Thermal fields in laser–multi-layer structures interaction

In the present paper, we are dealing with the thermal fields for laser–periodic multilayer structures interaction. Our point of view is originally that we consider any order transverse laser beams, like heating sources. We consider that the laser beam acts in IR (Nd:YAG or CO₂ laser beam) and it is in one transverse mode or in only a few decoupled modes. In order to solve this problem, we will use the Green function method. Specific results are presented for a laser beam (Nd:YAG laser) operating in the mode TEM₀₁ and a two-layer structure.     

Mass spectrometric studies of heterocyclic organophosphorus compounds: 1,3,2-benzodioxaphospholes

The mass spectral behaviour of a new type of organophosphorus compound, 1,3,2-benzodioxaphospholes, under 70 eV electron impact has been studied by means of high and low resolution mass spectrometry as well as by B/E and B²/E linked scans. The influence of different substituents in the molecule (O, S or N) on the mass spectra is investigated. The reason for isomerization between oxygen and sulphur within a molecule studied by mass spectrometry is discussed.     

Stress-concentration factors for semielliptical notches in beams under pure bending

Elliptical notches in rectangular beams under pure bending are examined photoelastically. Stress-concentration factors due to a single elliptical notch are obtained for wide ranges of 2a/h andd/h, where 2a, d, andh are the width of notch, depth of notch, and depth of beam, respectively. In particular, the geometries of the optimum elliptical notches producing the least stress concentrations are obtained. Almost the whole elliptical boundary of these notches are stressed to the same peak, which indicates that these notches will probably produce the least stress concentrations among all notches, elliptical or nonelliptical. The graphs herein will enable the designers to find the stress-concentration factors of elliptical notches and to pick out the geometry of the optimum notch which will give the least stress concentration for any given values of 2a/h andd/h. Stresses and the stress-concentration factors at the bottom of the beam opposite the notch are also obtained. These stresses, though smaller in magnitude, are of an opposite sign to the peak stress at the notch. For brittle materials, a smaller tensile stress may be more critical than a large compressive stress; therefore, these stress-concentration factors are also given.     

Fabrication of nanostructured silicon by metal-assisted etching and its effects on matrix-free laser desorption/ionization mass spectrometry

A matrix-free, high sensitivity, nanostructured silicon surface assisted laser desorption/ionization mass spectrometry (LDI-MS) method fabricated by metal-assisted etching was investigated. Effects of key process parameters, such as etching time, substrate resistance and etchant composition, on the nanostructured silicon formation and its LDI-MS efficiency were studied. The results show that the nanostructured silicon pore depth and size increase with etching time, while MS ion intensity increases with etching time to 300 s then decreases until 600 s for both low resistance (0.001–0.02 Ω cm) and high resistance (1–100 Ω cm) silicon substrates. The nanostructured silicon surface morphologies were found to directly affect the LDI-MS signal ion intensity. By characterizing the nanostructured silicon surface roughness using atomic force microscopy (AFM) and sample absorption efficiency using fluorescence microscopy, it was further demonstrated that the nanostructured silicon surface roughness was highly correlated to the LDI-MS performance.     

Unequal crossover recombination - population screening for PHOX2B gene polyalanine polymorphism using CE

Congenital central hypoventilation syndrome (CCHS) is a rare neurological disorder characterized by abnormal autonomic central nervous system control of breathing during sleep. Mutations in the paired-like homeobox 2B (PHOX2B) gene, including point mutation, frameshift, and polyalanine expansion, are associated with the pathogenesis of CCHS. In this study, PHOX2B mutations were analyzed in seven CCHS patients, their family members, and 1520 healthy individuals from the general population using CE to provide high sensitivity and resolution screening for the PHOX2B polyalanine polymorphism. Seven mutations in the PHOX2B gene, including two frameshift mutations and five polyalanine expansions in the 20-residue polyalanine tract, were identified. The various phenotypes observed in CCHS patients with PHOX2B mutations suggest that the size of the expansion allele is associated with the CCHS risk. In addition, significant differences were found in allele and genotype distributions between the healthy individuals. Alleles (GCN)(20) and (GCN)(15) had the highest population incidence rates of 94.84 and 4.51%, respectively, with the remaining alleles, (GCN)(13) and (GCN)(7), accounting for 0.59 and 0.06%, respectively. Therefore, it has been demonstrated that CE can be used to improve the detection of polyalanine expansions in the PHOX2B gene. The attractive alternative method is a promising tool for the detection of disorders involving trinucleotide repeat tracts.     

The Inclusion Properties of a New Watersoluble Sulfonated Calix[4]resorcinarene towards Alkylammonium and N-Methylpyridinium Cations

The inclusion behaviour of a new water-soluble sulfonated calix[4]resorcinarene towards alkylammonium and N-methylpyridinium cations has been investigated on the basis of ¹H NMR spectroscopy and pH-potentiometry data. The inclusion of the N-methylpyridinium cation has been found to be dependent on pH with the preferable inclusion of the methyl substituent in alkaline and the aromatic ring in neutral aqueous media.     

SYNTHESIS OF MELEZITOSE DERIVATIVES

The reactivity of melezitose hydroxyls is studied during tritylation in pyridine. Some novel derivatives of melezitose are prepared. An acetyl is transferred from the 4- to the 6-position after detritylation of 3 and 4. The structures of the products are proved by elemental analysis; ¹ H, ¹³ C, and ¹ H- ¹ H COSY NMR spectra;IR spectra; and fast-atom bombardment mass spectrometry.     

Production of fumaric acid by immobilized rhizopus using rotary biofilm contactor

Rotary biofilm contactor (RBC) is a reactor consisting of plastic discs that act as supports for micro-organisms. The discs are mounted on a horizontal shaft and placed in a medium-containing vessel. During nitrogen-rich growth phase, mycelia ofRhizopus oryzae ATCC 20344 grew on and around the discs and formed the “biofilm” of self-immobilized cells on the surface of the plastic discs. During the fermentation phase, the discs are slowly rotated, and the biofilms are exposed to the medium and the air space, alternately. With RBC, in the presence of CaCO₃,Rhizopus biofilm consumes glucose and produces fumaric acid with a volumetric productivity of 3.78 g/L/h within 24 h. The volumetric productivity is about threefolds higher with RBC than with a stirred-tank fermenter with CaCO₃. Furthermore, the duration of fermentation is one-third of the stirred-tank system. The immobilized biofilm is active for over a 2-wk period with repetitive use without loss of activity.

     

Performance enhancement on mechanical and electrical effects for on-line fiber-optic bending loss measurement

For an automatic testing of the fiber bending loss parameter, we proposed an on-line fiber optic bending loss measurement system. Many impact factors from the supporting systems, free space coupling alignment, external spatial perturbation device and the other automatic testing systems may degrade the on-line fiber-optic bending loss measurement system. We reduce those impact factors and show the mechanical and electrical improvement in this paper. The accuracy can be improved by 3–5 dB for the proposed on-line bending loss measurement system. Development of an on-line fiber-optic bending loss measurement system can provide a fast-checking solution for jump-line quality improvement on fiber-from-the-desk (FFTD) access network.