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排序方式: 共有178条查询结果,搜索用时 15 毫秒
41.
Jyh‐Horng Wu Yi‐Fu Chang Yu‐Tang Tung Minoru Tsuzuki Akira Izuka Sheng‐Yang Wang Yueh‐Hsiung Kuo 《Helvetica chimica acta》2010,93(4):753-756
Two novel 15(10→1)abeomuurolane sesquiterpenes, cosmosoic acid ( 1 ) and cosmosaldehyde ( 2 ), were isolated from the whole plant of Cosmos sulfurous. Their structures were established by a combination of 1D‐ and 2D‐NMR spectroscopic techniques. Additionally, a chemical correlation between 1 and 2 was also established. 相似文献
42.
Jinfeng Wang Takuya Tsuzuki Bin Tang Pavel Cizek Lu Sun Xungai Wang 《Colloid and polymer science》2010,288(18):1705-1711
The preparation of silica-coated ZnO nanocomposite using polyvinyl pyrrolidone (PVP) as a coupling agent was investigated.
Transmission electron microscopy analysis revealed that silica has been deposited on the surface of PVP-capped ZnO nanoparticles
as a continuous thin layer. Two-dimensional correlation analysis based on the time-dependent UV–vis spectra was introduced
to study the interaction governing the deposition of silica on to PVP-capped ZnO. Strong hydrogen bonds formed between the
amphiphilic PVP molecules and silica in the silica-coated PVP-capped ZnO composites. The reduced photocatalytic activity of
silica-coated ZnO nanoparticles will enhance their performance as durable, safe, and non-reactive UV blockers in plastics,
paints, and coating for outdoor textile and timber products. 相似文献
43.
Tsuzuki S Honda K Uchimaru T Mikami M Fujii A 《The journal of physical chemistry. A》2006,110(33):10163-10168
The CCSD(T) level interaction energies of CH/pi complexes at the basis set limit were estimated. The estimated interaction energies of the benzene complexes with CH(4), CH(3)CH(3), CH(2)CH(2), CHCH, CH(3)NH(2), CH(3)OH, CH(3)OCH(3), CH(3)F, CH(3)Cl, CH(3)ClNH(2), CH(3)ClOH, CH(2)Cl(2), CH(2)FCl, CH(2)F(2), CHCl(3), and CH(3)F(3) are -1.45, -1.82, -2.06, -2.83, -1.94, -1.98, -2.06, -2.31, -2.99, -3.57, -3.71, -4.54, -3.88, -3.22, -5.64, and -4.18 kcal/mol, respectively. Dispersion is the major source of attraction, even if substituents are attached to the carbon atom of the C-H bond. The dispersion interaction between benzene and chlorine atoms, which is not the CH/pi interaction, is the cause of the very large interaction energy of the CHCl(3) complex. Activated CH/pi interaction (acetylene and substituted methanes with two or three electron-withdrawing groups) is not very weak. The nature of the activated CH/pi interaction may be similar to the hydrogen bond. On the other hand, the nature of other typical (nonactivated) CH/pi interactions is completely different from that of the hydrogen bond. The typical CH/pi interaction is significantly weaker than the hydrogen bond. Dispersion interaction is mainly responsible for the attraction in the CH/pi interaction, whereas electrostatic interaction is the major source of attraction in the hydrogen bond. The orientation dependence of the interaction energy of the typical CH/pi interaction energy is very small, whereas the hydrogen bond has strong directionality. The weak directionality suggests that the hydrogen atom of the interacting C-H bond is not essential for the attraction and that the typical CH/pi interaction does not play critical roles in determining the molecular orientation in molecular assemblies. 相似文献
44.
The Ramanujan Journal - In this paper, we give an optimal estimate of an average of Hurwitz class numbers. As an application, we give an equidistribution result of the family $$\Big... 相似文献
45.
Yoshiharu Tsujita Ryoko Ojika Koji Tsuzuki Akira Takizawa Takatoshi Kinoshita 《Journal of polymer science. Part A, Polymer chemistry》1987,25(4):1041-1048
Copoly(γ-stearly-L -glutamate-γ-methyl-L -glutamate)s with various compositions were synthesized by the ester exchange reaction of poly(γ-methyl-L -glutamate). Circular dichroism studies were carried out for solution and solid film as a function of the degree of stearylation and temperature. The slight and gradual temperature dependence of molecular ellipticity was observed for solution of all the copolyglutamates studied here and for the solid film of the copolyglutamate with the degree of stearylation of 16%, indicative of no reversal in the helix sense. However the remarkable change in negative molecular ellipticity with temperature was detected for the solid film of the copolyglutamate with a low degree of stearylation, e.g., 52%, whereas the drastic change in molecular ellipticity from a negative to positive value appeared for that with a higher degree of stearylation. This is discussed in terms of the reversal in the helix sense from a right- to left-handed α helix with the increase of temperature occurring at the melting temperature of the ordered side chain region. 相似文献
46.
Intermolecular interaction energies of 12 orientations of C(3)F(8) dimers were calculated with electron correlation correction by the second-order M?ller-Plesset perturbation method. The antiparallel C(2h) dimer has the largest interaction energy (-1.45 kcal/mol). Electron correlation correction increases the attraction considerably. Electrostatic energy is not large. Dispersion is mainly responsible for the attraction. Orientation dependence of the interaction energy of the C(3)F(8) dimer is substantially smaller than that of the C(3)H(8) dimer. The calculated interaction energy of the C(3)F(8) dimer at the potential minimum is 78% of that of the C(3)H(8) dimer (-1.85 kcal/mol), whereas the interaction energies of the CF(4) and C(2)F(6) dimers are larger than those of the CH(4) and C(2)H(6) dimers. The intermolecular separation in the C(3)F(8) dimer at the potential minimum is substantially larger than that in the C(3)H(8) dimer. The larger intermolecular separation due to the steric repulsion between fluorine atoms is the cause of the smaller interaction energy of the C(3)F(8) dimer at the potential minimum. The calculated intermolecular interaction energy potentials of the C(3)F(8) dimers using an all atom model OPLS-AA (OPLS all atom model) force field and a united atom model force field were compared with the ab initio calculations. Although the two force fields well reproduces the experimental vapor and liquid properties of perfluoroalkenes, the comparison shows that the united atom model underestimates the potential depth and orientation dependence of the interaction energy. The potentials obtained by the OPLS-AA force field are close to those obtained by the ab initio calculations. 相似文献
47.
Uchimaru T Uebayasi M Hirose T Tsuzuki S Yliniemelä A Tanabe K Taira K 《The Journal of organic chemistry》1996,61(5):1599-1608
The enzymatic cleavage of RNA takes place via a cyclic pentacoordinate oxyphosphorane intermediate/transition state. We carried out ab initio investigations on the neutral cyclic oxyphosphorane, which exists as a stable intermediate. As a consequence of the conformational preferences of the pentacoordinate trigonal bipyramidal intermediates, the rotation of the P-OH bonds is strongly coupled with the reaction coordinate for the pseudorotation process. In addition, the neutral PF(4)OH species has a higher barrier to pseudorotation than the corresponding anionic species PF(4)O(-). These findings are related to the positive charge of the hydrogen atoms on the equatorial oxygens in the trigonal bipyramidal structures: the hydrogen atoms preferably adopt eclipsed positions relative to the axial ligands. Fixing the cationic species in these regions causes an increase in the barrier heights for pseudorotation processes and, thus, prevents isomerization by pseudorotation. Consequently, metal coordination in the double-metal ion mechanism for enzymatic cleavage of RNA should serve to exclusively stabilize the trigonal bipyramidal intermediate/transition state for the in-line attack and departure process. 相似文献
48.
49.
Let G be the unitary group of a non-degenerate Hermitian space and H the stabilizer of a one-dimensional positive definite subspace of the Hermitian space. For a uniform lattice Γ in G such that Γ∩H is a uniform lattice of H, we introduce the (averaged) H-period integrals of automorphic forms on Γ G; we study their behavior as Γ shrinks to the identity along a tower of lattices in G and prove a limit formula of the H-period integrals. 相似文献
50.
Effect of Particle Size on the Photocatalytic Activity of Nanoparticulate Zinc Oxide 总被引:3,自引:0,他引:3
In this study, a three-stage process consisting of mechanical milling, heat treatment, and washing has been used to manufacture nanoparticulate ZnO powders with a controlled particle size and minimal agglomeration. By varying the temperature of the post-milling heat treatment, it was possible to control the average particle size over the range of 28–57 nm. The photocatalytic activity of these powders was characterized by measuring the hydroxyl radical concentration as a function of irradiation time using the spin-trapping technique with electron paramagnetic resonance spectroscopy. It was found that there exists an optimum particle size of approximately 33 nm for which the photocatalytic activity is maximized. The existence of this optimal particle size is attributable to an increase in the charge carrier recombination rate, which counteracts the increased activity arising from the higher specific surface area for a sufficiently small particle size. 相似文献