Adiabatic passage Hartmann-Hahn cross polarization in NMR under magic angle sample spinning

We have recently demonstrated that polarization transfer using an adiabatic passage through the Hartmann-Hahn condition (APHH-CP) by a variation of the radio-frequency amplitude can substantially improve the transfer efficiency over Hartmann-Hahn cross polarization. Here we show that APHH-CP can be combined with fast magic angle sample spinning (MAS). The heteronuclear dipolar order, established in the course of the transfer, can indeed be created and preserved.     

Transformation of malonic acid adsorbed on a clay-mineral by gamma irradiation

The effect of clay on the radiolysis of malonic acid solutions was studied. The results showed an enhanced of decarboxylation rather than condensation reactions.     

Searching for losers

We investigate the following process: N people select b losers by flipping coins. The 0-party continues until there are less than b losers; then the 1-party has to find the other losers by the same process. The average time for this process is about long₂ N, but this result requires rather advanced methods. Furthermore, the average size of a binary tree associated to this process and the average number of coin flippings are computed. The method used in this article can be used to give asympotical solutions of a special type of bivariate recurrences. © 1993 John Wiley & Sons, Inc.     

Experimental study of acoustic probing of electrical space charge in solid insulators

Experimental results are presented on acoustic probing of electric fields in solid insulators. An experimental apparatus and methods are described for acoustic measurements of the bulk space charge density and electric field strength in solid insulators. The sensitivity and spatial resolution of the acoustic probe technique are determined.Institute of Introscopy Research, Polytechnical University, Tomsk. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 9, pp. 62–67, September, 1993.     

Optical absorption bistability in quasi-one-dimensional peierls semiconductors

The optical absorption coefficient γ of a thin film of a Peierls semiconductor has been calculated in the dipole approximation for direct interband transitions as a function of intensity I and central frequency ω₀ of a quasi-monochromatic frequency spectrum near the lower optical transition edge. It is shown that the γ(I, ω₀) dependence is strongly nonlinear, and within a certain region of I and ω₀ variation, not single-valued, which indicates the onset of resonator-free optical bistability with increasing absorption.     

Electromagnetic field singularities

An integral transform based method is given for determining information about the locating and properties of singularities of electromagnetic fields associated with axially symmetric radiating sources.     

Spectra and Transport in Almost Periodic Dimers

We study spectral properties of discrete Schrödinger operators with potentials obtained via dimerization of a class of aperiodic sequences. It is shown that both the nature of the autocorrelation measure of a regular sequence and the presence of generic (full probability) singular continuous spectrum in the hull of primitive and palindromic (four block substitution) potentials are robust under dimerization. Generic results also hold for circle potentials. We illustrate these results with numerical studies of the quantum mean square displacement as a function of time. The numerical techniques provide a very fast algorithm for the time evolution of wave packets.     

An M/G/1 Retrial Queueing System with Two-Phase Service and Preemptive Resume

An M/G/1 retrial queueing system with additional phase of service and possible preemptive resume service discipline is considered. For an arbitrarily distributed retrial time distribution, the necessary and sufficient condition for the system stability is obtained, assuming that only the customer at the head of the orbit has priority access to the server. The steady-state distributions of the server state and the number of customers in the orbit are obtained along with other performance measures. The effects of various parameters on the system performance are analysed numerically. A general decomposition law for this retrial queueing system is established.     

Efficient Collocation Schemes for Singular Boundary Value Problems

We discuss an error estimation procedure for the global error of collocation schemes applied to solve singular boundary value problems with a singularity of the first kind. This a posteriori estimate of the global error was proposed by Stetter in 1978 and is based on the idea of Defect Correction, originally due to Zadunaisky. Here, we present a new, carefully designed modification of this error estimate which not only results in less computational work but also appears to perform satisfactorily for singular problems. We give a full analytical justification for the asymptotical correctness of the error estimate when it is applied to a general nonlinear regular problem. For the singular case, we are presently only able to provide computational evidence for the full convergence order, the related analysis is still work in progress. This global estimate is the basis for a grid selection routine in which the grid is modified with the aim to equidistribute the global error. This procedure yields meshes suitable for an efficient numerical solution. Most importantly, we observe that the grid is refined in a way reflecting only the behavior of the solution and remains unaffected by the unsmooth direction field close to the singular point.     

Thoms Effect as Influenced by the Concentration and Molecular Parameters of the Cationic Copolymer of Acrylamide

The Thoms effect observed with water-soluble cationic copolymer of acrylamide was studied in relation to the concentration, molecular weight, and molecular weight polydispersity of the polymeric additive, with its composition and composition polydispersity being constant.