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41.
42.
Structures of Charge-Perturbed or Sterically Overcrowded Molecules. 16. Tetracyanoethylene Sodium Dimethoxyethane The Single crystal structure of [(NC)2C? C(CN)2?·Na⊕(H3CO? CH2CH2? OCH3)]∞ reveals two formula units within the triclinic (P1 ) unit cell. The tetracyanoethylene radical anions are arranged along parallel double layers, which are shifted relative to each other, and in between which are interspersed the sodium counter cations and their dimethoxyethane ligands. The distances within the double layers amount to 300 pm and the ones between them to 385 pm. The six-fold coordinated Na⊕ centers are surrounded by four radical anions with contact distances Na…?N between 250 and 254 pm as well as by a twofold solvent ligand with Na…?O of 238 and 241 pm. Due to the electron transfer to the acceptor molecule, its (NC)2C-halves twist by 8° and the bond lengths of the N?C? C subunits, bent by each 3°, are shortened up to 2 pm. The structural parameters are compared to those of the analogous potassium salt [TCNE?K⊕DME], of the dianion , of the sodium salts [(NC)3C?Na⊕]∞ as well as [(NC)2C? C(CHCH)2? C(CN)2?Na⊕]∞ and, in addition, are discussed based on geometry-optimized MNDO calculations. 相似文献
43.
T. C. Awes C. Barlag F. Berger M. A. Bloomer C. Blume D. Bock R. Bock E. -M. Bohne D. Bucher A. Claussen G. Clewing L. Dragon A. Eklund S. Garpman R. Glasow H. Gustafsson H. H. Gutbrod G. Hölker J. Idh P. Jacobs K. H. Kampert B. W. Kolb H. Löhner I. Lund F. E. Obenshain A. Oskarsson I. Otterlund T. Peitzmann F. Plasil A. M. Poskanzer M. Purschke B. Roters S. Saini R. Santo H. R. Schmidt S. P. Sørensen K. Steffens P. Steinhaeuser E. Stenlund D. Stüken G. R. Young 《Zeitschrift fur Physik C Particles and Fields》1995,65(2):207-213
Correlations between protons are studied in the target fragmentation region of reactions of protons and16O with C, Cu, Ag, Au and of32S with Al and Au at 200A GeV. The emitted protons were measured with the Plastic Ball detector in the WA80 experiment at the CERN SPS. The comparison of the correlation function with calculations, assuming a spherical, gaussian shaped source with a lifetime τ=0 fm/c, allows the extraction of radius parameters. The values are very close to those expected from the geometry of the target nuclei and increase with the target mass as αA Target 1/3 . Even in proton induced reactions the whole target nucleus is involved. The dependence of the radii on centrality, polar angleθ lab, and energy, and their relation to measured proton yields are presented. 相似文献
44.
Jeffrey Axten Jennifer Troy Peter Jiang Mendel Trachtman Charles W. Bock 《Structural chemistry》1994,5(2):99-108
Ab initio molecular orbital calculations are used to study the modified Schlenk equilibrium: 2RMgCl (RMgCl)2 MgR2 + MgCl2 Mg(Cl2)MgR2 with R=H and CH3. In the absence of any solvents, calculations indicate that the formation of the various possible bridged dimers (RMgCl)2 is substantially exothermic. However, using dimethylether as a model solvent, we show that the formation of the dimer (Me2O)(CH3)Mg(Cl2)Mg(CH3)(OMe2) is exothermic only when entropic effects are included. 相似文献
45.
There is a new method of constructing generalized quadrangles (GQs) given by S. Löwe, which is based on covering of nets; all GQs with a regular point can be represented in this way. Here we give a method of constructing GQs with a regular point using the so-called content functions on nets. In the last part of the paper we lay the foundations for a research project aiming to use the more general notion of content to classify GQs and maybe to construct new ones.Both authors acknowledge the financial support by CRUI and DAAD in the frame of Programma Vigoni, which made this work possible. 相似文献
46.
Letf be a meromorphic function of infinite order,T(r, f) its Nevanlinna (or Ahlfors-Shimizu) characteristic, andM(r, f) its maximum modulus. It is proved that $$\mathop {\lim \inf }\limits_{r \to \infty } \frac{{\log M(r,f)}}{{rT'(r,f)}} \leqslant \pi and\mathop {\lim \inf }\limits_{r \to \infty } \frac{{\log M(r,f)}}{{T(r,f)\psi (log T(r,f))}} = 0$$ . if ? (x)/x is non-decreasing, ?′(x)<-√?(x) and ∝∞ dx/?(x) < ∞. 相似文献
47.
Weaver M Arisaka K Roberts D Slater W Briere RA Cheu E Harris DA Roodman A Schwingenheuer B Wah YW Winstein B Winston R Barker AR Swallow EC Bock GJ Coleman R Crisler M Enagonia J Ford R Hsiung YB Jensen DA McFarland KS Ramberg E Tschirhart R Collins EM Gollin GD Nakaya T Yamanaka T Gu P Haas P Hogan WP Kim SK Matthews JN Myung SS Schnetzer S Somalwar SV Thomson GB Zou Y 《Physical review letters》1994,72(24):3758-3761
48.
J. B?chler J. Bartke H. Bia?kowska R. Bock D. Brinkmann R. Brockmann P. Buncic S. I. Chase I. Derado V. Eckardt et al. 《Zeitschrift fur Physik C Particles and Fields》1994,61(4):551-561
The intermittency phenomenon is investigated in proton-gold, oxygen-gold, sulphur-gold and sulphur-sulphur collisions at 200 GeV per nucleon. The data were taken with the NA 35 streamer chamber detector at the CERN SPS. The data samples are carefully corrected for double counting of tracks and for contamination from photon conversions, particle decays and secondary interactions. The analysis is carried out in terms of factorial moments, using a new definition, and of correlation integrals. Both methods show the presence of nonstatistical fluctuations (intermittency). The main conclusions are: The observation of the effect for pairs of hadrons with negative charges and its near absence for pairs of opposite charges is consistent with the assumption that Bose-Einstein correlations yield the dominant contribution. The intermittency effect is not proportional to (dn/dy)–1 which would be expected in superposition models. The measured relation between the second and third factorial moment for negative hadrons indicates that genuine 3-particle correlations are small. The predictions of a Monte Carlo simulation which is based on the Lund Fritiof model with the inclusion of Bose-Einstein correlations agree with the experimental results.Deceased 相似文献
49.
Gu P Haas P Hogan WP Kim SK Matthews JN Myung SS Schnetzer S Thomson GB Zou Y Arisaka K Roberts D Slater W Spencer MB Weaver M Briere RA Cheu E Harris DA Krolak P McFarland KS Roodman A Schwingenheuer B Somalwar SV Wah YW Winstein B Winston R Barker AR Swallow EC Bock GJ Coleman R Crisler M Enagonio J Ford R Hsiung YB Jensen DA O'Dell VR Ramberg E Tschirhart R Collins EM Gollin GD Nakaya T Yamanaka T 《Physical review letters》1996,76(23):4312-4315
50.