the front grid to 4.0% compared to 5.8% for a conventional 3 busbar front grid printed with print‐on‐print. The 1.8% reduction in shadowing loss results in equal parts from the reduced finger width with dual print as well as from a reduced total busbar width of the 5 busbar design. The resulting PERC solar cells with 5 busbars demonstrate independently confirmed conversion efficiencies of 21.2% compared to 20.6% efficiency of the 3 busbar PERC solar cell. The increased conversion efficiency is primarily due to an increased short‐circuit current resulting from the reduced shadowing loss. To our knowledge, 21.2% conversion efficiency is the highest value reported so far for industry typical silicon solar cells with printed metal front and rear contacts. (© 2014 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim) 相似文献
122.
123.
Mateja Pogorevc Ulrike T. Strauss Marianne Hayn Kurt Faber 《Monatshefte für Chemie / Chemical Monthly》2000,220(2):639-644
Biocatalytic resolution of the tertiary terpene alcohol (±)-linalool was accomplished via hydrolysis of its corresponding acetate ester using two highly enantiospecific enzymes (E > 100). The latter were identified in a crude cell-free extract of Rhodococcus ruber DSM 43338 and could be separated by (partial) protein purification. Since they showed opposite enantiopreference, they were
termed (R)- and (S)-linalyl acetate hydrolase (LAH). The activity and selectivity of the enzyme preparations was markedly dependent on the fermentation
conditions. 相似文献
124.
125.
126.
Ulrike Paap Vera Seidl Karsten Meyer Florian Maier Hans-Peter Steinrück 《Molecules (Basel, Switzerland)》2022,27(23)
We investigated the surface tension and surface composition of various mixtures of the two ionic liquids (ILs) 1-methyl-3-octyl-imidazolium hexafluorophosphate [C8C1Im][PF6] and 1,3-bis(polyethylene glycol)imidazolium iodide [(mPEG2)2Im]I in the temperature range from 230 to 370 K under ultraclean vacuum conditions. The surface tension was measured using a newly developed apparatus, and the surface composition was determined by angle-resolved X-ray photoelectron spectroscopy (ARXPS). In the pure ILs, the alkyl chains of [C8C1Im][PF6] and the PEG chains of [(mPEG2)2Im]I are enriched at the IL/vacuum interface. In the mixtures, a strong selective surface enrichment of the alkyl chains occurs, which is most pronounced at low [C8C1Im][PF6] contents. For the surface tension, strong deviations from an ideal mixing behaviour take place. By applying a simple approach based on the surface composition of the mixtures as deduced from ARXPS, we are able to predict and reproduce the experimentally measured temperature-dependent surface tension values with astonishingly high accuracy. 相似文献
127.
Laura M. Luh Ulrike Scheib Katrin Juenemann Lars Wortmann Michael Brands Philipp M. Cromm 《Angewandte Chemie (International ed. in English)》2020,59(36):15448-15466
Targeted protein degradation (TPD), the ability to control a proteins fate by triggering its degradation in a highly selective and effective manner, has created tremendous excitement in chemical biology and drug discovery within the past decades. The TPD field is spearheaded by small molecule induced protein degradation with molecular glues and proteolysis targeting chimeras (PROTACs) paving the way to expand the druggable space and to create a new paradigm in drug discovery. However, besides the therapeutic angle of TPD a plethora of novel techniques to modulate and control protein levels have been developed. This enables chemical biologists to better understand protein function and to discover and verify new therapeutic targets. This Review gives a comprehensive overview of chemical biology techniques inducing TPD. It explains the strengths and weaknesses of these methods in the context of drug discovery and discusses their future potential from a medicinal chemist's perspective. 相似文献
128.
129.
Holger Lange María Machón Mikhail Artemyev Ulrike Woggon Christian Thomsen 《固体物理学:研究快报》2007,1(6):274-276
We investigated the influence of an epitaxially grown ZnS shell on the phonon spectra of CdSe nanorods of different sizes. The CdSe related Raman peaks shift with addition of a ZnS shell. The longitudinal optical phonon shifts slightly due to strain and the low‐energy shoulder shifts stronger, which can be explained within a model for surface optical phonons. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
130.