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41.
Polarized reflection spectra of a K-TCNQ single crystal have been measured at 27,295 and 413 K. The absorption spectra were derived from the observed reflection spectra by Kramers-Kronig transformation. At 27 K, the near-infrared absorption band which is associated with the charged transfer between TCNQ? ions, splits into a strong sharp peak at 8 × 103 cm?1 and a weak broad band at 11 × 103 cm?1. These bands were interpreted in terms of the strongly correlated extended Hubbard model including the nearest-neighbor Coulomb interaction. 相似文献
42.
Kanho H Yaoya S Kawahara N Nakane T Takase Y Masuda K Kuroyanagi M 《Chemical & pharmaceutical bulletin》2005,53(4):361-365
The glucosylation of some coumarin and flavone derivatives on incubation with the hairy roots of morning glory (Pharbitis nil) was previously reported. We further studied the biotransformation of benzaldehyde- and acetophenone-type derivatives. Vanillin and isovanillin were reduced to alcoholic derivatives and glucosylated at the phenolic and the alcoholic hydroxyl groups. In the case of 3,4-dihydroxybenzaldehyde, the formyl group was reduced and the 3-hydroxyl or 4-hydroxyl groups were glucosylated to give monoglucosides. The 3-hydroxyl group was predominantly glucosylated to the 4-hydroxyl group. 4-beta-D-Glucopyranosyloxy-3-methoxybenzylalcohol was obtained in low yield. In time-course experiments with vanillin, it was found that the high-level reduction of the formyl group and glucosylation of the phenolic hydroxyl group occurred, and finally 4-O-beta-D-glucopyranosylvanillylalcohol was obtained as the main product. In the case of 3,4-dimethoxybenzaldehyde, 3,4,5-trimethoxybenzaldehyde, and salicylaldehyde, the formyl groups were reduced, and then the hydroxyl groups at the benyl position were glucosylated to give alcoholic glucosides in relatively high yields. In 4-hydroxy-3-methoxyacetophenone, the 4-hydroxyl group was glucosylated and two dimerized glucosides, biphenyl and biphenylether types, were obtained in low yields. In acetophenone, 1-beta-D-glucopyranosyloxy-1-phenylethane and 2-beta-D-glucopyranosyloxyacetophenone were obtained. As mentioned above P. nil hairy roots showed various biotransformative activities including glucosylation of phenolic and benzylic hydroxyl groups, reduction of the formyl group near the benzene ring, and phenol oxidation dimerization. The glucosylation reaction was especially interesting for the production of valuable glucosides. 相似文献
43.
Takahiro Hirotsu Shunsaku Katoh Kazuhiko Sugasaka Masako Sakuragi Kunihiro Ichimura Yoshio Suda Mitsugi Fujishima Yoshimoto Abe Takahisa Misonoo 《Journal of polymer science. Part A, Polymer chemistry》1986,24(8):1953-1966
Preparation of new chelating polymers bearing dihydroxamic acid groups and the adsorptive ability for uranium in sea water are described. Chloromethylated polystyrene crosslinked with divinylbenzene was treated with diethyl malonate in N, N-dimethylformamide to give the polymer having diethyl malonate groups. This polymer was then treated with hydroxylamine in methanol to afford the dihydroxamic acid polymer. The presence of hydroxamic acid groups was confirmed by the appearance of IR absorption band at 1680 cm?1. The dihydroxamic acid polymer contained carboxylic acid groups as well as hydroxamic acid ones, and the contents of carboxylic acid and hydroxamic acid groups were estimated from elemental analysis to be 2–3 and 2–4 mmol/g, respectively. The polymer showed the adsorptive ability of 40 μg-U/g in 8 days for uranium in sea water. In addition, the polymer showed the selective adsorptivity for iron, nickel, copper, and zinc as well as uranium. The macroreticular-type polymer showed much higher adsorption rate for uranium in sea water than the gel-type ones did, suggesting that the rate depends on the diffusion of the uranium in the polymer support. 相似文献
44.
Takahisa Machiguchi 《合成通讯》2013,43(13):1021-1026
Tropone is prepared by an improved method in high yields without troublesome workup processes. Thus, di-7-cycloheptatrienyl ether is treated at room temperature with a small amount of trifluoroacetic acid as a catalyst. 相似文献
45.
Katsuhiro Shirono Kosei Iwase Hiroshi Okazaki Masaru Yamazawa Kazuhiro Shikakume Natsuo Fukumoto Masashi Murakami Masaaki Yanagisawa Takahisa Tsugoshi 《Accreditation and quality assurance》2013,18(3):161-174
Methods of utilizing the Youden plot obtained from interlaboratory comparison tests are proposed. The Youden plot is a powerful tool for visually evaluating between- or within-laboratory errors. However, there are no generally applicable methods to indicate the anomalies in the between- and the within-laboratory errors in qualitative terms. An evaluation frame was therefore developed in this study as an indication method. Moreover, the Youden plot is considered to be useful for visually assessing the comprehensive performance of laboratories using two types of results. Although the confidence ellipse has been proposed in ISO 13528:2005 for this purpose, robust determination of the parameters has not yet been implemented. In the present study, robust determination of one of the parameters, the correlation coefficient, was developed. Our proposals were analytically validated using two types of statistical models. In addition, the properties were evaluated through computational simulations. From the results obtained, it can be concluded that our proposals are practically applicable to actual interlaboratory comparison tests. 相似文献
46.
Matsumoto Yutaka Takeo Yoko Egawa Satoru Yamaguchi Gota Yokomae Shunya Takei Masashi Yumoto Hirokatsu Koyama Takahisa Ohashi Haruhiko Tono Kensuke Yabashi Makina Mimura Hidekazu Kimura Takashi 《Optical Review》2022,29(1):7-12
Optical Review - A microfluidic device was developed for coherent diffraction imaging using an X-ray free-electron laser (XFEL-CDI). Liquid samples, which are separately packed in reservoirs of the... 相似文献
47.
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49.
The application of electrospray ionization mass spectrometry (ESI-MS) for aluminum speciation in the positive and negative ion modes was discussed. Aluminum nitrate, perchlorate and sulfate solutions were measured by ESI-MS. In the positive ion mode, aluminum species containing anions (Al-L; L=NO3, ClO4 and SO4) were identified, while [Al(OH)2(H2O)n]+ (n=2-4) were the main species. The affinity of the anions with Al3+ estimated by ESI-MS was consistent with the hardness of the anions (hard and soft acids and bases principle) and the results from 27Al nuclear magnetic resonance studies. This indicates that the results observed from the positive ion mode preserved the chemical state of aluminum in the solution. In the negative ion mode, [Al(OH)4-nLn]- (n=0-2, L=NO3, ClO4) were the main species, which were considered to be converted from positive aluminum species, [Al(OH)(H2O)n]+ (n=2-4), by the successive addition of anions. Anions did not only attach to one aluminum ion but also bridged two aluminum ions. In Al2(SO4)3 solution, the behavior of SO4(2-) in the negative ion mode differed from that of NO3- and ClO4-. This may reflect the affinity of SO4(2-) with Al3+ in the solution or in the mass spectrometer or in both. Finally, detection mechanisms for the aluminum species in the solution are proposed for both the positive and negative ion modes. It is shown that ESI-MS can be used to observe the interaction between Al3+ and anions. We show the importance of the interpretation of the results by ESI-MS for obtaining new information of the metal species in the solution. 相似文献
50.