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91.
While performing biomolecular interaction analysis (BIA), scientistsoften use surface plasmon resonance (SPR) to measure rate constantsof the associated reactions. A mathematical model of a BIAcoreTM,a common SPR device, consists of a convection-diffusion equationin a channel with a reacting surface at the channel ceiling.Asymptotic and singular perturbation techniques are used toanalyse the concentration of the reacting species in two cases:when the reaction occurs much more slowly than diffusion, andwhen the reaction occurs on the same time-scale as diffusion.Linear and nonlinear integral equations result from the analysis;explicit and asymptotic solutions are constructed for physicallyrealizable cases. These expressions provide a direct way toestimate the rate constants from raw data. 相似文献
92.
V. M. Tyurin 《Mathematical Notes》1999,66(1):120-123
The invertibility and injectivity properties of linear differential operators with closed range and Poisson coefficients are
studied in the context of their equivalence in several spaces of vector functions defined on the axis.
Translated fromMatematicheskie Zametki, Vol. 65, No. 1, pp. 143–147, January, 1999. 相似文献
93.
The conformation ofэSiOC·H2 radicals was determined by comparison of the ESR data and results of quantum-chemical calculations. Based on the experimental
data, the characteristic times τc of rotational mobility ofэSiOC·H2 radicals grafted onto a silica surface were estimated over the temperature interval from 77 (τc = 15.8 · 10-8 s) to 295 K (τc 1.3 · 10-8 s).
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2092–2095, November, 1999. 相似文献
94.
95.
A. S. Demyanova T. L. Belyaeva A. N. Danilov Yu. A. Glukhov S. A. Goncharov S. V. Khlebnikov V. A. Maslov Yu. D. Molchanov Yu. E. Penionzkevich R. V. Revenko M. V. Safonenko Yu. G. Sobolev W. Trzaska G. P. Tyurin A. A. Ogloblin 《Physics of Atomic Nuclei》2009,72(10):1611-1616
We present new measurements of the α + 12C elastic and inelastic (to the states 4.44, 7.65, and 9.64 MeV) scattering at E lab = 110 MeV in the wide angular range from ~10° to 175°, which enable us to examine the condensate and cluster properties of the low-lying excited states in 12C. We present the diffraction-radius analysis of our data together with a considerable amount of the existing data. The magnitudes of the diffraction radii for the ground and the first excited (4.44 MeV) states are found to be equal, whereas they appear to be enhanced by ~0.6 fm both for 7.65 and 9.64 MeV states. This result shows that the radius of the Hoyle’s 0 2 + , 7.65 MeV state in 12C is by a factor of ~1.2–1.3 larger than that of the ground state. It is demonstrated that the direct transfer mechanism of 8Be dominates at the largest angles in all four reactions reported here. The configuration corresponding to the transfer of 8Be in its ground state (I π = 0+) with L = 0 turns out to be the most important for the 7.65 MeV state of 12C. Evidence of existence of some features of α-condensed structure of the Hoyle’s 0 2 + state in 12C was obtained: its enhanced radius and large contribution of α-particle configuration with L = 0. 相似文献
96.
97.
对-叔丁基杯[8]芳烃键合硅胶制备及其毛细管电色谱性能研究 总被引:1,自引:0,他引:1
以γ-(环氧丙氧)丙基键合硅胶为前体,于硅胶表面键合环氧基,在催化剂存在下以杯芳烃钠盐开环制备杯芳烃键合硅胶固定相.该方法反应条件温和,适用性强.将这个新方法首次用于制备对-叔丁基杯[8]芳烃电色谱键合固定相(C8BS),采用加压电色谱初步评价其电色谱性能.研究结果表明,C8BS电渗流(Electrosmoticflow,EOF)较小,但通过控制键合反应及使用压力辅助电色谱可部分弥补上述不足.该固定相的EOF受流动相pH影响小(pH=3-8),同时大环配体屏蔽效应能有效地克服硅羟基引起的碱性化合物拖尾现象,这对电色谱分离具有重要意义.通过分步封尾研究EOF的来源发现,杯芳烃酚羟基对EOF有弱的贡献,这与报道的杯芳烃涂层具有径向电渗流调控能力相一致. 相似文献
98.
99.
100.
A. Yu. Tyurin A. M. Churakov Yu. A. Strelenko V. A. Tartakovsky 《Russian Chemical Bulletin》2009,58(1):212-215
Thermolysis of 7-azido-8-(2H-1,2,3-triazol-2-y1)-1,2,3,4-benzotetrazine 1,3-dioxide and 7-azido-8-(l H-1,2,3-triazol-l-yl)-1,2,3,4-benzotetrazine 1,3-dioxide afford new heterocyclic systems, viz., 7,11-dehydro-7H, 11H [1,2,3]triazolo[l′,2′:2,3][1,2,3]triazolo[4,5-f]-[1,2,3,4]benzotetrazine 1,3-dioxide and 7,9-dehydro-7 H, 9H [1,2,3]triazolo[2′,1′:2,3]-[1,2,3]triazolo[4,5-f][1,2,3,4]benzotetrazine 1,3-dioxide, respectively, and their thermal stability has been studied. 相似文献