Laser magnetic resonance spectra of ClO2 tuned by the avoidance of zeeman level crossing

LMR of the ν₁ band of the stable ClO₂ radical has exhibited clearly-resolved spectra under strong magnetic fields. Some of these were well described by a new type Zeeman-tuning due to the avoidance of the Zeeman level crossing.     

On the treatment of the annihilation interaction in antiproton-nucleus collisions

We discuss how to treat the annihilation interaction in antiproton-nucleus collisions within the framework of the multiple scattering model under the constraint that real annihilation of the projectile can take place only once.     

Scale Free Properties of Random <Emphasis Type="Italic">k</Emphasis>-Trees

Scale free graphs have attracted attention as their non-uniform structure that can be used as a model for many social networks including the WWW and the Internet. In this paper, we propose a simple random model for generating scale free k-trees. For any fixed integer k, a k-tree consists of a generalized tree parameterized by k, and is one of the basic notions in the area of graph minors. Our model is quite simple and natural; it first picks a maximal clique of size k + 1 uniformly at random, it then picks k vertices in the clique uniformly at random, and adds a new vertex incident to the k vertices. That is, the model only makes uniform random choices twice per vertex. Then (asymptotically) the distribution of vertex degree in the resultant k-tree follows a power law with exponent 2 + 1/k, the k-tree has a large clustering coefficient, and the diameter is small. Moreover, our experimental results indicate that the resultant k-trees have extremely small diameter, proportional to o(log n), where n is the number of vertices in the k-tree, and the o(1) term is a function of k.     

The Synthesis of Fluorine Containing Phenyl Benzoates and Their Properties as Liquid Crystals

A new series of fluorine containing phenyl benzoates has been synthesized and the transition temperatures of these compounds have been determined. A series of 4-trifluoromethylphe 4nyl 4-n-alkybenzoates showed no liquid crystalline behaviour, but the 4-trifluoromethylphenyl 4-n-alkoxybenzoates series, with six carbons or more in alkoxy chain, was mesomorphic. The 4-cyanophenyl 4-perfluoroalkylbenzoates showed smectic liquid crystalline properties.     

Synthesis,Structure, Optical,and Electrochemical Properties of Triple‐ and Quadruple‐Decker Co‐facial Tetrathiafulvalene Arrays

Understanding the details of the electronic structure in face‐to‐face arranged tetrathiafulvalenes (TTFs) is very important for the design of supramolecular functional materials and superior conductive organic materials. This article is a comprehensive study of the interactions among columnar stacked TTFs using trimeric (trimer) and tetrameric (tetramer) TTFs linked by alkylenedithio groups (‐S(CH₂)_nS‐, n=1–4) as models of triple‐ and quadruple‐decker TTF arrays. Single‐crystal X‐ray analyses of neutral trimeric TTFs revealed that the three TTF moieties are oriented in a zigzag arrangement. Cyclic voltammetry measurements (CV) reveal that the trimer and tetramer exhibited diverse reversible redox processes with multi‐electron transfers, depending on the length of the ‐S(CH₂)_nS‐ units and substituents. The electronic spectra of the radical cations, prepared by electrochemical oxidation, showed charge resonance (CR) bands in the NIR/IR region (1630–1850 nm), attributed to a mixed valence (MV) state of the triple‐ and quadruple‐decker TTF arrays. In the trimeric systems, the dicationic state (+2; 0.66 cation per TTF unit) was found to be a stable state, whereas the monocationic state (+1) was not observed in the electronic spectra. In the tetrameric system, substituent‐dependent redox processes were observed. Moreover, π‐trimers and π‐tetramers, which show a significant Davydov blueshift in the spectra, are formed in the tricationic (trimer) and tetracationic (tetramer) state. In addition, these attractive interactions are strongly dependent on the length of the linkage unit.