全文获取类型
收费全文 | 650089篇 |
免费 | 5755篇 |
国内免费 | 1912篇 |
专业分类
化学 | 335198篇 |
晶体学 | 9366篇 |
力学 | 32016篇 |
综合类 | 24篇 |
数学 | 82765篇 |
物理学 | 198387篇 |
出版年
2021年 | 5769篇 |
2020年 | 6272篇 |
2019年 | 7073篇 |
2018年 | 9225篇 |
2017年 | 9386篇 |
2016年 | 13283篇 |
2015年 | 7605篇 |
2014年 | 12301篇 |
2013年 | 29143篇 |
2012年 | 22826篇 |
2011年 | 27480篇 |
2010年 | 19973篇 |
2009年 | 19905篇 |
2008年 | 25713篇 |
2007年 | 25481篇 |
2006年 | 23477篇 |
2005年 | 21095篇 |
2004年 | 19511篇 |
2003年 | 17524篇 |
2002年 | 17244篇 |
2001年 | 18538篇 |
2000年 | 14330篇 |
1999年 | 11092篇 |
1998年 | 9436篇 |
1997年 | 9242篇 |
1996年 | 8740篇 |
1995年 | 7852篇 |
1994年 | 7764篇 |
1993年 | 7475篇 |
1992年 | 8040篇 |
1991年 | 8520篇 |
1990年 | 8006篇 |
1989年 | 7918篇 |
1988年 | 7734篇 |
1987年 | 7543篇 |
1986年 | 7208篇 |
1985年 | 9437篇 |
1984年 | 9746篇 |
1983年 | 8136篇 |
1982年 | 8565篇 |
1981年 | 7988篇 |
1980年 | 7684篇 |
1979年 | 8111篇 |
1978年 | 8405篇 |
1977年 | 8259篇 |
1976年 | 8235篇 |
1975年 | 7907篇 |
1974年 | 7687篇 |
1973年 | 8023篇 |
1972年 | 5654篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
2.
3.
Padavattan Govindaswamy Patrick J. Carroll Yurij A. Mozharivskyj Mohan Rao Kollipara 《Journal of Chemical Sciences》2006,118(4):319-326
The reaction of [{(η5-C5Me5)M(μ-Cl)Cl}2] {where M = Rh (1), Ir (2)} with functionalized phosphine viz., diphenyl-2-pyridylphosphine (PPh2Py) in dichloromethane solvent yield neutral ϰ1-P-coordinated rhodium and iridium complexes [(η5-C5Me5)RhCl2(κ1-P-PPh2Py)]3 and [(η5-C5Me5) IrCl2(ϰ1-P-PPh2Py)]4. Reaction of complexes 1 and 2 with the ligand PPh2Py in methanol under reflux give bis-substituted complexes such as [(η5-C5Me5)RhCl(ϰ1-P-PPh2Py)2]+
5 and [(η5-C5Me5)IrCl(ϰ1-P-PPh2Py)2]+
6, whereas stirring in methanol at room temperature gives P-, N-chelating complexes of the type [(η5-C5Me5)RhCl(ϰ2-P-N-PPh2Py)]+ 7 and [(η5-C5Me5)IrCl(ϰ2-P-N-PPh2Py)]+
8. Neutral ϰ1-P-coordinated complexes [(η5-C5Me5)RhCl2(ϰ1-P-PPh2Py)]3 and [(η5-C5Me5)IrCl2(ϰ1-P-PPh2Py)]4 easily undergo conversion to the cationic P-, N-chelating complexes [(η5-C5Me5)RhCl(ϰ2-P-N-PPh2Py)]+
7 and [(η5-C5Me5) IrCl(ϰ2-P, N-PPh2Py)]+
8 on stirring in methanol at room temperature. These complexes are characterized by FT-IR and FT-NMR spectroscopy as well as
analytical methods. The molecular structures of the representative complexes [(η5-C5Me5)RhCl2(ϰ1-P-PPh2Py)]3, [(η5-C5Me5)IrCl2(ϰ1-P-PPh2Py)]4 and hexafluorophosphate salt of complex [(η5-C5Me5)IrCl(ϰ2-P-PPh2Py)2]+
6 are established by single-crystal X-ray diffraction methods 相似文献
4.
The European Physical Journal E - The isothermal gas adsorption of two hexane isomers (n-hexane and cyclohexane) in the mesopores of MCM-41 silica have been investigated by small angle neutron... 相似文献
5.
The formation of singularities in the three-dimensional Euler equation is investigated. This is done by restricting the number of Fourier modes to a set which allows only for local interactions in wave number space. Starting from an initial large-scale energy distribution, the energy rushes towards smaller scales, forming a universal front independent of initial conditions. The front results in a singularity of the vorticity in finite time, and has scaling form as function of the time difference from the singularity. Using a simplified model, we compute the values of the exponents and the shape of the front analytically. The results are in good agreement with numerical simulations. 相似文献
6.
An optimal control model of exhaustible resources is used to clarify the long run relationship between mineral rent and depletion cost at the industry level. A standard first order condition of the time rate of change of rents is reformulated to reveal that rent data may be used to help forecast the rise in extraction costs resulting from resource depletion. This application of the theory of exhaustible resources is illustrated using historical mineral industry rent and extraction cost data. A forecast of U.S. coal extraction costs, following the method proposed in this paper, suggests that future rates of extraction cost increases will be similar to rates experienced in the past. 相似文献
7.
S. A. Gurevich T. A. Zaraiskaya S. G. Konnikov V. M. Mikushkin S. Yu. Nikonov A. A. Sitnikova S. E. Sysoev V. V. Khorenko V. V. Shnitov Yu. S. Gordeev 《Physics of the Solid State》1997,39(10):1691-1695
The concentration and chemical state of copper in the subsurface region of Cu/SiO2 composite films obtained by simultaneous magnetron sputtering from two sources (Cu and SiO2) are determined by x-ray photoelectron spectroscopy (XPS). It is established that copper in the as-grown film is primarily in the form of unoxidized atoms dispersed in a SiO2 matrix. Annealing of the film results in practically no oxidation, but about 70% of the copper atoms condense into metallic clusters with sizes below 10 Å in the subsurface region and about 50 Å in the bulk of the film. The changes in the binding energy of core electrons, and especially in the energies of Auger electrons, are so large in this situation that photoelectron and Auger spectroscopy are efficient methods for monitoring the chemical state of this composite material. 相似文献
8.
A converging perturbation series that can be summed analytically has been obtained for intersubband transitions of electrons
coherently tunneling through the middle of a dimensionally quantized level in an asymmetric double-barrier structure in a
high-frequency terahertz electric field. The possibility of a substantial increase in tunneling current accompanied by either
absorption or emission of a photon has been demonstrated. The quantum efficiency of radiative transitions between dimensionally
quantized levels can be up to 66%.
Zh. éksp. Teor. Fiz. 112, 237–245 (July 1997) 相似文献
9.
L. K. Aminov I. N. Kurkin D. A. Lukoyanov K. P. Chernov 《Physics of the Solid State》1997,39(8):1184-1186
Results are reported for measurements of the spin-lattice relaxation times of E′1 centers in quartz glass, produced by neutron irradiation, with the measurements made at two frequencies 9.25 and 24.0 GHz
over a wide temperature interval 1.5–300 K. The experimental data are interpreted on the basis of interaction mechanisms of
the spins with two-level systems with excitation energies ∼6, ∼26, and ∼420 cm−1. A small modification of the existing theory allows us to explain a number of features of the observed temperature and frequency
dependence of the relaxation rate. The results are compared with the data available in the literature on spin-lattice relaxation
of irradiation centers in crystalline quartz and quartz glass.
Fiz. Tverd. Tela (St. Petersburg) 39, 1335–1337 (August 1997) 相似文献
10.
V. A. Krakovskii 《Russian Physics Journal》1997,40(1):6-12
The problem of exciting bulk elastic waves at the surface of a piezoelectric with symmetries 422,622 has been solved by a
successive approximation method. In the approximation of a fixed electric field, created at the surface of the piezoelectric
crystal by a two-electrode transducer, the distributions are found for the shear wave stress and the energy flux density in
the far zone. The equivalent circuit parameters for a two-electrode radiator are determined taking account of the dynamic
piezoelectric correction obtained in the second approximation. The equivalent circuit parameters and the transducer loss are
treated for TeO2 crystals. A realistic possibility of using surface transducers in the development of acousto-optic modulators in the s.h.f.
region is shown.
Tomsk State Academy of Control Systems and Radio Electronics. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika,
No. 1, pp. 8–15, January, 1997. 相似文献