Origins of hole doping and relevant optoelectronic properties of wide gap p-type semiconductor, LaCuOSe

LaCuOSe is a wide band gap (～2.8 eV) semiconductor with unique optoelectronic properties, including room-temperature stable excitons, high hole mobility ～8 cm(2)/(Vs), and the capability of high-density hole doping (up to 1.7 × 10(21) cm(-3) using Mg). Moreover, its carrier transport and doping behaviors exhibit nonconventional results, e.g., the hole concentration increases with decreasing temperature and the high hole doping does not correlate with other properties such as optical absorption. Herein, secondary ion mass spectroscopy and photoemission spectroscopy reveal that aliovalent ion substitution of Mg at the La site is not the main source of hole doping and the Fermi level does not shift even in heavily doped LaCuOSe:Mg. As the hole concentration increases, the subgap optical absorption becomes more intense, but the increase in intensity does not correlate quantitatively. Transmission electron microscopy indicates that planar defects composed of Cu and Se deficiencies are easily created in LaCuOSe. These observations can be explained via the existence of a degenerate low-mobility layer and formation of complex Cu and Se vacancy defects with the assistance of generalized gradient approximation band calculations.     

Sorption and partial molar volume of gases in poly (dimethyl siloxane)

Sorption of N₂, O₂, Ar, CH₄, CO₂, C₂H₄, and C₂H₆ in poly (dimethyl siloxane) liquid and rubber and the dilation of the polymers due to sorption of the gases are studied at 25°C under pressures up to 50 atm. In the liquid, the sorption isotherms for low-solubility and high-solubility gases are described by Henry's law and the Flory–Huggins equation, respectively. Gas sorption in the rubber, which contains a 29 wt % silica filler, follows the dual-mode sorption model, though marked hysteresis is observed in the sorption of O₂ and CH₄. The dilation isotherms increase linearly or exponentially in both polymers with increasing pressure. Considering that gas molecules adsorbed into micropores of the filler particles do not participate in the dilation, partial molar volumes of the dissolved gases in the rubber are determined from data of sorption and dilation. The values are nearly equal to the partial molar volumes in the liquid (48–60 cm³/mol).     

Analysis of a cylindrical shell with spiral groove

Summary The analytical method is presented for a cylindrical shell with spiral groove. The governing equations of cylindrical shell derived by one of the authors are introduced and Kirchhoff's boundary conditions along any smooth path are deduced from the principle of energy. The analysis is carried out for a cylindrical shell under a uniform bending moment by considering the equilibrium conditions of a shell element. Numerical results are given for various geometrical parameters of cylindrical shell and the angle of the spiral groove, some of which are confirmed by an experiment.

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übersicht Die analytische Methode wird für eine Kreiszylinderschale mit spiraler Fuge entwickelt. Die von einem der Verfasser eingeführten Differentialgleichungen der Kreiszylinderschale und die Kirchhoffschen Randbedingungen l?ngs des beliebig geneigten Randes, die vom Prinzip der Energie hergeleitet wurden, werden angegeben. Das Problem der Kreiszylinderschale mit spiraler Fuge unter einem uniformen Biegemoment wird unter Berücksichtigung der komplizierten Gleichgewichtsbedingungen der Schalenelemente analysiert. Die numerischen Ergebnisse zeigen gute übereinstimmung mit experimentellen Ergebnissen.

     

An Anti CuO2‐type Metal Hydride Square Net Structure in Ln2M2As2Hx (Ln=La or Sm,M=Ti,V, Cr,or Mn)

Using a high pressure technique and the strong donating nature of H⁻, a new series of tetragonal La₂Fe₂Se₂O₃‐type layered mixed‐anion arsenides, Ln₂M₂As₂H_x, was synthesized (Ln=La or Sm, M=Ti, V, Cr, or Mn; x≈3). In these compounds, an unusual M₂H square net, which has anti CuO₂ square net structures accompanying two As³⁻ ions, is sandwiched by (LaH)₂ fluorite layers. Notably, strong metal–metal bonding with a distance of 2.80 Å was confirmed in La₂Ti₂As₂H_2.3, which has metallic properties. In fact, these compounds are situated near the boundary between salt‐like ionic hydrides and transition‐metal hydrides with metallic characters.     

Nonexistence of type II blowup solution for a semilinear heat equation

A solution u of a Cauchy problem for a semilinear heat equation

     

A sufficient condition for type I blowup in a parabolic-elliptic system

This paper is concerned with blowup of positive solutions to a Cauchy problem for a parabolic-elliptic system

     

The study for the incipient solvation process of NaCl in water: the observation of the NaCl-(H2O)n (n = 1, 2, and 3) complexes using Fourier-transform microwave spectroscopy

Pure rotational spectra of the sodium chloride-water complexes, NaCl-(H(2)O)(n) (n = 1, 2, and 3), in the vibronic ground state have been observed by a Fourier- transform microwave spectrometer coupled with a laser ablation source. The (37)Cl-isotopic species and a few deuterated species have also been observed. From the analyses of the spectra, the rotational constants, the centrifugal distortion constants, and the nuclear quadrupole coupling constants of the Na and Cl nuclei were determined precisely for all the species. The molecular structures of NaCl-(H(2)O)(n) were determined using the rotational constants and the molecular symmetry. The charge distributions around Na and Cl nuclei in NaCl are dramatically changed by the complex formation with H(2)O. Prominent dependences of the bond lengths r(Na-Cl) on the number of H(2)O were also observed. By a comparison with results of theoretical studies, it is shown that the structure of NaCl-(H(2)O)(3) is approaching to that of the contact ion-pair, which is considered to be an intermediate species in the incipient solvation process.     

La2Sb, a layered superconductor with metal-metal bonds

We found that La(2)Sb with a layered structure composed of alternate stacking of La square nets and LaSb layers exhibits bulk superconductivity with a critical temperature of 5.3 K. This suggests that the presence of the square net with strong La-La metal bonding is essential for the emergence of superconductivity.     

Production of laser-heated plasma in high- pressure Ar gas and emission characteristics of vacuum ultraviolet radiation from Ar2 excimers

A new pump scheme for the realization of a practical Ar₂ excimer laser operating at 126 nm has been proposed and investigated experimentally. In this scheme, pre-ionized high-pressure Ar gas was excited by an intense transversely-excited atmospheric (TEA) CO₂ laser irradiation. A 100-mm-long line plasma was successfully produced at an argon gas pressure of 2 MPa. The vacuum ultraviolet emission at 126 nm from the Ar₂ excimers was observed and its emission characteristics were investigated under various experimental conditions. Received: 10 December 2001 / Published online: 14 March 2002