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181.
We report an online concentration and separation method for basic proteins using poly(diallyldimethylammonium chloride) (PDDA) solutions in the presence of reversed EOF. Using a capillary dynamically coated with 2% PDDA containing 0.1 M NaCl and filled with 1.2% PDDA under neutral conditions (10 mM phosphate, pH 7.0), we have demonstrated the separation of six basic proteins with peak efficiencies ranging from 175 000 to 616 000 plates/m and RSDs of migration time less than 0.4%. Additionally, high-speed separation of six basic proteins (<7 min) was achieved using a short capillary filled with 0.6% PDDA solutions. Under injection of the large-volume sample (210 nL), the LODs at S/N of 3 for basic proteins are down to nanomolar range. For example, the LOD for lysozyme is 1.2 nM, which is a 260-fold sensitivity enhancement compared with conventional injection method. The proposed method has been applied to the stacking of lysozyme in human saliva samples. Without any pretreatment, we also demonstrated the capability of this method to detect low amounts of peptide samples through the stacking of tryptic peptide of myoglobin. The experimental results indicate that our proposed method has great potential for use in clinical diagnosis and proteomics applications. 相似文献
182.
Hana Bellerová Ampere A. Tseng Michal Pohanka Miroslav Raudensky 《Heat and Mass Transfer》2012,48(11):1971-1983
The transient temperatures of a metal testing plate during spray cooling using alumina/water nanofluids were measured. The heat transfer coefficient (HTC) was calculated by an inverse heat-conduction technique using the measured temperatures. The results show a decrease of approximately 20?% of the HTC of spray cooling with the nanoparticle suspension changing from 0 to 16.45?%. The nature and the reason of the HTC deduction were investigated and the HTC correlations with the mass fluxes and nanoparticle fraction were specifically reported. 相似文献
183.
Bo-Xi Liao Neng-Chun Tseng Ziyi Li Yingshu Liu Jen-Kun Chen Chuen-Jinn Tsai 《Journal of nanoparticle research》2018,20(7):203
This study characterized the process by-product particles (mostly nanoparticles) released during the preventive maintenance of semiconductor fabrication facilities, such as chemical mechanical planarization (CMP), plasma-enhanced chemical vapor deposition (PECVD), and ion implantation. Manual sampling and real-time measurements with direct reading instruments were conducted to assess the exposure levels of nanoparticles and their physical and chemical properties. Significant amount of nanoparticles were observed in the breathing zone of the workers during the maintenance of the PECVD and ion implanters with the peak number concentrations as high as 6,470,000 and 65,444 #/cm3, respectively, indicating that the deposited residual chemicals in the reaction chambers were released as airborne nanoparticles by the maintenance activities. In contrast, nanoparticles released during the maintenance of the local scrubber, CMP, and replacing CMP slurry drums were insignificant. Causes of the particle release were discussed and suggestions were made to mitigate the nanoparticle release and reduce the exposure levels. 相似文献
184.
Pi-Ying Cheng Wen-Tse Hsiao Chien-Kai Chung Shih-Feng Tseng Ien-Chang Liao 《Optical Review》2014,21(5):732-735
To accomplish an electrode patterning in large area, we present a high speed stitching technique used in an ultraviolet laser processing system and investigate the interaction between laser beams and indium tin oxide (ITO) thin films deposited on glass substrates. After optimizing the process parameters of the laser direct imaging (LDI) for the large-area electrode patterning, the ablated lines looked like regularly fish-scale marks of about a 40 μm diameter and a 120 nm depth around the processing path. The parameters includes the laser power of 1W, the scanning speed of galvanometers of 800 mm/s, and the laser pulse repetition frequency of 50 kHz. Moreover, the resistance value of the ablated ITO thin film is larger than 200MΩ that is electrically insulated from the other regions of electrode structure. LDI technology with UV laser beam has great potential applications in patterning on wafer or sapphire substrates and patterning a conductive layer deposited on the touch panels for semiconductor and optoelectric industries, respectively. 相似文献
185.
Ming‐Han Liu Yao‐Hung Tseng Heather F. Greer Prof. Dr. Wuzong Zhou Prof. Dr. Chung‐Yuan Mou 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(50):16104-16113
Mesocrystals of ZnO were synthesized hydrothermally by using gum arabic as a structure‐directing agent. Their hierarchical structure has a unique twin‐brush form consisting of vertically aligned nanorods in a single‐crystal‐like porous form. The formation mechanism of the twin‐brush ZnO was investigated by quenching a series of samples at different times and examining them by TEM, SEM, and XRD. The alignment of ZnO crystal units can be modulated by adding simple salts such as KCl to change the units from nanorods to nanoplates. This can be explained by screening the dipolar force of the polar crystal. Local cathodoluminescence of twin‐brush ZnO was used to follow the local structure changes. 相似文献
186.
Chih-Hua Tseng Chi-Yi Li Chien-Chih Chiu Huei-Ting Hu Chein-Hwa Han Yeh-Long Chen Cherng-Chyi Tzeng 《Molecular diversity》2012,16(4):697-709
A number of 2,4,5-triaryl-1H-imidazole derivatives were synthesized and evaluated for their antiproliferative activities against the growth of five cell lines including three non-small cell lung cancers (H460, H1299, and A549), one breast cancer (MCF-7), and one normal diploid embryonic lung cell line (MRC-5). Preliminary results indicated that both 2-(5-bromofuran-2-yl)-4,5-bis{4-[3-(dimethylamino) propoxy] phenyl}-1H-imidazole (10f) and 4,5-bis{4-[3-(dimethylamino)propoxy]phenyl}-2-(5-nitrofuran-2-yl)-1H -imidazole (10g) were selectively active against the growth of H1229 with an IC50 of less than 0.1???M, thus were more active than topotecan (IC50 >?10.0??? M). However, both 10f and 10g exhibited only marginal cytotoxicity against H460, A549, MCF-7, and MRC-5 requiring an IC 50 of at least 4.16???M. Our results also indicated that 10f induced H1299 cell cycle arrest at G0/G1 through the inactivation of p38 MAPK, JNK, ERK, as well as the expression of SIRT1 and survivin. These results suggested that 10f might have therapeutic potential against H1299 (non-small cell lung cancer cell). 相似文献
187.
CC Yeh CN Tseng JI Yang HW Huang Y Fang JY Tang FR Chang HW Chang 《Molecules (Basel, Switzerland)》2012,17(9):10916-10927
The water extract of Gracilaria tenuistipitata have been found to be protective against oxidative stress-induced cellular DNA damage, but the biological function of the ethanolic extracts of G. tenuistipitata (EEGT) is still unknown. In this study, the effect of EEGT on oral squamous cell cancer (OSCC) Ca9-22 cell line was examined in terms of the cell proliferation and oxidative stress responses. The cell viability of EEGT-treated OSCC cells was significantly reduced in a dose-response manner (p < 0.0001). The annexin V intensity and pan-caspase activity of EEGT-treated OSCC cells were significantly increased in a dose-response manner (p < 0.05 to 0.0001). EEGT significantly increased the reactive oxygen species (ROS) level (p < 0.0001) and decreased the glutathione (GSH) level (p < 0.01) in a dose-response manner. The mitochondrial membrane potential (MMP) of EEGT-treated OSCC cells was significantly decreased in a dose-response manner (p < 0.005). In conclusion, we have demonstrated that EEGT induced the growth inhibition and apoptosis of OSCC cells, which was accompanied by ROS increase, GSH depletion, caspase activation, and mitochondrial depolarization. Therefore, EEGT may have potent antitumor effect against oral cancer cells. 相似文献
188.
In this paper, we establish some new refinements for the celebrated Fejér??s and Hermite-Hadamard??s integral inequalities for convex functions. 相似文献
189.
Yu-Chih Tseng Yow-Jon Lin Hsing-Cheng Chang Ya-Hui Chen Chia-Jyi Liu Yi-Yan Zou 《Journal of luminescence》2012,132(2):491-494
This study investigates the effect of Ti content on the optical and structural properties of the Ti-doped ZnO (TixZn1?xO) nanoparticles by x-ray diffraction, scanning electron microscopy, photoluminescence and Raman scattering measurements. A dependence of luminescent properties and crystal structure upon Ti content has been found. The band-edge-luminescence (BEL) intensity of Ti0.10Zn0.90O at room temperature was nearly 1.7 times higher than that of ZnO. The enhanced BEL intensity is attributed to a decrease in the oxygen-vacancy density. However, the lower BEL intensity of Ti0.15Zn0.85O than Ti0.10Zn0.90O is attributed to an increase in the probability of nonradiative recombination. In addition, the intensity of the x-ray diffraction peaks remarkably decreases with increasing Ti content, suggesting weakened crystallinity. 相似文献
190.
Attachment of the redox-active C(60)(H)PPh(2) group modulates the electronic structure of the Fe(2) core in [(μ-bdt)Fe(2)(CO)(5)(C(60)(H)PPh(2))]. The neutral complex is characterized by X-ray crystallography, IR, NMR spectroscopy, and cyclic voltammetry. When it is reduced by one electron, the spectroscopic and density functional theory results indicate that the Fe(2) core is partially spin-populated. In the doubly reduced species, extensive electron communication occurs between the reduced fullerene unit and the Fe(2) centers as displayed in the spin-density plot. The results suggest that the [4Fe4S] cluster within the H cluster provides an essential role in terms of the electronic factor. 相似文献