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71.
A. Miele T. Wang C. Y. Tzeng W. W. Melvin 《Journal of Optimization Theory and Applications》1993,77(1):1-29
This paper deals with the identification of the wind profile along a flight trajectory by means of a two-dimensional dynamic approach. In this approach, the wind velocity components are computed as the difference between the inertial velocity components and the airspeed components. The airspeed profile as well as the nominal thrust, drag, and lift profiles are obtained from the available DFDR measurements. The actual values of the thrust, drag, and lift are assumed to be proportional to the respective nominal values via multiplicative parameters, called the thrust, drag, and lift factors. The thrust, drag, and lift factors plus the inertial velocity components at impact are determined by matching the flight trajectory computed from DFDR data with the flight trajectory available from ATCR data. This leads to a least-square problem which is solved analytically under the additional requirement of closeness of the multiplicative factors to unity. Application of the 2D-dynamic approach to the case of Flight Delta 191 shows that, with reference to the last 180 sec before impact, the values of the multiplicative factors were 1.09, 0.84, and 0.89; this implies that the actual values of the thrust, drag, and lift were 9% above, 16% below, and 11% below their respective nominal values. For the last 60 sec before impact, the aircraft was subject to severe windshear, characterized by a horizontal wind velocity difference of 123 fps and a vertical wind velocity difference of 80 fps. The 2D-dynamic approach is applicable to the analysis of windshear accidents in take-off or landing, especially for the case of older-generation, shorter-range aircraft which do not carry the extensive instrumentation of newer-generation, longer-range aircraft. The same methodology can be extended to the investigation of aircraft accidents originating from causes other than windshear (e.g., icing, incorrect flap position, engine malfunction), above all if its precision is further increased by combining the 2D-dynamic approach and the 2D-kinematic approach. 相似文献
72.
The reactions of trimethylindium (TMIn) with HN3 and NH3 are relevant to the chemical vapor deposition of indium nitride thin film. The mechanisms and energetics of these reactions in the gas phase have been investigated by density functional theory and ab initio calculations using the CCSD(T)/Lanl2dz//B3LYP/Lanl2dz and CCSD(T)/Lanl2dz//MP2/Lanl2dz methods. The results of both methods are in good agreement for the optimized geometries and relative energies. These results suggest that the reaction with HN3 forms a new stable product, dimethylindiumnitride, CH3-In=N-CH3 via another stable In(CH3)2N3 (dimethylindium azide, DMInA) intermediate. DMInA may undergo unimolecular decomposition to form CH3InNCH3 by two main possible pathways: (1) a stepwise decomposition process through N2 elimination followed by CH3 migration from In to the remaining N atom and (2) a concerted process involving the concurrent CH3 migration and N2 elimination directly giving N2+CH3InNCH3. The reaction of TMIn with NH3 forms a most stable product DMInNH2 following the initial association and CH4-elimination reaction. The required energy barrier for the elimination of the second CH4 molecule from DMInNH2 is 74.2 kcal/mol. Using these reactions, we predict the heats of formation at 0 K for all the products and finally for InN which is 123+/-1 kcal/mol predicted by the two methods. The gas-phase reaction of HN3 with TMIn is compared with that occurring on rutile TiO2 (110). The most noticeable difference is the high endothermicity of the gas-phase reaction for InN production (53 kcal/mol) and the contrasting large exothermicity (195 kcal/mol) released by the low-barrier Langmuir-Hinshelwood type processes following the adsorption of TMIn and HN3 on the surface producing a horizontally adsorbed InN(a), Ti-NIn-O(a), and other products, CH4(g)+N2(g)+2CH3O(a) [J. Phys. Chem. B 2006, 110, 2263]. 相似文献
73.
Photodissociation dynamics for various tryptophan chromophores was studied at 193 or 248 nm using multimass ion imaging techniques. The competition between internal conversion to the ground electronic state and dissociation from the repulsive excited state reveals size-dependent photostability for these amino acid chromophores. As the size of chromophore increases, internal conversion to the ground state becomes the major nonradiative process. For tryptophan and larger chromophores, dissociation directly from the repulsive state is completely quenched. 相似文献
74.
75.
Wang CF Tzeng FS Chen HG Chang CJ 《Langmuir : the ACS journal of surfaces and colloids》2012,28(26):10015-10019
In this paper, we report a simple and an inexpensive method for fabricating superhydrophobic/superoleophilic mesh films from microstructured ZnO coatings. The microstructured ZnO coatings, which do not contain any fluorinated compounds, maintain their superhydrophobicity and superoleophilicity after ultraviolet irradiation and display environmental stability. Furthermore, those microstructured ZnO-coated mesh films exhibit good selectivity (even underwater) and excellent recyclability, making them promising candidates for many potential applications, including liquid-liquid separation, water treatment, and liquid transportation. 相似文献
76.
Prof. Biing‐Chiau Tzeng Tsung‐Yi Chang Sheng‐Luen Wei Dr. Hwo‐Shuenn Sheu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(16):5105-5112
A 1D double‐zigzag framework, {[Zn(paps)2(H2O)2](ClO4)2}n ( 1 ; paps=N,N′‐bis(pyridylcarbonyl)‐4,4′‐diaminodiphenyl thioether), was synthesized by the reaction of Zn(ClO4)2 with paps. However, a similar reaction, except that dry solvents were used, led to the formation of a novel 2D polyrotaxane framework, [Zn(paps)2(ClO4)2]n ( 2 ). This difference relies on the fact that water coordinates to the ZnII ion in 1 , but ClO4? ion coordination is found in 2 . Notably, the structures can be interconverted by heating and grinding in the presence of moisture, and such a structural transformation can also be proven experimentally by powder and single‐crystal X‐ray diffraction studies. The related N,N′‐bis‐ (pyridylcarbonyl)‐4,4′‐diaminodiphenyl ether (papo) and N,N′‐(methylenedi‐para‐phenylene)bispyridine‐4‐carboxamide (papc) ligands were reacted with ZnII ions as well. When a similar reaction was performed with dry solvents, except that papo was used instead of paps, the product mixture contained mononuclear [Zn(papo)(CH3OH)4](ClO4)2 ( 5 ) and the polyrotaxane [Zn(papo)2(ClO4)2]n ( 4 ). From the powder XRD data, grinding this mixture in the presence of moisture resulted in total conversion to the pure double‐zigzag {[Zn(papo)2(H2O)2](ClO4)2}n ( 3 ) immediately. Upon heating 3 , the polyrotaxane framework of 4 was recovered. The double‐zigzag {[Zn(papc)2(H2O)2](ClO4)2}n ( 6 ) and polyrotaxane [Zn(papc)2(ClO4)2]n ( 7 ) were synthesized in a similar reaction. Although upon heating the double‐zigzag 6 undergoes structural transformation to give the polyrotaxane 7 , grinding solid 7 in the presence of moisture does not lead to the formation of 6 . Significantly, the bright emissions for double‐zigzag frameworks of 1 and 3 and weak ones for polyrotaxane frameworks of 2 and 4 also show interesting mechanochromic luminescence. 相似文献
77.
Y.C. Huang W.S. Tzeng C.C. Wang B.C. Cheng Y.K. Chang H.H. Chen P.C. Lin T.Y. Huang T.J. Chuang J.W. Lin C.P. Chang 《Magnetic resonance imaging》2013
Purpose
This study aimed to further investigate the effects of agmatine on brain edema in the rats with middle cerebral artery occlusion (MCAO) injury using magnetic resonance imaging (MRI) monitoring and biochemical and histopathologic evaluation.Materials and methods
Following surgical induction of MCAO for 90 min, agmatine was injected 5 min after beginning of reperfusion and again once daily for the next 3 post-operative days. The events during ischemia and reperfusion were investigated by T2-weighted images (T2WI), serial diffusion-weighted images (DWI), calculated apparent diffusion coefficient (ADC) maps and contrast-enhanced T1-weighted images (CE-T1WI) during 3 h–72 h in a 1.5 T Siemens MAGNETON Avanto Scanner. Lesion volumes were analyzed in a blinded and randomized manner. Triphenyltetrazolium chloride (TTC), Nissl, and Evans Blue stainings were performed at the corresponding sections.Results
Increased lesion volumes derived from T2WI, DWI, ADC, CE-T1WI, and TTC all were noted at 3 h and peaked at 24 h–48 h after MCAO injury. TTC-derived infarct volumes were not significantly different from the T2WI, DWI-, and CE-T1WI-derived lesion volumes at the last imaging time (72 h) point except for significantly smaller ADC lesions in the MCAO model (P < 0.05). Volumetric calculation based on TTC-derived infarct also correlated significantly stronger to volumetric calculation based on last imaging time point derived on T2WI, DWI or CE-T1WI than ADC (P < 0.05). At the last imaging time point, a significant increase in Evans Blue extravasation and a significant decrease in Nissl-positive cells numbers were noted in the vehicle-treated MCAO injured animals. The lesion volumes derived from T2WI, DWI, CE-T1WI, and Evans blue extravasation as well as the reduced numbers of Nissl-positive cells were all significantly attenuated in the agmatine-treated rats compared with the control ischemia rats (P < 0.05).Conclusion
Our results suggest that agmatine has neuroprotective effects against brain edema on a reperfusion model after transient cerebral ischemia. 相似文献78.
Tzeng BC Chang TY Wei SL Sheu HS 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(16):5105-5112
A 1D double-zigzag framework, {[Zn(paps)(2)(H(2)O)(2)](ClO(4))(2)}(n) (1; paps = N,N'-bis(pyridylcarbonyl)-4,4'-diaminodiphenyl thioether), was synthesized by the reaction of Zn(ClO(4))(2) with paps. However, a similar reaction, except that dry solvents were used, led to the formation of a novel 2D polyrotaxane framework, [Zn(paps)(2)(ClO(4))(2)](n) (2). This difference relies on the fact that water coordinates to the Zn(II) ion in 1, but ClO(4)(-) ion coordination is found in 2. Notably, the structures can be interconverted by heating and grinding in the presence of moisture, and such a structural transformation can also be proven experimentally by powder and single-crystal X-ray diffraction studies. The related N,N'-bis- (pyridylcarbonyl)-4,4'-diaminodiphenyl ether (papo) and N,N'-(methylenedi-para-phenylene)bispyridine-4-carboxamide (papc) ligands were reacted with Zn(II) ions as well. When a similar reaction was performed with dry solvents, except that papo was used instead of paps, the product mixture contained mononuclear [Zn(papo)(CH(3)OH)(4)](ClO(4))(2) (5) and the polyrotaxane [Zn(papo)(2)(ClO(4))(2)](n) (4). From the powder XRD data, grinding this mixture in the presence of moisture resulted in total conversion to the pure double-zigzag {[Zn(papo)(2)(H(2)O)(2)](ClO(4))(2)}(n) (3) immediately. Upon heating 3, the polyrotaxane framework of 4 was recovered. The double-zigzag {[Zn(papc)(2)(H(2)O)(2)](ClO(4))(2)}(n) (6) and polyrotaxane [Zn(papc)(2)(ClO(4))(2)](n) (7) were synthesized in a similar reaction. Although upon heating the double-zigzag 6 undergoes structural transformation to give the polyrotaxane 7, grinding solid 7 in the presence of moisture does not lead to the formation of 6. Significantly, the bright emissions for double-zigzag frameworks of 1 and 3 and weak ones for polyrotaxane frameworks of 2 and 4 also show interesting mechanochromic luminescence. 相似文献
79.
Zheng-Hao Tzeng 《Tetrahedron》2009,65(15):2879-1979
Efficient synthetic routes have been developed for the synthesis of a series of pyrrolidinyl-camphor containing organocatalysts (1-10). Structural modifications were made by varying the stereo- and electronic properties of the camphor scaffold and the aromatic substituents. These readily tunable and amphiphilic organocatalysts were evaluated for the direct asymmetric aldol reaction of various aromatic aldehydes and cyclohexanone either in organic solvents or in the presence of water. The aldol reaction proceeded smoothly with excellent chemical yields (up to 99%), enantioselectivities (up to 99% ee), and anti-diastereoselectivities (up to 99:1) with a catalytical amount of the bifunctional organocatalysts (20 mol %) under optimal reaction conditions. Mechanistic transition models are proposed and the stereochemical bias of the asymmetric aldol reaction is presented. 相似文献
80.
Growth characteristics of ultra long double-ended acicular ZnO synthesized by a hydrothermal process
Double-ended acicular ZnO structure can be synthesized via a hydrothermal process with tetramethylammonium hydroxide and zinc acetate as precursors and polyvinyl alcohol (PVA) as a structure-directing agent. The as-prepared ZnO products show the well crystalline wurtzite structure with growth direction along [0 0 0 1]. For the first time, PVA is found to be employed as a reservoir of Zn2+ ions in the present study, and can control the concentration of Zn2+ in reaction solution, and the acicular morphology can be formed at the two ends of the 1-D ZnO structure, due to the effect of secondary growth that occurs as the sufficient concentration of Zn2+ ions chelated by PVA releasing to the reaction solution. Furthermore, the size of the 1-D ZnO structure can be tuned by different amounts of PVA addition. 相似文献