Superconductivity at 45 K in La2CuO4+δ oxidized by NaClO

An efficient and convenient oxidizing agent, sodium hypochlorite solution, has been used to chemically prepare the superconductor La₂CuO_4+δ at room temperature. The crystallographic data show an enhanced orthorhombic distortion and an increase of the unit-cell volume. The magnetic susceptibility properties reveal a sharp transition beginning at 45 K and the oxidized sample is a homogeneous and single-phase bulk superconductor. The iodometric titration measurements indicate that the oxidized sample has a higher excess-oxygen content of 0.11. Scanning electron microscope observations showed that no grain size difference was observed for the sample before and after oxidation. Received: 15 September 2000 / Accepted: 19 January 2001 / Published online: 3 April 2001     

Design and Synthesis of Guanidinoglycosides Directed against the TAR RNA of HIV‐1

Replication of human immunodeficiency virus type 1 (HIV‐1) requires specific interactions of the Tat protein with the transactivation responsive region (TAR) RNA. Tat‐TAR RNA Interaction is mediated by a short arginine‐rich domain of the protein. Disruption of this interaction could, in theory, create a state of complete viral latency. Here, four novel 6‐amino‐6‐deoxytrehalose guanidinoglycoside derivatives ( 10 and 13 – 15 ) as target molecules have been designed to bind to TAR RNA for blocking the interaction of Tat‐TAR RNA. They were obtained by coupling 6‐amino‐6‐deoxy‐α,α‐trehalose ( 6 ) with the protected amino acids, deprotection by catalytic hydrogenation, followed by guanidinylated with S‐methylisothiourea sulfate. Their abilities to inhibit Tat‐TAR RNA interaction were determined by a Tat‐dependent HIV‐1 long terminal repeats (LTR)‐driven chloramphenicol acetyltransferase (CAT) assays.     

Some 4(1h) Pyridylidene Compounds II Synthesis and Structure of N,N-Conjugated-4-Pyridine Compounds

The reaction of 4-methylpyridine and its methiodide with p-N, N-dimethylamino-benzaldehyde gave 4-p-N, N-dimethylaminostyrylpyridine (I) and 4-p-N, N-dimethylaminostyrylpyridine methiodide (II), respectively, II was also prepared by methylation of I with methyl iodide in methanol. The pyridylidene structure of II, N-benzyl-4-(p-N, N-dimethylaminophenyl) pyridinium chloride (IV_a) and its methiodide (V_a) was discussed in terms of UV, NMR and mass spectra.     

Influence of microstructure on space charges of polypropylene

The correlation of chemical structure, crystalline morphology, and space charge distribution under a dc electrical field was investigated with three kinds of poly(propylene) (PP) with a different chemical structure, that is, homogeneous PP and block copolymer and random copolymer of PP. The space charge distribution of the samples was prominently affected by their chemical sequence structure and crystalline microstructure. Among samples of different PPs, all isothermally crystallized at 140 °C, the sample of random coPP represents the most well proportional space charge distribution and the smallest number of space charges. The effect of thermal history on the space charge distribution was also investigated by the samples of block coPP. The sample thermally treated at 50 °C clearly represents a better proportional distribution than that at higher temperature of 140 and 100 °C. Subsequent experiments indicate that the better proportional distribution attributes to imperfect and fine sperulites with the fine distribution of the “amorphous” region. The imperfect and fine sperulites originate from the random incorporation of ethylene segments or units into PP chains or from the low annealing temperature, and play an important role in the formation of shallow traps and transportation of space charges. © 2002 John Wiley & Sons, Inc. J Polym Sci Part B: Polym Phys 40: 365–374, 2002; DOI 10.1002/polb.10100     

Copper‐Catalyzed Formal [2+2+1] Heteroannulation of Alkenes,Alkylnitriles, and Water: Method Development and Application to a Total Synthesis of (±)‐Sacidumlignan D

A copper‐catalyzed three‐component reaction of alkenes, alkylnitriles, and water affords γ‐butyrolactones in good yields. The domino process involves an unprecedented hydroxy‐cyanoalkylation of alkenes and subsequent lactonization with the creation of three chemical bonds and a quaternary carbon center. The synthetic potential of this novel [2+2+1] heteroannulation reaction was illustrated by a concise total synthesis of (±)‐sacidumlignan D.     

例谈复合场中的守恒量

通过对3个复合场中守恒量的寻找和处理,体现某些物理量的特点,直观展示物理变化过程中的规律,这对我们平时分析和研究物理问题或许有一定的借鉴.     

Optimizing the manufacturing parameters of carbon nanotubes stiffened speaker diaphragm using Taguchi method

This study developed a thermal transfer printing (TTP) technique to fabricate a carbon nanotubes (CNTs) stiffened speaker diaphragm. The self-developed TTP stiffening technique does not require a high curing temperature that decreases the mechanical property of CNTs. Therefore, the inherent strength of CNTs was preserved. In addition to increasing the stiffness of diaphragm substrate, this technique alleviates the middle and high frequency attenuation associated with the sound pressure curve of a speaker, thereby smoothing the sound pressure curve and achieving a full sound range as well as reducing bass distortion and enhancing treble clarity. Furthermore, the TTP technique can stiffen a localized area on a diaphragm substrate, thus increasing diaphragm stiffness without markedly raising diaphragm weight. The Taguchi quality engineering method was applied to identify the optimal process parameters (i.e., transfer area, stiffening pattern, coating layers, and transfer temperature). Finally, the optimal process parameters were employed to fabricate a stiffened diaphragm, which was then assembled onto a speaker. The result indicated that the stiffened diaphragm improved the smoothness of the sound pressure curve for the speaker, which produced a mid-frequency dip difference (ΔdB) of 1.9 dB and an attenuation peak frequency (f_peak) of 4220 Hz.     

Syntheses of diheterocyclic compounds based on 2-thioacetohydrazide-5,7-dimethyl-1,2,4-triazolo[1,5-a]- pyrimidine

The syntheses of some diheterocyclic compounds from 2-thioacetohydrazide- 5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine (1) are described. Compound 1 can be converted into triazoles, 1,3,4-oxadiazoles, and 1,3,4-thiadiazoles. The structures of the intermediates and the target compounds were confirmed by (1)H-NMR, MS and elemental analyses.