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Teruhisa S. Komatsu Naoko Nakagawa Shin-Ichi Sasa Hal Tasaki 《Journal of statistical physics》2009,134(2):401-423
Recently a novel concise representation of the probability distribution of heat conducting nonequilibrium steady states was
derived. The representation is valid to the second order in the “degree of nonequilibrium”, and has a very suggestive form
where the effective Hamiltonian is determined by the excess entropy production. Here we extend the representation to a wide
class of nonequilibrium steady states realized in classical mechanical systems where baths (reservoirs) are also defined in
terms of deterministic mechanics. The present extension covers such nonequilibrium steady states with a heat conduction, with
particle flow (maintained either by external field or by particle reservoirs), and under an oscillating external field. We
also simplify the derivation and discuss the corresponding representation to the full order. 相似文献
114.
Shirakawa E Nakao Y Tsuchimoto T Hiyama T 《Chemical communications (Cambridge, England)》2002,(17):1962-1963
Polycyclic compounds having linearly-fused six-membered rings can be readily prepared by various modes of cyclization from dienediynes, which were synthesized through the nickel-catalysed alkynylstannylation of 1,2-dienes followed by the palladium-catalysed oxidative homocoupling of the resulting alkenylstannanes. 相似文献
115.
A triphenylphosphine having a strong electron-donating group, an oxyanion, at the para position of one of the benzene rings was found to show much higher efficiency compared with other structurally related triarylphosphines in the palladium-catalysed arylation of alkenes. 相似文献
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117.
Nakajima Y Shiraishi Y Tsuchimoto T Ozawa F 《Chemical communications (Cambridge, England)》2011,47(22):6332-6334
Cu(I) complexes bearing BPEP as a PNP-pincer type phosphaalkene ligand undergo effective bonding interactions with SbF(6)(-) and PF(6)(-) as non-coordinating anions to give [Cu(SbF(6))(BPEP)] and [Cu(2)(BPEP)(2)(μ-PF(6))](+), respectively [BPEP = 2,6-bis(1-phenyl-2-phosphaethenyl)pyridine]. NMR and theoretical studies indicate a reduced anionic charge of the μ-PF(6) ligand, which is induced by the strong π-accepting ability of BPEP. 相似文献