Synchronization of chaotic system with uncertain variable parameters by linear coupling and pragmatical adaptive tracking

We study the synchronization of general chaotic systems which satisfy the Lipschitz condition only, with uncertain variable parameters by linear coupling and pragmatical adaptive tracking. The uncertain parameters of a system vary with time due to aging, environment, and disturbances. A?sufficient condition is given for the asymptotical stability of common zero solution of error dynamics and parameter update dynamics by the Ge?CYu?CChen pragmatical asymptotical stability theorem based on equal probability assumption. Numerical results are studied for a Lorenz system and a quantum cellular neural network oscillator to show the effectiveness of the proposed synchronization strategy.     

Experimental and numerical investigations on the dispersion behaviors of wedge waves propagating along wedges with bilinear cross sections

Wedge waves (WW) are guided acoustic waves propagating along the tip of a wedge, with energy tightly confined near the apex. This study is focused on exploring the dispersion behaviors of WW propagating along a bilinear wedge (BW). A BW is wedge with a cross section of two apex angles, compared with a linear wedge (LW) having a single apex angle. In the literature, many studies regarding to the dispersion behaviors of ASF modes are reported for LW, but not for BW. In this study, a combined experimental and numerical stidy is used to investigate the dispersion behavior of WW propagating in BW's. It is found out that WW in a BW is a result of mode coupling between the two WW's corresponding to simple wedges with the two apex angles of the BW.     

Photoassisted Synthesis of Luminescent Mannose–Au Nanodots for the Detection of Thyroglobulin in Serum

We have employed mannose‐modified gold nanodots (Man–Au NDs) as a luminescence sensor for the detection of the thyroid‐cancer marker thyroglobulin (Tg) in homogeneous solutions. The luminescent Man–Au NDs are prepared through the reaction of 2.9 nm‐diameter gold nanoparticles (Au NPs) with 11‐mercapto‐3,6,9‐trioxaundecyl‐α‐D ‐mannopyranoside (Man‐RSH) under the irradiation of a light‐emitting diode (LED). We have found that the irradiation enhances the quantum yield (～11 %), alters the emission wavelength and lifetimes, and shortens the preparation time. A luminescence assay has been developed for Tg based on the competition between Tg and Man–Au NDs for the interaction with the concanavalin A (Con A). Because luminescence quenching of the Man–Au NDs by Con A is inhibited by Tg selectivity, we have obtained a highly sensitive and selective assay for Tg.     

Chaos synchronization by variable strength linear coupling and Lyapunov function derivative in series form

A new general strategy to achieve chaos synchronization by variable strength linear coupling without another active control is proposed. They give the criteria of chaos synchronization for two identical chaotic systems and two different chaotic dynamic systems with variable strength linear coupling. In this method, the time derivative of Lyapunov function in series form is firstly used. Lorenz system, Duffing system, Rössler system and Hyper-Rössler system are presented as simulated examples.     

A model for simulating the dynamic surface tension behavior of aqueous surfactant dispersions

A dynamic adsorption model for surface-active materials at air/liquid interfaces with the consideration of aggregate dissolution effect was developed to investigate the dynamic surface tension behavior of aqueous surfactant dispersions. Two catanionic surfactants, cetylpyridinium dodecylsulfate (CP-DS) and dodecyltrimethylammonium dodecylsulfate (DTMA-DS), with low critical aggregation concentrations were chosen as model systems. Dynamic surface tensions of aqueous CP-DS and DTMA-DS systems were measured by a drop volume tensiometer. A model with diffusion-controlled or mixed-kinetic dynamic adsorption mechanisms considering the dissolution effect of dispersed aggregates was developed to simulate the dynamic surface tension data. An analysis by comparing the model predictions with experimental data demonstrated that the dynamic surface tension behavior of aqueous CP-DS and DTMA-DS dispersions could be described with a diffusion-controlled dynamic adsorption model taking the aggregate dissolution effect into account.     

Relevance of phenolic diterpene constituents to antioxidant activity of supercritical CO(2) extract from the leaves of rosemary

Isolation of phenolic diterpene constituents from the freeze-dried leaves of Rosmarinus officinalis has been obtained by supercritical extraction with carbon dioxide. To determine the ideal conditions for the maximum yield of extract, nine different conditions using three levels of pressures (3000, 4000 and 5000 psi) in combination with three temperatures at 40, 60 and 80 degrees C, respectively, in combination with the analyses of the corresponding antioxidant activities and constituents which existed in extracts has been investigated. The antioxidant activity of each obtained extract was determined by using the 2,2-diphenyl-1-picrylhydrazyl (DPPH) radicals test. GC/MS method was used as an alternative to conventional HPLC method for the determination of the principal antioxidant constituents in extract, including phenolic diterpenes carnosic acid (CA) and carnosol (CAL). The confirmation of CA and CAL in extract was forward performed by subjecting HPLC isolates from extract into an ion trap mass spectrometer through an electrospray ionization (ESI) interface for MS/MS analysis. These results indicate that an ideal extraction process was obtained at 5000 psi and 80 degrees C with an extraction yield of 4.27% (w/w) and rich in phenolic antioxidants CA and CAL as contents of 35.23 and 0.46 mg g(-1) in extract, respectively.     

Exploring the interactions between gold nanoparticles and analytes through surface‐assisted laser desorption/ionization mass spectrometry

Surface‐assisted laser desorption/ionization mass spectrometry (SALDI‐MS) is applied to provide strong evidence for the chemical reactions of functionalized gold nanoparticles (Au NPs) with analytes – Hg²⁺ ions induced MPA?Au NPs aggregation in the presence of 2,6‐pyridinedicarboxylic acid (PDCA) and H₂O₂ induced fluorescence quenching of 11‐MUA?Au NDs. PDCA‐Hg²⁺‐MPA coordination is responsible for Au NPs aggregation, while the formation of 11‐MUA disulfide compounds that release into the bulk solution is responsible for H₂O₂‐induced fluorescence quenching. In addition to providing information about the chemical structures, SALDI‐MS is also selective and sensitive for the detection of Hg²⁺ ions and H₂O₂. The limits of detection (LODs) for Hg²⁺ ions and H₂O₂ by SALDI‐MS were 300 nM and 250 µM, respectively. The spot‐to‐spot variations in the two studies were both less than 18% (50 sample spots). Our results reveal that SALDI‐MS can be used to study analyte‐induced changes in the surface properties of nanoparticles. Copyright © 2010 John Wiley & Sons, Ltd.     

Detection of melamine in infant formula and grain powder by surface‐assisted laser desorption/ionization mass spectrometry

We have developed a method for the determination of melamine (MEL), ammeline (AMN), and ammelide (AMD) by surface‐assisted laser desorption/ionization mass spectrometry (SALDI‐MS) using gold nanoparticles (Au NPs). The major peaks for MEL, AMN, and AMD at m/z 127.07, 128.05, and 129.04 are assigned to the [MEL + H]⁺, [AMN + H]⁺, and [AMD + H]⁺ ions. Because the three tested compounds adsorb weakly onto the surfaces of the Au NPs through Au–N bonding, they can be easily concentrated from complex samples by applying a simple trapping/centrifugation process. The SALDI‐MS method provides limits of detection of 5, 10, and 300 nM for MEL, AMN, and AMD, respectively, at a signal‐to‐noise ratio of 3. The signal variation for 150‐shot average spectra of the three analytes within the same spot was 15%, and the batch‐to‐batch variation was 20%. We have validated the practicality of this approach by the analysis of these three analytes in infant formula and grain powder. This simple and rapid SALDI‐MS approach holds great potential for screening of MEL in foods. Copyright © 2012 John Wiley & Sons, Ltd.     

IONS CONFINEMENT IN ELECTRON BEAM ION TRAP

This paper shows the evolution of density and temperature of multi-charged ions in an electron beam ion trap (EBIT). Three cases are studied: the continuous neutral gas injection, ion source injection, and evaporative cooling. The effects of the neutral gas density, axial potential, and the beam current density on the ions evolution are discussed.     

Synthesis of graft copolymers by reaction of polymethyl methacrylate with heterochain polyesters

Summary Graft copolymers were obtained by the interaction of polymethyl methacrylate with heterochain polyesters, their properties were studied and a hypothesis was put forward on their structure.The thermomechanical curves and x-ray pictures were obtained in the laboratories directed by G. L. Slonimskii and A. I. Kitaigorodskii, to whom we express our sincere thanks.