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71.
Maeda Y Miyashita J Hasegawa T Wakahara T Tsuchiya T Feng L Lian Y Akasaka T Kobayashi K Nagase S Kako M Yamamoto K Kadish KM 《Journal of the American Chemical Society》2005,127(7):2143-2146
The chemical reduction and oxidation of M@C82 (M = Y, La, and Ce) afford the corresponding anion and cation, respectively, which show unique and interesting chemical reactivities. It is found that the successful reversible gain or loss of electrons by ionization is useful for controlling the stability and reactivity of M@C82 toward both nucleophiles and electrophiles. 相似文献
72.
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74.
Charge-transfer complexes of TCNQ with ylides, new-type donors, were synthesized and the X-ray photoelectron spectra of these complexes were measured. A broad satellite caused by TCNQ radicals observed. 相似文献
75.
76.
Tsuchiya T Wakahara T Lian Y Maeda Y Akasaka T Kato T Mizorogi N Nagase S 《The journal of physical chemistry. B》2006,110(45):22517-22520
A preferential extraction of endohedral metallofullerenes (EMFs) from carbon soot through the use of reduction in the extraction process and a convenient isolation of endohedral metallofullerene anions (EMFs(-)) and empty fullerenes utilizing their difference in solubility are accomplished. EMFs are easily isolated by one-stage high-performance liquid chromatography after chemical oxidation of the extracted endohedral EMFs(-). 相似文献
77.
Tsuchiya S Sunazuka T Hirose T Mori R Tanaka T Iwatsuki M Omura S 《Organic letters》2006,8(24):5577-5580
K01-0509 B is a novel natural product which contains a carbamoylated cyclic guanidine. Our asymmetric total synthesis features a Sharpless asymmetric epoxidation and a stereocontrolled construction of the cyclic guanidine via an asymmetric nitroaldol reaction, followed by intramolecular SN2 cyclization. These reactions allowed the cyclic guanidine and the adjacent hydroxy group to be assembled, facilitating the asymmetric total synthesis and determination of the absolute stereochemistry of K01-0509 B. [reaction: see text]. 相似文献
78.
T. Tsuchiya F. Yamaguchi I. Morimoto T. Nakajima T. Kumagai 《Applied Physics A: Materials Science & Processing》2010,98(4):745-749
A tin-doped indium oxide (ITO) film on a SiO2 substrate was prepared by photo-irradiation of spin-coated nanoparticles using a Xe excimer lamp and a KrF excimer laser.
The effects of the excimer lamp and the excimer laser on the resistivity, mobility, and carrier concentration of the film
were investigated. To better understand how to control the microstructure of the film, we investigated the effect of thickness
on the resistivity of a film prepared by the two-step process, and found that the resistivity was higher in a thicker film.
Using two-step irradiation plus one-step KrF irradiation in N2 at room temperature, we produced an ITO film with lowest resistivity of any in this study. The electrical resistivity of
this film was 5.94×10−4 Ω cm. On the other hand, when using a simple thermal process, the resistivity of a film sintered at 500°C in N2 was 4.10×10−3 Ω cm. The differences in resistivity are discussed on the basis of the microstructure of the films using atomic force microscopy
and Hall measurements. 相似文献
79.
Tetsuo Tsuchiya Akio Watanabe Tomohiko Nakajima Toshiya Kumagai 《Applied Physics A: Materials Science & Processing》2010,101(4):681-684
Europium-doped yttrium oxide (Y2O3:Eu) thin films were successfully deposited on quartz and ITO/glass substrates by excimer-laser-assisted metal organic deposition
(ELAMOD) at low temperatures. The effects of laser wavelength and thermal temperature on the films’ crystallinity and photoluminescence
properties were investigated. Films irradiated by an ArF laser at 80 mJ/cm2 and 400–500°C were highly crystallized compared with those prepared by thermal MOD. In contrast, when the film was irradiated
by a KrF laser at 500°C, no crystalline Y2O3:Eu was formed. The Y2O3:Eu film irradiated by the ArF laser at 80 mJ/cm2 and 500°C showed typical PL spectra of Eu3+ ions with cubic symmetry and a 5D0→7F2 transition at ∼612 nm. The PL intensity at 612 nm was much higher for the film prepared with ELAMOD than for that prepared
by the thermal-assisted process, and the photoemission intensity of the film prepared with ELAMOD strongly depended on the
substrate material. 相似文献
80.
We consider driftless stochastic differential equations and the diffusions starting from the positive half line. It is shown that the Feller test for explosions gives a necessary and sufficient condition to hold pathwise uniqueness for diffusion coefficients that are positive and monotonically increasing or decreasing on the positive half line and the value at the origin is zero. Then, stability problems are studied from the aspect of Hölder-continuity and a generalized Nakao–Le Gall condition. Comparing the convergence rate of Hölder-continuous case, the sharpness and stability of the Nakao–Le Gall condition on Cantor stochastic differential equations are confirmed. Furthermore, using the Malliavin calculus, we construct a smooth solution to degenerate second order Fokker–Planck equations under weak conditions on the coefficients. 相似文献