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In order to gain insight into the preactivation of merocyanine 540 (MC540) 1 for the photodynamic therapy (Gulliya et al., 1990a, Photochem. Photobiol. 52, 831-838) its photo-oxidation was investigated. After irradiation of MC540 1 on a preparative scale three main photodegradation products were isolated with 16-20% yields. They turned out to be derivatives of benzoxazole, thiouracil and thiohydantoin with the structures 4, 5 and 6, respectively. It may be possible that they contribute to the cytostatic and antiviral activity of preactivated MC540 1. 相似文献
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G. Ren van der Hoff Steven M. Gort Robert A. Baumann Piet Van Zoonen Udo A. Th. Brinkman 《Journal of separation science》1991,14(7):465-470
The ASPEC (Automatic Sample Preparation with Extraction Columns) system has been coupled on-line to capillary GC-ECD by means of a loop-type interface equipped with a solvent vapour exit. Both ASPEC and GC conditions have been optimized leading to an effective clean-up of the extracts analyzed. By means of solid-phase extraction cartridges filled with silica, it has been possible to analyze concentrated surface water extracts for a group of 18 electron-capturing compounds present in the water at ppt levels. ASPEC-GC has also been applied to the determination of synthetic pyrethroids at ppt levels in surface water. The complete analytical procedure is greatly facilitated by automation and miniaturization. Miniaturization results in a considerable decrease in the sample volume required. The potential of the method for the analysis of other pesticides is estimated. 相似文献
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We introduce the fuzzy supersphere as sequence of finite-dimensional, noncommutative
2-graded algebras tending in a suitable limit to a dense subalgebra of the
2-graded algebra of
∞-functions on the (2|2)-dimensional supersphere. Noncommutative analogues of the body map (to the (fuzzy) sphere) and the super-deRham complex are introduced. In particular we reproduce the equality of the super-deRham cohomology of the supersphere and the ordinary deRham cohomology of its body on the “fuzzy level”. 相似文献
129.
Rob J. Vreeken Maria E. Jager Rudy T. Ghijsen Udo A. Th. Brinkman 《Journal of separation science》1992,15(12):785-790
Fatty acids can be conveniently derivatized in less than one minute with (chloro)alkyl chloroformates such as methyl chloroformate, 2-chloroethyl chloroformate and 2,2,2-trichloroethyl chloroformate. 2,2,2-Trichloroethyl chloroformate is the most reactive reagent, and yields a reaction product which can be sensitively detected by GC ECD (detection limit 50 ng/ml, i.e. 25 pg/injection, for C8, C10, and C12 acids). In non-aqueous media 3-picoline, N-methylpiperidine, and dimethylaminopyridine show catalytic activity comparable with that of pyridine and can, therefore, replace it. N-methylpiperidine is the best basic catalyst in aqueous media (i.e. media containing up to 40 % water). 相似文献
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