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1.
Tsarev Yu. V. Dmitriev A. E. Kostrov V. V. 《Russian Journal of Applied Chemistry》2003,76(11):1772-1775
Stages of synthesis of a copper-containing catalyst for electrocatalytic oxidation of acetone in waste gases were studied. The course of the extrusion and calcination and their influence on electrocatalytic oxidation of acetone on the catalyst synthesized were analyzed. 相似文献
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Ricerche di Matematica - Let $${\mathfrak {X}}$$ be a class of simple groups with a completeness property $$\pi ({\mathfrak {X}}) = \mathrm {char} \, {\mathfrak {X}}$$ . A formation is a class of... 相似文献
3.
V. N. Tsarev S. E. Lyubimov S. V. Zheglov A. A. Shiryaev V. A. Davankov K. N. Gavrilov 《Russian Chemical Bulletin》2004,53(9):2025-2028
A chiral P,N-bidentate aryl phosphite ligand containing peripheral (R)-(+)-camphor-derived ketimine and its rhodium(I) and palladium(II) chelate complexes were synthesized for the first time. These compounds were found to be suitable for asymmetric allylic substitution. The Pd-catalyzed sulfonylation of 1,3-diphenylallyl acetate with sodium p-toluenesulfinate gave the product in 73% ee; in the alkylation of the same substrate with dimethyl malonate, the ee was 94%. These ee values are higher than the enantioselectivity achieved with the known phosphine analogs.Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1942–1945, September, 2004. 相似文献
4.
A. B. Aleksandrov A. V. Bagulya M. S. Vladimirov L. A. Goncharova A. I. Ivliev G. V. Kalinina L. L. Kashkarov N. S. Konovalova N. M. Okat’eva N. G. Polukhina A. S. Rusetskii N. I. Starkov V. A. Tsarev 《Bulletin of the Lebedev Physics Institute》2008,35(9):276-285
The search for and identification of energetic nuclei of superheavy elements of cosmic rays in olivine crystals frommeteorites, currently performedwithin the Olympia project [1], are based on measurements of dynamic and geometrical parameters of tracks, i.e., chemically etchable regions of the traces of slowing down of these nuclei before their stop, using the fully automated PAVIKOM measuring system [2]. 相似文献
5.
Interference of effects of different levels and magnitudes in producing a net magnetooptical response was considered for the first time in structures similar to magnetophotonic crystals at different wavelengths of the incident irradiation in regions far from plasmon resonances. Contributions of interference and diffraction phenomena in maxima of different orders in three-dimensional systems of the magnetophotonic crystal type were studied. Use of the integral response in the analysis of the magnetooptical effects was shown to lead to disappearing of the interference phenomena. The zero-order diffraction maximum reflects adequately the magnetic component of the magnetooptical response. Numerical estimates of the observed diffraction and interference effects are reported. 相似文献
6.
K. N. Gavrilov V. N. Tsarev S. I. Konkin P. V. Petrovskii E. D. Lubuzh V. A. Davankov 《Russian Journal of Coordination Chemistry》2007,33(5):383-387
Previously unknown chiral P,N-bidentate N-pyrrolylphosphines and their chelate complexes [Rh(η2-P,N)(CO)Cl] and [Pd(Allyl)(η2-P,N)]BF4 were synthesized by phosphorylation of (E,1R,2R,3R,5S)-2-[(2,6,6-trimethylbicyclo[3.1.1]heptyl-3-)iminomethyl]-1H-pyrrole. The composition and structures of the novel compounds were determined by the 1H, 13C, and 31P NMR, IR, mass spectrometry (electrospray), and elemental analysis methods. N-pyrrolylphosphines were found to have unusual electronic properties, being simultaneously more strong π-acids and σ-bases as compared to phosphites. 相似文献
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Adsorption of Cr(VI) on Fe2O3 from model solutions with various Cr(VI) concentrations was studied. The adsorption capacity was determined, the constants of chromium(VI) adsorption on iron(III) oxide for the pseudo-second-order model were calculated, and the diffusion coefficients for the process were evaluated. 相似文献