全文获取类型
收费全文 | 369篇 |
免费 | 9篇 |
国内免费 | 5篇 |
专业分类
化学 | 265篇 |
晶体学 | 3篇 |
力学 | 16篇 |
数学 | 24篇 |
物理学 | 75篇 |
出版年
2024年 | 2篇 |
2023年 | 5篇 |
2022年 | 29篇 |
2021年 | 25篇 |
2020年 | 11篇 |
2019年 | 14篇 |
2018年 | 14篇 |
2017年 | 24篇 |
2016年 | 17篇 |
2015年 | 13篇 |
2014年 | 17篇 |
2013年 | 19篇 |
2012年 | 16篇 |
2011年 | 26篇 |
2010年 | 7篇 |
2009年 | 19篇 |
2008年 | 17篇 |
2007年 | 13篇 |
2006年 | 12篇 |
2005年 | 18篇 |
2004年 | 11篇 |
2003年 | 11篇 |
2002年 | 7篇 |
2001年 | 3篇 |
2000年 | 3篇 |
1999年 | 2篇 |
1998年 | 1篇 |
1997年 | 2篇 |
1996年 | 2篇 |
1994年 | 3篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1990年 | 2篇 |
1987年 | 3篇 |
1986年 | 1篇 |
1985年 | 4篇 |
1984年 | 1篇 |
1982年 | 1篇 |
1981年 | 3篇 |
1980年 | 1篇 |
1973年 | 2篇 |
排序方式: 共有383条查询结果,搜索用时 0 毫秒
41.
In this paper, radial basis function (RBFs) based mesh-free method is implemented to find numerical solution of the Kuramoto-Sivashinsky equations. This approach has an edge over traditional methods such as finite-difference and finite element methods because it does not require a mesh to discretize the problem domain, and a set of scattered nodes in the domain of influence provided by initial data is required for the realization of the method. The accuracy of the method is assessed in terms of the error norms L2,L∞, number of nodes in the domain of influence, free parameter, dependent parameter RBFs and time step length. Numerical experiments demonstrate accuracy and robustness of the method for solving a class of nonlinear partial differential equations. 相似文献
42.
Alfi Khatib Vikneswari Perumal Qamar Uddin Ahmed Bisha Fathamah Uzir Faridah Abas Suganya Murugesu 《Analytical letters》2017,50(12):1977-1991
Momordica charantia is widely consumed edible fruit. The food and pharmaceutical industries use it as a natural antioxidant. However, the quality control of M. charantia-based medicinal products is questionable due to the complexity of metabolites in this fruit. Hence, this study has developed a statistical model in predicting the antioxidant value through the 2, 2-diphenyl-1 picrylhydrazyl radical scavenging activity and ferric reducing antioxidant power based on infrared spectroscopy with attenuated total reflectance. This technique was reliably used for quality control. Six ethanol extracts (0, 20, 40, 60, 80, and 100% in water) of this plant’s fruit were prepared. The radical scavenging and ferric reducing antioxidant power activities were measured and the chemical profiling of the extracts was fingerprinted by infrared spectroscopy between 4,000 and 600?cm?1 at a resolution of 4?cm?1. Statistical analysis was developed by correlating the bioactivity and infrared spectra of each extract using orthogonal partial least square discriminant analysis. The C–N, C?O, C–O, C–H, and OH infrared signals were positively correlated with biological activity. The antioxidant activity of the fruit of M. charantia may be due to the presence of several antioxidants that work synergistically. 相似文献
43.
A triterpenoid saponin, guaianin O (1), oleanolic acid 3-O-{α-L-rhamnopyranosyl-(1 → 2)-[β-D-glucopyranosyl-(1 → 3)]-α-L-arabinopyranoside}-28- O-[β-D-glucopyranosyl]-ester, was isolated from the n-butanol extract of flowers of Guaiacum officinale L. The structural elucidation of 1 was accomplished by extensive studies of both one and two dimensional 1H, 13C-NMR spectra, the FAB mass spectrum, and alkaline and acid hydrolyses. 相似文献
44.
M.J. Uddin D. MondalC.A. Morris T. Lopez U. DieboldR.D. Gonzalez 《Applied Surface Science》2011,257(18):7920-7927
Despite the therapeutic efficacy of valproic acid towards numerous diseases, its poor bioavailability and systemic side effects pose significant barriers to long term treatment. In order to take advantage of controlled release implants of valproic acid, the drug was encapsulated into titania ceramic matrices via a sol-gel process. The integrity and structure of valproic acid-containing matrices were characterized through the use of FESEM, TEM, and BET analyses. In vitro controlled release studies and kinetic analyses were performed under ambient conditions (25 °C, atmospheric pressure) and controlled release behaviors were studied using a GC-MS method. Results showed first order dependence in the rate of valproic acid release as a function of drug concentrations in the titania ceramic device. A marked dependence on the surface area and pore size distribution with drug loading was also observed. This research opens new possibilities for the design of novel time-delayed controlled release systems for valproic acid encapsulates. 相似文献
45.
Radial basis function method is an effective tool for solving differential equations in engineering and sciences. Many radial basis functions contain a shape parameter c which is directly connected to the accuracy of the method. Rippa [1] proposed an algorithm for selecting good value of shape parameter c in RBF-interpolation. Based on this idea, we extended the proposed algorithm for selecting a good value of shape parameter c in solving time-dependent partial differential equations. 相似文献
46.
Erhan Bayraktar Arash Fahim 《Numerical Methods for Partial Differential Equations》2014,30(3):902-929
We present a stochastic numerical method for solving fully nonlinear free boundary problems of parabolic type and provide a rate of convergence under reasonable conditions on the nonlinearity. © 2013 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 30: 902–929, 2014 相似文献
47.
ViqarUddin Ahmad MuhammadAthar Abbasi Muhammad Zubair Naheed Fatima Umar Farooq M.Iqbal Choudhary 《Helvetica chimica acta》2004,87(1):67-72
Phytochemical investigation of Symplocos racemosa resulted in the isolation of two new glycosides, symploracemoside ( 1 ) and symplomoside ( 2 ), which are structurally related to the reported benzoylsalireposide ( 3 ) and salireposide ( 4 ). The structure elucidation of the isolated compounds was based primarily on 1D‐ and 2D‐NMR analysis, including COSY, NOESY, HMQC, and HMBC correlations. These glycosides showed inhibitory activity against snake‐venom phosphodiesterase I. 相似文献
48.
Iqbal Saeed Raza Aadil Butt Muhammad Fasih Uddin Mirza Jawad Iqbal Muhammad Ghafoor Salman El-Hajjar Mohammed 《Optical Review》2021,28(3):278-288
Optical Review - In this paper, we propose a full duplex architecture based on a hybrid link composed of free space optics (FSO) and multimode plastic optical fiber (MMPOF) for short-range wireless... 相似文献
49.
Muhammad Zahid Akbar Ali Omar Ishurd Amir Ahmed Zulfiqar Ali ViqarUddin Ahmad Yuanjiang Pan 《Helvetica chimica acta》2002,85(2):689-697
Two new monodesmosidic cycloartane triterpene glycosides, depressosides E and F, and two new flavonol glycosides, depressonol A and B, were isolated from the butanol‐soluble part of the EtOH extract of Corchorus depressus L . The structures of the new compounds were elucidated as (22R,24S)‐22,25‐epoxy‐9,19‐cyclolanostane‐3β,16β,24‐triol 3‐[α‐L ‐rhamnopyranosyl‐(1→4)‐β‐D ‐glucopyranoside] ( 1 ), (22R,24S)‐22,25‐epoxy‐9,19‐cyclolanostane‐3β,16β,24‐triol 3‐[α‐D ‐glucopyranosyl‐(1→3)‐β‐D ‐glucopyranoside] ( 2 ), kaempferol 3‐[β‐D ‐glucopyranosyl‐(1→4)‐β‐D ‐galactopyranoside] 7‐[α‐L ‐arabinofuranoside] ( 4 ), and kaempferol 3‐[β‐D ‐glucopyranosyl‐(1→6)‐β‐D ‐galactopyranoside] 7‐[α‐L ‐arabinofuranoside] ( 5 ) on the basis of chemical evidence and detailed spectroscopic studies. 相似文献
50.
O. A. Bég M. J. Uddin M. M. Rashidi N. Kavyani 《Journal of Engineering Thermophysics》2014,23(2):79-97
This paper investigates combined heat and mass transfer by mixed magneto-convective flow of an electrically conducting flow along a moving radiating vertical flat plate with hydrodynamic slip and thermal convective boundary conditions. The governing transport equations are converted into a system of coupled nonlinear ordinary differential equations with prescribed boundary conditions using similarity variables developed by Lie group theory. The transformed nondimensional boundary value problem is then solved numerically with MAPLE13 quadrature. Excellent correlation with previous nonmagnetic, no-slip studies is achieved. Surface shear stress function and local Nusselt number (heat transfer gradient at the wall) are increased with Richardson number, whereas local Sherwood number is found to initially decrease then subsequently increase. The “thermally thick” scenario (Biot number > 0.1) is investigated and increasing Biot number is observed to enhance shear stress function (skin friction), local Nusselt number, and local Sherwood number. Increasing thermal radiation flux increases thermal boundary layer thickness as does increasing the magnetic field effect. Increasing hydrodynamic slip parameter reduces skin friction but enhances local Nusselt and Sherwood numbers. The study has applications in high-temperature polymeric synthesis and magnetic field flow control. 相似文献