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11.
Chakraborty TK Roy S Koley D Dutta SK Kunwar AC 《The Journal of organic chemistry》2006,71(16):6240-6243
Cyclic oligomers of tetrahydrofuran amino acids, cyclo-(Taa1-Leu-Val)2 (left), cyclo-(Taa2-Leu-Val)2 (middle), and cyclo-(Taa2-Phe-Leu)2 (right), displayed well-defined intramolecularly hydrogen-bonded structures with distorted "beta-beta corner" motifs similar to the tennis ball seam. 相似文献
12.
Organocatalytic Asymmetric Mannich Cyclization of Hydroxylactams with Acetals: Total Syntheses of (−)‐Epilupinine, (−)‐Tashiromine,and (−)‐Trachelanthamidine 下载免费PDF全文
Dr. Dipankar Koley Yarkali Krishna Kyatham Srinivas Afsar Ali Khan Ruchir Kant 《Angewandte Chemie (International ed. in English)》2014,53(48):13196-13200
An asymmetric, organocatalytic, one‐pot Mannich cyclization between a hydroxylactam and acetal is described to provide fused, bicyclic alkaloids bearing a bridgehead N atom. Both aliphatic and aromatic substrates were used in this transformation to furnish chiral pyrrolizidinone, indolizidinone, and quinolizidinone derivatives in up to 89 % yield and 97 % ee. The total syntheses of (?)‐epilupinine, (?)‐tashiromine, and (?)‐trachelanthamidine also achieved to demonstrate the generality of the process. 相似文献
13.
Goossen LJ Koley D Hermann HL Thiel W 《Journal of the American Chemical Society》2005,127(31):11102-11114
The mechanism of the cross-coupling of phenylboronic acid with acetic anhydride, a viable model of the widely used Suzuki reaction, has been studied by DFT calculations at the BP86/6-31G level of theory. Two alternative catalytic cycles have been investigated, one starting from a neutral Pd(0)L(2) complex, the other from an anionic "Jutand-type" [Pd(0)L(2)X](-) species. The reaction profiles are in good agreement with the experimental findings, as both pathways require only moderate activation energies. Both pathways are dominated by cis-configured square-planar palladium(II)diphosphine intermediates. Despite careful investigations, we did not find in this model reaction any evidence for five-coordinate palladium(II) intermediates, which are commonly believed to cause the profound effects of counterions in palladium-catalyzed transformations. Instead, our calculations suggest that the higher catalytic activity of anionic complexes, such as [Pd(PMe(3))(2)OAc](-), may arise from their stronger ability to coordinate to carbon electrophiles. The transmetalation sequence is the same for both catalytic cycles, involving the dissociation of one phosphine ligand from the palladium. In the decisive transition state, in which the phenyl group is transferred from boron to palladium, the acetate base is found to be in a bridging coordination between these two atoms. 相似文献
14.
Ujjwal Koley 《Central European Journal of Mathematics》2012,10(1):173-187
We are concerned with convergence of spectral method for the numerical solution of the initial-boundary value problem associated to the Korteweg-de Vries-Kawahara equation (Kawahara equation, in short), which is a transport equation perturbed by dispersive terms of the 3rd and 5th order. This equation appears in several fluid dynamics problems. It describes the evolution of small but finite amplitude long waves in various problems in fluid dynamics. These equations are discretized in space by the standard Fourier-Galerkin spectral method and in time by the explicit leap-frog scheme. For the resulting fully discrete, conditionally stable scheme we prove an L 2-error bound of spectral accuracy in space and of second-order accuracy in time. 相似文献
15.
Jet substructure is typically studied using clustering algorithms, such as k(T), which arrange the jets' constituents into trees. Instead of considering a single tree per jet, we propose that multiple trees should be considered, weighted by an appropriate metric. Then each jet in each event produces a distribution for an observable, rather than a single value. Advantages of this approach include (1) observables have significantly increased statistical stability, and (2) new observables, such as the variance of the distribution, provide new handles for signal and background discrimination. For example, we find that employing a set of trees substantially reduces the observed fluctuations in the pruned mass distribution, enhancing the likelihood of new particle discovery for a given integrated luminosity. Furthermore, the resulting pruned mass distributions for (background) QCD jets are found to be substantially wider than that for (signal) jets with intrinsic mass scales, e.g., boosted W jets. A cut on this width yields a substantial enhancement in significance relative to a cut on the standard pruned jet mass alone. In particular the luminosity needed for a given significance requirement decreases by a factor of 2 relative to standard pruning. 相似文献
16.
A direct access to symmetrical and unsymmetrical 2,5-disubstituted [1,3,4]-oxadiazoles has been accomplished through an imine C-H functionalization of N-arylidenearoylhydrazide using a catalytic quantity of Cu(OTf)(2). This is the first example of amidic oxygen functioning as a nucleophile in a Cu-catalyzed oxidative coupling of an imine C-H bond. These reactions can be performed in air atmosphere and moisture making it exceptionally practical for application in organic synthesis. 相似文献
17.
Bhattacharyya Sombuddha Ghosh Tuhin 《Journal of Fourier Analysis and Applications》2019,25(3):661-683
Journal of Fourier Analysis and Applications - We consider the following perturbed polyharmonic operator $$\mathcal {L}(x,D)$$ of order 2m defined in a bounded domain $$\Omega \subset \mathbb... 相似文献
18.
Dette Holger Dhar Subhra Sankar Wu Weichi 《Annals of the Institute of Statistical Mathematics》2021,73(5):855-889
Annals of the Institute of Statistical Mathematics - This article studies the problem whether two convex (concave) regression functions modelling the relation between a response and covariate in... 相似文献
19.
Silanylidene and Germanylidene Anions: Valence‐Isoelectronic Species to the Well‐Studied Phosphinidene 下载免费PDF全文
Dr. Mujahuddin M. Siddiqui Dr. Soumen Sinhababu Sayan Dutta Dr. Subrata Kundu Paul Niklas Ruth Annika Münch Dr. Regine Herbst‐Irmer Prof. Dietmar Stalke Dr. Debasis Koley Prof. Herbert W. Roesky 《Angewandte Chemie (International ed. in English)》2018,57(36):11776-11780
The reduction of TipMCl3 (Tip=2,4,6‐triisopropylphenyl) (M=Si, Ge) with KC8 in the presence of cyclic alkyl(amino) carbene (cAAC) afforded the acyclic silanylidene and germanylidene anions in the form of potassium salt [K(cAAC)MTip]2 (M=Si ( 1 ); Ge ( 2 )). The silanylidene and germanylidene anions are valence‐isoelectronic to the well‐studied phosphinidene and are a new class of acyclic anions of Group 14. Compounds 1 and 2 were isolated and well characterized by NMR and single‐crystal X‐ray structure analysis. Furthermore, the structure and bonding of compounds 1 and 2 was investigated by computational methods. 相似文献
20.
Pande S Sarkar AK Basu M Jana S Sinha AK Sarkar S Pradhan M Saha S Pal A Pal T 《Langmuir : the ACS journal of surfaces and colloids》2008,24(16):8991-8997
A straightforward route to gram level synthesis of a pure phase of the Sn-Ag nanoalloy in an eutectic composition (Sn/Ag 96.5:3.5) in silicone oil is reported. The composition, morphology, and microstructure of the alloy were fully characterized. In a mixture of ethylene glycol and silicone oil, direct reduction of Sn(II) acetate and Ag(I) nitrate gave the Sn-Ag nanoalloy. The nanoalloy disintegrates by sonication and reforms by heating, leading to smaller particles with a melting point as low as 128 degrees C. 相似文献